The invention belongs to the technical field of
alumina production. The invention provides a deep purification process of a
sodium aluminate solution. The deep purification process comprises the steps of pretreatment,
quaternary synergistic
impurity removal, first-stage
solid-liquid separation,
oxalic acid selective decalcification, second-stage refined
filtration and residue treatment. According to the method, a four-element synergistic
impurity removal
system of
barium salt,
sodium sulfide, quick
lime and a desiliconizing agent is innovatively constructed, impurities such as
silicon, iron,
phosphorus,
titanium,
vanadium,
copper, lead and
zinc ions and organic matters in the
sodium aluminate solution are synchronously and deeply removed through function division and synergistic interaction,
calcium ions are selectively removed through
oxalic acid, and finally the high-purity
sodium aluminate solution is obtained for producing high-purity aluminum
oxide. According to the method, the problems of poor
impurity removal pertinence, high impurity residue and large secondary
pollution risk of a traditional
single agent are solved, the removal rate of various impurities is larger than or equal to 99%, Ca in the purified solution is smaller than or equal to 0.001 g / L, the method adapts to the
Bayer process and
sintering process aluminum
oxide production process, the purification efficiency is high, the process is compact, and the method is
environmentally friendly and economical.