The invention relates to a treatment device and a
recovery method for zero
sludge resource recovery of heavy
metal wastewater, the heavy
metal wastewater which mainly contains
copper is coagulated and sedimented chemically, after that,
sludge with high-concentration
copper ions is formed by concentration, the heavy
metal sludge is dipped in mixed liquid of
sulfuric acid and
hydrogen peroxide, thereby obtaining impregnation liquid with the high-concentration
copper ions;
ammonia water is further used for adjusting the pH value of the impregnation liquid, the selective impregnation is carried out,
ammonia copper solution and residues which are rich in iron or
aluminium can be obtained after the
solid-liquid separation, the
ammonia copper solution is done with the procedure of heating and ammonia
distillation, then
copper oxide and ammonia with very high utilization values can be obtained by
recovery, wherein, the generated residues are recovered to be directly added in a
rapid mixing tank during the
wastewater treatment process as a coagulating agent, the harmless treatment is carried out by wet treatment, or the
resource recovery is carried out by using the dry
smelting method to recover the iron or the
aluminium, and the generated ammonia during the procedure of heating and ammonia
distillation can be recovered and reused. The purposes of zero sludge,
zero waste and
zero emission output can be achieved.