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Polymer nano-silica temperature-resistant, salt-tolerant and fluid loss reducing agent and preparation method thereof

InactiveCN103525379ANew features of strong high temperature resistanceGood temperature and salt resistanceDrilling compositionPolymer scienceEmulsion polymerization
The invention discloses a polymer nano-silica temperature-resistant, salt-tolerant and fluid loss reducing agent and a preparation method thereof. According to the preparation method, in the presence of nano-silica, a polymer-base nanometer composite material with amphiphilic block hydrophobic associating polymer wrapping inorganic nano-silica is successfully synthesized by virtue of a micellar emulsion polymerization method and combines the rigidity and the heat stability of the inorganic nano-silica and the characteristics of the amphiphilic block hydrophobic associating polymer together, and the temperature resistance, the salt tolerance and the thickening property of the polymer are obviously improved by virtue of the polymer-base nanometer composite material on the basis of the existing good performances of the amphiphilic block hydrophobic associating polymer. As a temperature-resistant, salt-tolerant and fluid loss reducing agent for a drilling fluid in the drilling engineering, the polymer nano-silica temperature-resistant, salt-tolerant and fluid loss reducing agent has a remarkable fluid loss reducing effect under high temperature and high salinity.
Owner:CHINA UNIV OF PETROLEUM (EAST CHINA)

Sludge charcoal for repairing heavy metal contaminated soil and preparation method of sludge charcoal

The invention belongs to the technical field of in-situ repair of heavy metal contaminated soil. Municipal sludge is used for preparing sludge-based charcoal through thermophilic thermolysis. The charcoal can be used as a repairing agent for the heavy metal contaminated soil. The sludge charcoal repairing agent comprises thickened sludge and palygorskite. A final black product namely the sludge-based charcoal is produced through the steps of performing biological and physical anhydration on sludge, then mixing the sludge after the biological and physical anhydration with the palygorskite, performing feeding into an atmosphere furnace, and then performing thermophilic thermolysis. The sludge charcoal is produced from the following components of 5-10% of the palygorskite and the balance of thethickened sludge. According to the sludge charcoal disclosed by the invention, the municipal sludge is subjected to decrement and harmless treatment, so that the municipal sludge can enter cycle of material and energy in natural environment again, and the difficult problem of treating and disposing the sludge is solved. The sludge charcoal is added to the heavy metal contaminated soil, so that heavy metal contaminated substances can be effectively solidified, the purposes of being durable and stable in repairing effect and being free from secondary pollution are realized, and the sludge charcoal is an ideal soil heavy metal contamination repairing agent with low cost.
Owner:LANZHOU JIAOTONG UNIV

High-substituted quaternary ammonium polysaccharide bioflocculant and preparation method thereof

The invention provides a high-substituted quaternary ammonium polysaccharide bioflocculant and a preparation method thereof. The preparation method comprises the following steps: alkalizing an aqueous solution of a raw material non-ionic bioflocculant in the presence of a certain amount of a catalyst at a certain water bath temperature through a wet process, slowly adding a certain amount of a dispersant in a dropwise manner, adding an etherifying agent, reacting for a period of time, precipitating, washing with water, washing with alcohol, drying, and grinding to prepare the quaternary ammonium polysaccharide bioflocculant with the substitution degree of 0.2-1.8. The method adopting the wet process has the advantages of good stability, simple operation, easy separation, high reaction conversion rate, high cost performance, and waste liquid recycling, and the quaternary ammonium polysaccharide bioflocculant has the advantages of non-toxicity, environmental protection, no secondary pollution and biodegradability, can be used for processing drinking water, printing and dyeing wastewater, coal washing water, mineral processing, oil refining wastewater, papermaking and chemical industry wastewater, and the like, and has substantial environmental and social benefits.
Owner:威海汉邦生物环保科技股份有限公司

Iron tailing soil improvement agent and iron tailing soil improvement method

The invention relates to an iron tailing soil improvement agent and an iron tailing soil improvement method. The iron tailing soil improvement agent comprises biochar, rice husks, ceramsite, organic fertilizers, attapulgite powder and planting soil. A mass ratio of the biochar to the rice husks to the ceramsite to the organic fertilizers to the attapulgite powder to the planting soil is (0.5-3):(0.2-1):(0.5-1.5):(1-4):(1-2.5):(1.0-2.2). The iron tailing soil improvement agent and the iron tailing soil improvement method have the advantages that the particle size of soil can be improved by theaid of the iron tailing soil improvement agent, the loss rate of water in the soil can be eased, the water retention capacity can be enhanced, organic matters can be quickly and effectively supplemented, the content of organic matters in tailing can be effectively increased, and suitable environments can be provided for plant growth; the rice husks and the ceramsite are matched with one another, the porosity of iron tailing soil can be improved, the hardening degree of the soil can be lowered, the tailing soil can keep in excellent gas-permeable and soft states for a long term, accordingly, the iron tailing soil improvement agent and the iron tailing soil improvement method are favorable for respiration of animals and plants in the soil, and the survival rate can be increased.
Owner:SHANDONG UNIV
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