1681 results about "Nitrate nitrogen" patented technology

The invention belongs to the technical filed of agricultural microorganisms, particularly relating to separate and screen Pseudomonas stutzeri YZN-001 for degrading ammoniacal nitrogen, nitrate nitrogen and nitrous nitrogen in water body and application. The screened Pseudomonas stutzeri YZN-001 of the invention is preserved in China Center for Type Culture Collection (CCTCC), with the preservation number being CCTCC NO:M 209107. The strain can effectively degrade ammoniacal nitrogen, nitrate nitrogen and nitrous nitrogen in water body within the range of 20-37 DEG C, has no toxicity to chub, has good degradation function on ammoniacal nitrogen in water body at normal temperature, the microorganism of the invention is inoculated for 72 hours, the degrading ratios to ammoniacal nitrogen in domestic sewage and aquaculture wastewater are respectively up to 83.10% and 61.38%.

The invention relates to aerobic denitrifying paracoccus denitrificans and application thereof. A bacterial strain provided in the invention is paracoccus denitrificans DN-3CGMCC No. 3658; the Paracoccus denitrificans can carry out aerobic denitrification by using nitrate nitrogen under both aerobic and oxygen-limited conditions and can also carry out heterotrophic nitrification-aerobic denitrification by using ammonia-N, and a total nitrogen removal rate on above mentioned occasions is greater than 90%. The paracoccus denitrificans provided in the invention has stable hereditary features, isapplicable to treatment of a variety of nitrogen-containing waste water and produces a good nitrogen removal effect.

A wastewater treatment process having improved solids separation characteristics and reduced biochemical oxygen demand (BOD) in the purified wastewater comprising the steps of: passing wastewater through a main aerobic biological oxidation zone and therein oxidizing a portion of the BOD a portion of the ammonia nitrogen content (NH3-N); passing the effluent from said aerobic biological oxidation zone to an aerobic/mixing zone and therein mixing said effluent with effluent from the anoxic/anaerobic zone; passing the effluent from said aerobic/mixing zone to a settling zone and therein separating purified wastewater having reduced BOD and suspended solids, and sludge containing suspended solids; passing a portion of the sludge formed in the settling zone and volatile acids to an anoxic/anaerobic zone and therein increasing the extracellular polymer content of said sludge, the release of phosphorus into solution and the reduction of nitrate nitrogen to molecular nitrogen gas; and recycling an effective amount of the effluent from said anoxic/anaerobic zone to said aerobic/mixing zone. In an alternative embodiment, a volatile acid is added to a zone to which no additional oxygen has been added that is in the flow path from the main aerobic biological oxidation zone or, alternatively, it may be added to the anoxic/anaerobic zone and the thus-treated effluent is passed to the aerobic/mixing zone wherein phosphate is removed from the effluent.

A wastewater treatment process providing nitrogen, phosphorus, biochemical oxygen demand (BOD) and suspended solids removal comprises the steps of: passing wastewater containing ammonia nitrogen, phosphate, BOD and suspended solids, said wastewater mixed with recycled activated sludge from a subsequent step, into a first anoxic zone therein reducing nitrate nitrogen from the recycled sludge to molecular nitrogen; passing effluent from the first anoxic zone to a first aerobic zone therein oxidizing at least a portion of the BOD and oxidizing at least a portion of the ammonia nitrogen to nitrate nitrogen; recycling a portion of the contents at the end of the first aerobic zone back to the first anoxic zone; passing the effluent of the first aerobic zone to a second anoxic zone; introducing volatile fatty acid such as acetic acid into the second anoxic zone therein releasing phosphorus into a liquid phase; passing effluent from the second anoxic zone including the volatile fatty acid to a second aerobic zone therein substantially absorbing phosphorus into biomass and removing and/or oxidizing ammonia nitrogen; passing effluent from the second anoxic zone to a final settling zone therein separating: (i) a purified wastewater having decreased nitrogen, phosphorus, BOD and suspended solids and (ii) a sludge containing suspended solids, phosphate and BOD; and recycling at least a portion of the sludge (ii) to the first anoxic zone. In another embodiment, at least a portion of the sludge (ii) is also recycled to the second anoxic zone. In yet another embodiment, the second anoxic zone is divided into a first section and a second section. In the first section, anoxic conditions are established and in the second section, volatile fatty acid is added after anoxic conditions have been established.

The invention relates to a method of removing nitrate in aquaculture water, relating to treat aquaculture water. The invention comprises a sulfur autotrophic denitrification and biodegradation polymer carbon source heterotrophic denitrification device, the invention is characterized in that: the sulfur autotrophic denitrification section and the biodegradation polymer carbon source heterotrophic section are series-connected from up to down according to the proportion of 1:1 to form a denitrifying device; after the integrated denitrifying device forms film, the aquaculture water enters from the water inlet of the lower part of the integrated denitrifying device, and flows through the filling layer of the sulfur autotrophic denitrification section from up to down to remove partial nitrate, the remained nitrate in the aquaculture water and the sulfate anion generated in the process of the sulfur autotrophic denitrification section enter the filling layer of the biodegradation polymer carbon source heterotrophic section, so as to remove the remained nitrate in the aquaculture water and also generate gaseous nitrogen, the reducing bacteria of the sulfate reduces the sulfate anion to hydrogen sulfur; the treated aquaculture water flows out from the water outlet of the lower part of the integrated denitrifying device; the gaseous nitrogen and hydrogen sulfur are exhausted from exhaust opening.

The invention discloses a preparation method and applications of a siderite-based nitrogen and phosphorus removal material. The preparation method is implemented through steps of crushing siderite ores, enabling the obtained ores to pass through a 40-mesh sieve, and adding a foaming agent into siderite ore powder in an appropriate proportion of the siderite ore powder, a binder and a pore-foaming agent or in an appropriate proportion of the siderite ore powder and a binder so as to obtain a porous granular material taking the siderite ore powder as a main body; and the porous granular material has the characteristics of high particle strength, high porosity, large specific surface area, large microbial load, and the like. The material is a microbial carrier, an anaerobic microorganism electron donor and a phosphorus removal adsorbent. The material is fed in a fixed bed to treat wastewater by way of filtering, and vaccinates nitrate-depended iron-oxidizing-bacteria-based anaerobic strain liquid, and under anaerobic conditions, microorganisms reduce nitrates into nitrogen by taking ferrous irons in siderite as electron donors, and the adsorption effect on phosphorus is enhanced. The material is mainly used for synchronously removing nitrate nitrogen and phosphates in wastewater.

The invention discloses an integrated pre-denitrification and denitrogenation biological filter sewerage treatment process. The integrated process is characterized in that: the process is realized by combining an anoxic denitrification biological filter and an aerobic nitrification biological filter in tandem, first, sewage with organic substances and ammonia nitrogen is mixed with part of effluent water of the aerobic nitrification biological filter which flows back to a water inlet end, then the sewage and the effluent water pass the anoxic denitrification biological filter together, and the organic substances in the sewage are taken as a carbon source by denitrifying bacteria adhesively growing on bio-ceramsite in the anoxic denitrification biological filter to reduce nitrate nitrogen from the return water of the aerobic nitrification biological filter into nitrogen gas, thus realizing denitrification function; and the effluent water of the anoxic denitrification biological filter flows to the aerobic nitrification biological filter, and a filter material in the aerobic nitrification biological filter is adhered with special growing aerobic decarbonization microbes and the growing denitrifying bacteria which further degrade the organic substances and the ammonia nitrogen from the anoxic denitrification biological filter, thus causing content indicators of the organic substances, the ammonia nitrogen, total nitrogen and the like in the effluent water of the aerobic nitrification biological filter to meet the discharge requirement.

The invention discloses a device and method for nitrogen and phosphorus removal treatment by denitrification on high-ammonia nitrogen anaerobic ammonia oxidation effluent and domestic sewage, belonging to the field of biological sewage treatment. The device comprises a high-ammonia nitrogen inflow water tank, an integrated partial nitrification and anaerobic ammonia oxidation reactor, a sedimentation tank, a domestic sewage inflow water tank, a denitrification nitrogen and phosphorus removal reactor and an effluent water tank sequentially connected in series. The method comprises the following steps: in the integrated reactor, effectively removing nitrogen of the high-ammonia nitrogen wastewater through the effect of partial nitrification and anaerobic ammonia oxidation; in the denitrification nitrogen and phosphorus removal reactor, performing anaerobic phosphorus release by phosphorus-accumulating bacteria by use of an organic carbon source in the domestic sewage, and performing hypoxia denitrification phosphorus removal by use of nitrate nitrogen in the anaerobic ammonia oxidation effluent; and finally, further absorbing phosphorus at the aerobic zone in accompany with the nitrification effect generated by the nitrification bacteria. According to the method, the nitrogen removal by anaerobic ammonia oxidation and phosphorus removal by denitrification are coupled into a biological nitrogen and phosphorus removal system for sewage, the nitrate nitrogen generated in the anaerobic ammonia oxidation process is effectively utilized, and the oxygen consumption and energy consumption are greatly reduced.

The invention provides a neural network based sewage disposal process optimal control method and aims to solve the problem of excessive energy consumption during a sewage disposal process. The sewage disposal process is a highly non-linear, time-varying and complicated process, and on the premise that effluent qualities meet the standard, reduction of operation energy consumption is much challenging. The method mainly includes two neural networks, wherein one neural network is used for establishing a sewage disposal process prediction model so as to achieve prediction of performance indexes, and the other neural network is used for real-timely optimizing control variable set values according to system states and predicted performance indexes. Finally, optimal control of dissolved oxygen concentration and nitrate nitrogen concentration is achieved, so that requirements of effluent qualities can met, and meanwhile, operation costs of the sewage disposal process can be effectively reduced.

The invention discloses a method for producing high-water solubility nitrophosphate fertilizer by phosphorite nitrolysis and calcium nitrate freezing. The high-water solubility nitrophosphate fertilizer is prepared from the processes of phosphorite nitrolysis, fluorine removal, calcium nitrate freezing separation, further removal of calcium in ammonium sulfate, ammonia liquor neutralization and deposition removal of impurities, and evaporation concentration and crystallization. Specially, the method for producing high-water solubility nitrophosphate fertilizer by phosphorite nitrolysis and calcium nitrate freezing comprises the following steps of 1, acidolysis, 2, fluorine removal, 3, calcium nitrate freezing crystallization, 4, double decomposition removal of calcium in ammonium sulfate,5, neutralization and deposition removal of impurities, 6, evaporation concentration and crystallization, and 7, phosphogypsum transformation. The high-water solubility nitrophosphate fertilizer prepared by the method has a dissolution rate great than or equal to 99.9% in water, wherein nitrate nitrogen is easy for be absorbed by drops, satisfies requirements of a few commercial crops, has a highutilization rate, and improves a crop yield by 8 to 25% and crop quality. The method reduces waste discharge, is environmentally friendly, can be utilized for structure adjustment and product upgradeand update of the traditional phosphorus chemical industry, and has good economic and environmental benefits.

The invention relates to a high salt-tolerant bacillus alitudinis with functions of heterotrophic nitrification-aerobic denitrification and phosphorous removal and application thereof to wastewater treatment. The bacillus alitudinis has strong high salt environment tolerance, grows well under a high-salt condition, and can metabolize by taking organic carbon as one and only carbon source and ammonia nitrogen as one and only nitrogen source; through the heterotrophic nitrification-aerobic denitrification, the ammonia nitrogen is directly converted into a gaseous product so as to achieve a denitrifying purpose; the bacillus alitudinis can also take nitrate nitrogen as one and only nitrogen source, the nitrate nitrogen is converted into a gaseous product through the aerobic denitrification; and under aerobic conditions inorganic phosphorus can be taken into a body and converted into a component of the body so as to realize a purpose of removing phosphorus in sewage. The bacillus alitudinis is applied to high-salt wastewater treatment, can achieve synchronization removal of nitrogen and phosphorus under a single aerobic condition, and provides a new way for solving a problem of biological removal of the nitrogen and phosphorus under the high-salt condition.

The invention discloses a system and method for treating municipal sewage through short-cut denitrification-anaerobic ammonia oxidation after short-cut nitrification-anaerobic ammonia oxidation and belongs to the field of sewage biological treatment. The system comprises a raw water tank, an organic matter removal and dephosphorization SBR reactor, a short-cut nitrification SBR reactor, an anaerobic ammonia oxidation granular sludge UASB reactor, a second regulating water tank and a short-cut denitrification-anaerobic ammonia oxidation UASB reactor. All functional floras are subjected to advantageous culture in different reactors according to respective growth characteristics, so that a sludge age contradiction between denitrification and dephosphorization is solved, and stability of the treatment system is enhanced; real-time control is applied to the short-cut nitrification SBR reactor to solve the problem that short-cut nitrification with a low ammonia and nitrogen level is hard to maintain stably; water discharged from the short-cut nitrification reactor and water discharged from the organic matter removal reactor are mixed to solve the problem that continuous flow half short-cut nitrification is hard to maintain; short-cut denitrification-anaerobic ammonia oxidation is used for further treatment of water discharged from the anaerobic ammonia oxidation reactor to solve the problem that nitrate nitrogen is generated during anaerobic ammonia oxidation.

The invention relates to a sewage double-biomembrane deep treatment technology comprising the steps: sewage enters an anaerobic tank, an anoxic tank and an oxygen maintaining tank after being pretreated by a grid and settled sand, and mud releases phosphorus in the anaerobic tank; the sewage is denitrified in a denitrification mode in the anoxic tank so as to remove most of organic matters; cilium biological fillers are arranged in the oxygen maintaining tank, biomembranes are attached to the cilium, absorb the phosphorus in excess and degrade the partial organic matters; the sewage enters a secondary sedimentation tank to carry out sedimentation treatment through the oxygen maintaining tank and then enters an aeration biological filter tank; granule biological fillers are arranged in the aeration biological filter tank, and the biomembranes are attached to granules, degrade the residual organic matters in the sewage and convert ammonia nitrogen into nitrate nitrogen; one part of the discharged water of the aeration biological filter tank flows back into the anoxic tank, and the other part is discharged; one part of the mud generated by the secondary sedimentation tank back flows into the anoxic tank, and the other part of the mud is discharged out of a system. The sewage double-biomembrane deep treatment technology has the advantages of investment saving, low operation cost, little land occupation and good treatment effect.

The invention relates to an environmental engineering and water treatment technology and aims to provide a self-sustaining type landscape restoration ecological floating island device. The device comprises floating beds, floating islands which consist of aquatic plants planted between the floating beds, photocatalysis ribbons, and aeration devices which supply power by using solar systems; and each photocatalysis ribbon comprises a horizontal loading main body which is submerged below a water surface, a plurality of holes for circulating water bodies are distributed at the bottom of each photocatalysis ribbon, a carrier material loaded with a photochemical catalyst is fixed on the surface of each photocatalysis ribbon, and an overflow weir is arranged at the periphery of each photocatalysis ribbon. Each aeration device comprises an aeration pipeline and a motor. The organic matter and nitrogen and phosphorus are removed from eutrophic water by combining a photocatalysis technology, an ecological floating island technology and a solar energy technology; nitrate nitrogen and ammonia nitrogen are converted into nitrogen by the photocatalysis technology simultaneously; the accumulation of nitrogen pollutants is reduced, and nitrate is prevented from being converted into nitrite or ammonium; and dissolved oxygen in the water body is increased by using the aeration devices, and the self-purification capacity of the water body is improved, so the aim of restoring the eutrophic water well is fulfilled.

This invention discloses apparatus and method for biological denitrification of wastewater by reinforced inner source reverse nitrification. The method solves the problem of low denitrification efficiency, high operation energy consumption, large floor area, and high sludge productivity faced by present wastewater treatment techniques. The method comprises: introducing wastewater from inlet pipe into grid and sand-settlement pool for treatment, mixing with returned sludge from the precipitation pool, and sending into a hydrolysis and acidification pool to reduce sludge and raise wastewater biochemical capacity. The hydrolysis and acidification liquid is used as the carbon source for anaerobic pool denitrification to reinforce the inner source reverse nitrification process in the anaerobic pool. Organic matters in wastewater are completely removed in the aerobic pool, and ammonia and nitrogen are completely converted into nitrate nitrogen by nitrobacteria. Sludge and water are separated in the precipitation pool, the supernatant is discharged via the outlet pipe, and residual sludge is returned to the hydrolysis and acidification pool. The whole system discharges sludge from the hydrolysis and acidification pool. This invention has such advantages as low energy consumption, high efficiency, low investment.

The invention discloses a process for treating nitrogen-containing wastewater by ion exchange and reclaiming ammonium nitrate, and belongs to the technical field of environmental protection and wastewater treatment. The process is characterized in that: a strong acid cation exchanger and a weak alkali anion exchanger are connected in series to realize denitrification of the nitrogen-containing wastewater of a nitrogen fertilizer plant; the process is used for treating the high-concentration ammonia nitrogen and median-concentration nitrate nitrogen containing wastewater of the nitrogen fertilizer plant; strong acid cation exchange resin and weak alkali anion exchange resin are regenerated by adopting nitric acid and aqueous ammonia respectively; and the regenerated waste liquid ammonium nitrate is evaporated and concentrated to reclaim the ammonium nitrate. Compared with the traditional wastewater denitrification method, the process can remove ammonia nitrogen and nitrate nitrogen from the wastewater at the same time, reclaim the ammonium nitrate and recycle production water, does not produce secondary pollution, reclaims products from the pollutants, has obvious environmental benefit and economic benefit, and is a new path for treating the high-concentration ammonia nitrogen and median-concentration nitrate nitrogen containing wastewater of the nitrogen fertilizer plant.

In allusion to the characteristics that in a sewage treatment process, the effluent water quality cannot reach the standard, the energy consumption is relatively high and the like, the invention provides a multi-objective real-time optimization control method for the sewage treatment process, by which optimization control over concentrations of dissolved oxygen SO and nitrate nitrogen SNO are achieved in the sewage treatment process. According to the optimization control method, an established energy consumption model and an established effluent water quality model, which are based on radial basis functions, are used as optimized objective functions, the optimized objective functions are treated via a multi-objective particle swarm algorithm to obtain optimized set values of the dissolved oxygen SO and the nitrate nitrogen SNO, and tracking control is performed on the optimized set values of the dissolved oxygen SO and the nitrate nitrogen SNO through a fuzzy neural network. According to the optimization control method, the problem of multi-objective real-time optimization control over the sewage treatment process is solved, the energy consumption is reduced on the basis that the effluent water quality is ensured, and high-efficiency and stable operation of a sewage treatment plant is promoted.

The invention discloses a metal element improved biochar-based nitrate radical adsorbent and a preparation method thereof. Straws are used as raw materials, and metal ions are impregnated, pyrolyzed and washed under certain conditions, so a metal ion improved cbiochar is prepared. According to the metal element improved biochar-based nitrate radical adsorbent and the preparation method thereof disclosed by the invention, by using adsorption research on nitrate radical waste water and comparing the adsorption effect of the biochar before and after improvement, the improved biochar prepared by the preparation method disclosed by the invention has good adsorption effect for potassium nitrate, wherein Mg<2+> improved wheat straw biochar has optimal adsorption effect for nitrate nitrogen; compared with the unmodified biochar, the Mg<2+> improved biochar prepared under the optimizing conditions has the advantages that the adsorption performance is improved by 10 times, and the adsorption equilibrium can be realized in a shorter time. The modified biochar adsorbent is a green adsorbent with application potential and can be used for effectively removing the nitrate nitrogen in a water body; besides, the effects of fixing carbon, reducing discharge and relieving the non-point source pollution are achieved.

The invention discloses a polymorphic microorganism aggregate autotrophic nitrogen removal integrated device which is provided with a reaction tank, wherein the reaction tank is internally filled with microorganism aggregates and is provided with a water decanting device with a vertical push rod, fixed packing, an aerator, an online pH value detector, an online dissolved oxygen detector, an online ammonia nitrogen detector and an online nitrate nitrogen detector; the reaction tank is connected with a water inlet pipeline, a water outlet pipeline, a sludge outlet pipeline, an air pipeline, an overflow pipeline, a water inlet pump, a blast blower and an electrically operated valve; the reaction tank is also provided with an online gas flowmeter and a PLC (Programmable Logic Controller); the online gas flowmeter, the online pH value detector, the online dissolved oxygen detector, the online ammonia nitrogen detector and the online nitrate nitrogen detector are all connected with the PLC through signals. An operation method comprises the steps: (1) inoculating sludge; (2) carrying out habituated culture; (3) starting partial nitrification reaction; (4) inoculating anaerobic ammonium oxidization granular sludge; (5) proliferating the anaerobic ammonium oxidization granular sludge; (6) culturing an anaerobic ammonium oxidization bacterium biological film; (7) stably operating the autotrophic nitrogen removal integrated device. The polymorphic microorganism aggregate autotrophic nitrogen removal integrated device is suitable for denitrification treatment of medium and high concentration ammonia nitrogen sewage, simple in structure, high in degree of automation, good in denitrification effect and low in operation cost.

The invention discloses an electrochemical reactor for processing nitrogenous organic wastewater, and an application and a processing method thereof, and belongs to the field of processing nitrogenous organic wastewater. The device comprises a reaction container, a power supply, a gas outlet pipe, a water outlet pipe, a water outlet pipe valve and a water inlet system, and further comprises a packing material, a negative plate and a positive plate, wherein the packing material is formed by mixing active carbon and magnet particles; the negative plate is connected with the negative electrode of the power supply; the negative plate is a silicon dioxide plate loaded copper-palladium coating electrode, and the coating material consists of Pd and Cu at a mass ratio of 6: 1; and the positive plate is a digital subtraction angiography (DSA) oxide coating electrode Ti/IrO2-PtO2. The reactor is a batch-type operation three-dimensional electrode reactor which adopts a mixture of active carbon particles and magnet particles with similar diameter as the packing material, and has the functions of efficiently removing nitrate nitrogen, ammonia nitrogen and COD (chemical oxygen demand), and is low in energy consumption; and the reactor is capable of achieving a purpose of removing nitrogen and COD in the nitrogenous organic wastewater.

The invention discloses an organic-inorganic mixed fertilizer containing alginic acid and a production method thereof. The organic-inorganic mixed fertilizer containing alginic acid comprises the following raw materials in parts by weight: 45-50 parts of carbamide, 18-20 parts of ammonium phosphate, 16-18 parts of potassium sulphate, 6-8 parts of seaweed fermentation residues, 8-10 parts of a seaweed synergist, 6-8 parts of a humic acid synergist, 3-5 parts of an EDTA chelated-state microelement fertilizer, 5-7 parts of plant ash, 3-5 parts of modified magnesia and 0.2-0.3 part of gibberellins. High-quality and high-effect synergist products are added into the technical field of value addition of the fertilizers, so that the high urease inhibition effect is achieved; the conversion from ammonium nitrogen to nitrate nitrogen is controlled; the utilization rate of the fertilizer is increased; the root growth of the crops is facilitated; the content of nutrient in the fertilizer is almost not influenced; the content of nitrogen in the value-added carbamide is not smaller than 30%; the organic-inorganic mixed fertilizer is obvious in synergistic effect and safe and effective in use; organic components are used for increasing the utilization rate of the fertilizer; inorganic components are used for improving the water-retaining property of the fertilizer; the action time of the fertilizer effect is prolonged; the absorption of nutrients in the crops is facilitated; the quality of agricultural products is improved.

The invention discloses a method for treating organic nitrogen in sewage. The method comprises the following steps of: treating sewage by using a sequencing batch biofilm reactor, decomposing macromolecular organic nitrogen into micromolecular organic nitrogen under the coexistence of anaerobic, anoxic and aerobic conditions, removing the micromolecular organic nitrogen by using the degradation of microbes, and simultaneously removing ammonia nitrogen and nitrate nitrogen through short-cut nitrification and denitrification and anaerobic ammonium oxidation; and treating by using a coagulation-microfiltration method, precipitating to remove bacteria, suspended solids (SS) and other nitrogen-containing substances by adding a coagulant, and removing refractory macromolecular organic nitrogen such as humic acid, fulvic acid and the like through filtration of a hollow fiber microfiltration membrane to reduce the total amount of the organic nitrogen in the sewage. The invention also discloses a device for implementing the treatment method.