The invention provides a process method for preparing
sulfur from
mirabilite, and relates to the technical field of
sulfur production and carbon emission reduction, and the process method comprises the following steps: with C or CO as a fuel, preheating
mirabilite, adding the preheated
mirabilite into a three-blade closed reduction
rotary kiln, and calcining at 900-1050 DEG C to obtain liquid Na2S; enabling the liquid or
solid Na2S calcined in the step S1 and
solid CaCO3 to enter a multi-phase reactor for reaction; performing
solid-liquid separation on the
slurry after the reaction in the step S2, wherein the filter residue is CaS and the filtrate is a Na2CO3 solution; the
gas phase obtained after
calcination in the step S1 enters a CO2
trapping system, and then
flue gas is discharged after being subjected to desulfurization,
denitrification and dust removal; the filter residues obtained in the step S3 and the CO2 captured in the step S4 are fed into a
supergravity carbonization reactor, the obtained solid phase is CaCO3, and the obtained
gas phase is H2S; the solid-phase CaCO3 is returned to the multi-phase reactor of S2 for recycling; h2S enters a Claus
reaction system, and finally a
sulfur product is obtained. According to the method, sulfur in the low-quality mirabilite is converted into sulfur; in the production process, CaCO3 can be recycled only through one-time feeding, and resources are saved.