The invention relates to a method special for selective
precipitation and
impurity removal of
phosphorus and
arsenic in a
sodium molybdate solution, and belongs to the technical field of
impurity removal. The
precipitation impurity removal method comprises the following steps: S1, adding strong acid into a pure
sodium molybdate solution to carry out acid
precipitation operation, adjusting the pH value of the solution to 2-3 by using the strong acid, and filtering to obtain a
molybdic acid solid; s2, dissolving a
molybdic acid solid and
magnesium oxide in water, adding a small amount of
phosphoric acid at the same time to ensure that the P concentration in the solution is 50-2000mg / l, and starting to carry out stirring reaction to obtain an impurity-removed solution; and S3, adding the impurity removal solution into the
sodium molybdate solution with high P and As, uniformly stirring, then adjusting the pH value to 8-10, carrying out a precipitation reaction, filtering after the reaction to obtain filter residues and a pure
sodium molybdate solution, enabling the pure
sodium molybdate solution to enter a rear working section for subsequent treatment, and simultaneously taking out a part of the pure
sodium molybdate solution to be used for preparing a new impurity removal solution. The method has the advantages of short impurity removal time, normal temperature and normal pressure, simple operation and easy industrialization.