142 results about "Co pyrolysis" patented technology

The invention relates to a silicon-carbon composite material with a porous structure and a preparation method thereof, and the silicon-carbon composite material with the porous structure comprises an N / P co-doped porous carbon skeleton with micropore, mesopore and macropore channel networks, and amorphous or low-crystalline nanometer silicon particles which are uniformly loaded in the porous carbon skeleton and have the average particle size of 15-40nm, the mass percent of silicon in the composite material is 40-60%, and good interface bonding is formed between silicon and carbon. The preparation method mainly comprises the following steps: firstly, preparing an N / P co-doped porous carbon skeleton through a template method in combination with high-temperature carbonization and N / P source co-pyrolysis; and hydrolyzing an organic silicon source in the carbon skeleton to form silicon dioxide, and performing low-temperature metal thermal in-situ reduction to obtain the nano-silicon loaded composite material. Through a unique porous carbon skeleton design and a precise in-situ composite strategy of nano silicon, the prepared material shows high specific capacity, high initial coulombic efficiency and excellent cycling stability and rate capability when being used as a negative electrode of a lithium ion battery.

The invention relates to the technical field of solid waste resource utilization, and particularly discloses a waste incineration fly ash resource treatment method which comprises the following steps: firstly, efficiently removing dioxin in fly ash in a manner of adding a vanadium-cerium-loaded charcoal catalyst and co-pyrolyzing with fluidized bed combustion ash; the method comprises the following steps: preparing fly ash from fly ash, washing the fly ash with micro-nano bubble water containing carbon dioxide for dechlorination, adding an iron-manganese-silicon biochar adsorbent after dechlorination to adsorb heavy metals in the fly ash, sintering the fly ash after adsorption and fly ash under an alkaline condition to further stabilize residual soluble chlorine and heavy metals in the fly ash, and finally, recycling the residual soluble chlorine and heavy metals in the fly ash. And the treated fly ash and cement are processed into cement building blocks with good mechanical properties, so that resource utilization of the waste incineration fly ash is realized.

The invention relates to the technical field of supercapacitors, in particular to an alkali-activated solid-waste-based supercapacitor and a preparation method thereof.The preparation method comprises the steps that industrial solid waste and fiber forestry and agricultural residues are subjected to co-pyrolysis to form organic-inorganic composite solid waste gelling powder, an alkali activator and a functional additive are added to prepare alkali-activated slurry, and the alkali-activated slurry is prepared; pouring, molding and curing to obtain an alkali-activated solid waste-based electrolyte substrate; the method comprises the following steps: performing high-temperature pyrolysis, activation and the like on granular agricultural and forestry wastes to prepare a carbon-based composite conductive material, and preparing a biochar electrode plate; the preparation method comprises the following steps: taking PVDF as a raw material, bonding and curing the PVDF and the raw material, immersing the PVDF and the raw material into a KOH solution containing a PVA thickener, inserting a glass fiber diaphragm, and regulating and controlling the use amount of PVDF and other binders and a solvent system to optimize slurry viscosity and film forming uniformity so as to obtain an electrode film with mechanical flexibility and interface adhesive force; the composite electrode forms a stable composite interface in the process of being in contact with an alkali-activated electrolyte interface, and the phenomena of interface aging and capacitance attenuation caused by mismatching between the electrode and the electrolyte in a traditional cement-based system are effectively avoided.

The invention discloses a sludge, bagasse and calcium oxide co-pyrolysis biochar as a soil additive, and a preparation method and application thereof, and belongs to the technical field of environmental restoration. Sludge biochar synergistically modified by bagasse and calcium oxide is used as a soil additive, calcium oxide is introduced for catalytic co-pyrolysis through the synergistic effect of bagasse and calcium oxide, and sludge-bagasse-calcium oxide biochar is prepared; the optimization effect of the sludge-bagasse-calcium oxide biochar in heavy metal contaminated soil remediation is evaluated through heavy metal occurrence form analysis, ecological risk assessment and soil remediation effect experiments. According to the sludge-bagasse-calcium oxide biochar prepared by the method, the fixing capacity of the biochar on heavy metals and the fixing efficiency of the heavy metals in soil are improved, and the physicochemical properties and fertility characteristics of the heavy metal contaminated soil are improved; the characteristics of the sludge-bagasse-calcium oxide biochar for well fixing heavy metals and improving soil properties are exerted, the ecological risk is reduced, the physicochemical properties and fertility characteristics of the soil are improved, and the application of a heavy metal contaminated soil remediation process is optimized.

The invention relates to the field of waste resource utilization, in particular to a method for preparing biochar through co-pyrolysis of coal-based solid waste and biomass. Through co-pyrolysis of the coal-based solid waste and the biomass, the energy conversion efficiency can be effectively improved. Compared with independent pyrolysis, the interaction between the volatile components of the biomass and the semicoke of the coal in the co-pyrolysis process can promote the pyrolytic reaction, and the heat value of the pyrolysis product is increased, so that the utilization efficiency of energy is improved. According to the method disclosed by the invention, the coal-based solid waste and the biomass are subjected to co-pyrolysis, so that the environmental pollution caused by independently treating the waste is reduced. In the co-pyrolysis process, volatile components of the biomass can catalyze pyrolysis of coal, formation of coke is reduced, meanwhile, emission of pollutants such as CO2, SOx and NOx is reduced, release of chemical components is reduced, and environment friendliness is achieved.

The invention relates to a calcium-based difunctional composite material and a preparation method and application thereof, the calcium-based difunctional composite material is applied to pollution control in a sludge-low-rank coal co-pyrolysis process, the calcium-based difunctional composite material is composed of Ca2Fe2O5 and an adsorptive material, and the mass ratio of Ca2Fe2O5 to the adsorptive material is 1: 1. According to the calcium-based bifunctional composite material, the fixation rate of sulfur in pyrolytic carbon is remarkably increased, conversion of heavy metal to a more stable form is facilitated, and the leaching capacity and potential ecological risks of the heavy metal are remarkably reduced.

The invention discloses a preparation method of a spherical hard carbon negative electrode material suitable for a sodium ion battery, and relates to the technical field of electrode materials, the preparation method comprises the following steps: (1) mixing acetic acid metal salt and a first acid solution in an aqueous solution, and stirring until the solution is transparent; (2) sequentially adding starch and a second acid solution into the transparent solution, and heating and stirring until uniformly dispersed suspension slurry is obtained; (3) carrying out spray drying on the suspension slurry to obtain uniformly mixed starch / acetic acid metal salt powder; (4) performing carbonization treatment, washing and drying on the powder in sequence to obtain a hard carbon precursor; and (5) calcining the hard carbon precursor to obtain the spherical hard carbon negative electrode material. By adopting an acetic acid metal salt co-pyrolysis method, foaming of the starch in the pyrolysis process can be inhibited, the original form and structural integrity of the material are kept, more closed pore volumes are shown, and the energy storage capacity and the cycling stability of the hard carbon material are remarkably improved.

The invention discloses a method for preparing a sodium-ion battery hard carbon negative electrode material by co-pyrolysis of biomass and plastic and application of the sodium-ion battery hard carbon negative electrode material. The preparation method comprises the following steps: mixing biomass powder and plastic powder, adding the mixture into a phosphate solution, and stirring for 0.2-2 hours; drying the obtained mixture, and carbonizing in an inert atmosphere; and carrying out acid pickling on the obtained carbonized product, cleaning with deionized water, and drying to obtain the sodium-ion battery hard carbon negative electrode material. According to the invention, biomass and plastic are used as raw materials, an inorganic phosphate solution is used as an aperture regulator, and in the heating carbonization process, biomass and plastic co-pyrolysis greatly improves the carbon yield of pure biomass raw materials. Compared with other methods for preparing hard carbon by using biomass materials, the method is completed in one step, further modification post-treatment is not needed, and the method has the advantages of being simple, practical, low in cost and high in performance.

The invention relates to the technical field of agricultural resources and environment, and particularly discloses a rapid fertilization improvement method for newly-reclaimed red soil dry land. The method systematically integrates the core steps of soil diagnosis aluminum toxicity passivation, composite conditioner deacidification, two-stage deep ploughing, organic and inorganic biological synergistic fertilization, soil moisture content regulation and control, earth surface covering, green manure planting and returning to the field and the like. The applied composition comprises a soil composite conditioner, a charcoal-based organic fertilizer and a specific functional microbial agent, wherein the soil composite conditioner comprises modified oyster shell powder, a calcium magnesium phosphate fertilizer, humic acid, polyglutamic acid and the like. The method relates to key processes such as temperature programming calcination modification of raw materials, co-pyrolysis and composite granulation of the materials and the like. The method can synchronously and quickly improve the chemical and biological properties of soil and optimize the physical structure of a plough layer, and has the advantages of high improvement targeting, synergistic interaction of all steps, high fertilizing speed and lasting effect; in addition, the method has the advantages of being coherent in process, high in resource utilization efficiency and easy to implement on a large scale.

The invention discloses a method for strengthening a co-pyrolysis synergistic effect based on hydrothermal-forming pretreatment. The method comprises the following steps: 1, grinding and screening raw materials, namely oil-rich coal and lignin, and then drying; 2, uniformly mixing with a CaO catalyst, and carrying out hydrothermal pretreatment to obtain a mixture to be formed; 3, mixing the to-be-formed mixture with deionized water, and carrying out double-roller forming treatment to obtain a formed substance; 4, carrying out a co-pyrolysis reaction on the molded product to generate solid semi-coke and a pyrolysis oil gas product; and 5, condensing and separating the pyrolysis oil-gas product to obtain pyrolysis tar and pyrolysis gas, and collecting solid semi-coke. According to the invention, the CaO catalyst, the hydrothermal pretreatment and the double-roller forming are utilized to synergistically improve the yield and the quality of the co-pyrolysis product of the oil-rich coal and the lignin, so that the co-pyrolysis synergistic effect of the oil-rich coal and the lignin can be enhanced to improve the yield of high-value components, and the emission of greenhouse gases and pollutants in the pyrolysis process can be reduced; and high-value utilization of oil-rich coal and waste lignin resources is realized.

The invention discloses an oil-containing solid waste and plastic co-pyrolysis method based on carbon residue in-situ catalysis, and belongs to the technical field of solid waste resource utilization. The method comprises the following steps: pre-treating and mixing oil-containing solid waste and waste plastic, and co-pyrolyzing to prepare primary carbon residue and pyrolysis steam; performing acid dipping or oxidation modification on the primary carbon residue to obtain modified carbon residue, performing in-situ catalytic reforming on the pyrolysis steam and the modified carbon residue under the condition that the temperature is not lower than the final pyrolysis temperature, performing fractional condensation separation on a product to obtain pyrolytic oil and hydrogen-rich gas, and performing high-valued preparation on a functional material from the secondary residue. According to the method, the problems that a catalyst needs to be additionally added and the product quality is low in the existing co-pyrolysis technology are solved. No additional catalyst is needed in the whole process, the process cost is reduced, and related secondary pollution of the catalyst is avoided; product quality improvement is effectively achieved, two kinds of solid waste are treated synchronously, and remarkable environmental protection and economic and social benefits are achieved.

The invention discloses an ammonia nitrogen adsorption material for soil improvement as well as a preparation method and application thereof. The preparation method comprises the following steps: firstly, mixing straw chippings with zeolite powder to obtain a mixed raw material; then putting the mixed raw material into a high-temperature tubular furnace for co-pyrolysis to obtain a composite co-pyrolysis product; and finally, adding the composite co-pyrolysis product into a NaOH solution, uniformly stirring, oscillating and dipping, taking out, repeatedly cleaning with deionized water to be neutral, and drying in a drying oven to prepare an alkali modified product, namely the ammonia nitrogen adsorption material. According to the application, the material adsorbing NH4 < + >-N is added into soil and is used for improving soil performance, so that germination and growth of plants are promoted; the composite material with high NH4 < + >-N adsorption capacity is prepared through co-pyrolysis of the zeolite and the straw, the composite material adsorbing NH4 < + >-N serves as a soil conditioner to be recycled, the adsorption performance of the biochar material to NH4 < + >-N is improved by supplementing the zeolite, and meanwhile the natural loose and porous mineral property of the biochar material also has the feasibility of soil improvement.

The invention discloses a pyrolysis efficiency prediction method based on an XGBoost model and a simulated annealing algorithm, and the method comprises the steps: collecting sample data, the data comprises data which does not contain the yield of hexane insoluble substances under the same mixing proportion and data which contains the yield of hexane insoluble substances under the same mixing proportion, the difference value of the two is the difference value of the yields of the non-hexane-containing insoluble substance and the n-hexane-containing insoluble substance. According to the method, a polynomial linear regression model is established, a plurality of independent variables are quantified, the influence of the independent variables on dependent variables is studied, a regression equation is made, a result is predicted, and through the fitted regression equation and curve, which pyrolysis products have the most obvious interaction effect between the sample weight and the mixing ratio, and which pyrolysis products have the most obvious mixing ratio are specifically analyzed. And based on the fitted regression formula and the characteristics and composition of the co-pyrolysis product, establishing an optimization model by using a simulated annealing algorithm, and solving the co-pyrolysis mixing proportion so as to improve the product utilization rate and the energy conversion efficiency. And searching a global optimal solution in a large-scale search space through an optimization algorithm.

The invention relates to a biochar-loaded nano zero-valent iron material as well as a preparation method and application thereof. The biochar loaded nano zero-valent iron material comprises biochar and nano zero-valent iron particles uniformly loaded on the surface and in pore channels of the biochar; the nano zero-valent iron particles have a core-shell structure; the biochar loaded nano zero-valent iron material is prepared by mixing biomass powder and iron mud powder and then pyrolyzing the mixture under a high-temperature condition. The biochar loaded nano zero-valent iron material is mixed with organic contaminated soil in situ, and the mixture is left to stand, so that organic pollutants can be degraded. Compared with the prior art, the biochar-loaded nano zero-valent iron material has the advantages that biomass and treated waste iron mud are subjected to co-pyrolysis reaction, so that the biochar and zero-valent iron are fully combined, and a unique porous structure and a core-shell structure are formed; and finally, in-situ efficient remediation of the new pollutant perfluorinated compound of the soil system is realized.

The present invention belongs to the technical field of bioporous carbon preparation, and discloses a method for preparing multi-stage activated waste fruit and vegetable peel bioporous carbon and its application. Through the multi-stage steps of ultrasonic impregnation of waste fruit and vegetable peels with metal salts, initial carbonization activation, ultrasonic impregnation mixing, and co-pyrolysis activation of etchants and phosphides, a bioporous carbon with an ultra-high specific surface area (3149 m 2 / g), macropore volume (1.76cm 3 / g) of PBC. This represents 102.7% of the currently patented maximum specific surface area. Furthermore, the PBC significantly improves its adsorption performance for VOCs (represented by acetone and n-hexane vapor), reaching 1046 mg / g and 760 mg / g, respectively, representing increases of 138% and 132%, and exhibits excellent recyclability. This invention truly transforms waste into treasure, improving energy efficiency and possessing significant economic and social benefits.

This invention provides an intelligent optimization method and system for co-pyrolysis feedstock ratio, relating to the field of data processing technology. The method includes: acquiring feedstock data; constructing a co-pyrolysis reaction characterization feature dataset under different ratio conditions based on the feedstock data, wherein the co-pyrolysis reaction characterization features include multi-scale reaction features and reaction trajectory features; constructing a kinetic feature dataset based on the reaction trajectory features; constructing a causal network for the co-pyrolysis feedstock ratio based on the co-pyrolysis reaction feature dataset and the kinetic feature dataset; constructing a causal constraint reinforcement learning environment based on the causal network; determining a co-pyrolysis feedstock ratio optimization strategy using a temporal difference reinforcement learning algorithm based on the causal constraint reinforcement learning environment; evaluating the reversibility of the co-pyrolysis feedstock ratio optimization strategy to determine the final strategy; and executing the final strategy.

The invention relates to an in-situ and ex-situ catalytic pyrolysis device with a movable heating area and a pyrolysis method. The in-situ and ex-situ catalytic pyrolysis device comprises a rack; the reaction tube is axially and horizontally arranged on the rack; the left end of the reaction tube is communicated with a nitrogen cylinder through a rotary joint, a flow meter and a pressure reducing valve; the first end of the three-way pipe is connected with the right end of the reaction pipe through a rotary joint, the second end of the three-way pipe is connected in series with the first condenser and the first gas storage bag through a first stop valve, and the third end of the three-way pipe is connected in series with the second condenser and the second gas storage bag through a second stop valve; the tubular heating furnace is horizontally arranged on the rack in a sliding manner along the axial direction of the reaction tube, and a first heating area and a second heating area which are different in temperature are arranged in the tubular heating furnace; according to the device, on the basis that the in-situ catalytic reaction and the ex-situ catalytic reaction are carried out in the same device, the influence of the heating rate on the rapid pyrolysis of the raw materials is avoided, the full contact between different raw materials in the co-pyrolysis process and the maximum production of target products are ensured, and a catalyst evaluation function is also considered.

The application discloses a method for preparing biofuel by low-temperature dechlorination of waste PVC and coupling biomass co-pyrolysis, which comprises the following steps: drying, crushing and screening waste PVC, and then performing low-temperature dechlorination in an inert atmosphere, wherein the carrier gas is inert gas, the dechlorination temperature is 340-380 DEG C, the dechlorination time is 20-40 min, and dechlorinated PVC is obtained; crushing and drying the dechlorinated PVC, and then mixing the dechlorinated PVC with biomass at a mass ratio of 0.1-10:1, and then heating and pyrolyzing at 500-700 DEG C for 20-40 min to obtain biofuel. The method achieves good dechlorination effect through step-by-step pyrolysis, and improves the quality of biofuel; the method has a simple process flow, does not need to add any catalyst and adsorbent, and has a good industrial application prospect.

The invention relates to the technical field of sewage treatment, in particular to a manganese oxide modified red mud-biochar magnetic adsorbent and a preparation method thereof. According to the method, magnetic red mud-biochar is prepared from red mud and biomass through co-pyrolysis, KMnO4, MnSO4 and the red mud-biochar are mixed, and the red mud-biochar is modified through generated manganese oxide in a co-precipitation mode. According to the method, manganese oxide can be uniformly loaded on the surface of the magnetic red mud-biochar composite material, so that the removal capacity on ammonia nitrogen and Mn < 2 + > is improved, and meanwhile, the raw material cost of magnetization modification is reduced; the adsorbent can be quickly separated and recycled, has good cyclic recycling performance, and provides a novel functional material which is green, low in cost, simple and convenient to operate, excellent in performance and environment-friendly for industrial wastewater, agricultural non-point source pollution and urban sewage treatment.

The present application relates to the technical field of environmental protection and resource comprehensive utilization, and is an oil and gas composition and a preparation method thereof, wherein the oil and gas composition is prepared according to the following steps: first, a required amount of oil sand and oil-containing waste white clay are crushed, dried and then uniformly mixed to obtain a mixture; then, the mixture is co-pyrolyzed in an oxygen-free environment to obtain the oil and gas composition, wherein the oil and gas composition comprises pyrolysis gas and clean fuel oil. The present application obtains pyrolysis gas and clean fuel oil by co-pyrolyzing oil sand and oil-containing waste white clay, the raw materials are reasonably matched, sulfides in the oil sand react with oxides in the residue of the oil-containing waste white clay, the generation of sulfides is reduced, the porous structure of the waste white clay enhances the diffusion efficiency of pyrolysis volatiles, inhibits secondary cracking and coking, improves the quality of oil products, co-pyrolysis effectively reduces the oil content of the residue, and no other catalyst is needed, thereby realizing efficient energy recovery, low-energy-consumption operation, harmless and resource utilization of solid waste.

The present invention discloses a method for preparing upgraded tar by co-pyrolysis of lignite and waste plastic (PE). The method comprises the following steps: pre-treating the raw materials lignite and waste plastic (PE), uniformly mixing a certain amount of the treated lignite with the waste plastic (PE) in a mass ratio of 7:3 to obtain a lignite / waste plastic (PE) mixed sample, and adding the sample to a fixed-bed pyrolysis reactor; heating the lignite / waste plastic (PE) mixed sample in the fixed-bed pyrolysis reactor to 440-540°C under an N2 atmosphere for pyrolysis reaction; after the reaction is completed, the gaseous product is passed into a spherical cold trap filled with n-hexane solvent, the spherical cold trap being immersed in an ice-salt bath at 0-5°C to capture the pyrolysis liquid product; filtering the obtained pyrolysis liquid product to remove impurities, and then rotary evaporating to remove the n-hexane solvent to obtain upgraded tar. This method not only achieves the synergy of the pyrolysis processes of the two, but also increases the PE content in the raw materials to 30%, and most importantly, improves the quality of the tar and pyrolysis gas.

The invention discloses a preparation method of a porous capacitor material rich in heteroatom doping. The preparation method comprises the following steps: uniformly mixing lignocellulose biomass and microalgae, and then carrying out a co-pyrolysis carbonization reaction; and carrying out activation and plasma doping modification on the co-pyrolysis biochar prepared by the co-pyrolysis carbonization reaction. According to the method disclosed by the invention, the microalgae can fully realize self-doping of a nitrogen element, and the lignocellulosic biomass provides a rich carbon-based framework, so that the prepared biochar contains more void structures and nitrogen-containing functional groups; meanwhile, the lignocellulose biomass and microalgae co-pyrolysis charcoal are further subjected to low-temperature plasma doping modification, so that the amount of heteroions introduced to the surface of the co-pyrolysis charcoal is synergistically increased, a certain defect structure is further formed on the surface, and an oxidation-reduction reaction is facilitated; the co-pyrolysis biochar modified by microalgae and NH3 has the lowest contact resistance and the most excellent double-electric-layer capacitance characteristic, and the specific capacitance reaches up to 216 F / g.

The application discloses a kind of photothermal synergic catalysis co-pyrolysis system and method of marine organic solid waste, method includes the following steps: waste fishing net, plastic garbage and seaweed are crushed and mixed uniformly according to mass ratio (2-4):(3-5):(1-3);Mixed material and multifunctional composite photocatalyst prepared by seaweed are sent into moving bed reactor according to mass ratio (10-20):1, under the condition of concentrated solar energy leading, electric heating auxiliary, continuous co-pyrolysis is carried out;Pyrolysis product is separated by three-stage condensation to obtain heavy oil, light oil, water and gas.The method realizes the green cycle of "waste treatment", the catalyst cost is low, the degree of system intelligence is high, and provides an efficient, environmentally friendly, economically feasible innovative path for the resource utilization of marine organic solid waste.

The invention provides co-pyrolysis biochar as well as a preparation method and application thereof, and relates to the technical field of solid waste recycling. The preparation method comprises the following steps: drying biogas residue and straw, and crushing to respectively obtain biogas residue powder and straw powder; the biogas residue powder and the straw powder are mixed for pyrolysis, and co-pyrolysis biochar is obtained. According to the invention, biogas residue and straw produced by anaerobic digestion of kitchen waste are used as raw materials, and co-pyrolysis biochar is prepared by a high-temperature pyrolysis method; the prepared co-pyrolysis biochar can increase the amount of methane produced through anaerobic digestion of the kitchen waste, and compared with biochar obtained through pyrolysis of a single biomass raw material, the co-pyrolysis biochar has a better strengthening effect on methane produced through anaerobic digestion of the kitchen waste; the biogas residues are waste products of kitchen waste anaerobic digestion, the biogas residues can be effectively used as biochar preparation raw materials, the biochar can be returned again to be used for strengthening anaerobic digestion to produce methane, a raw material closed loop is formed, and in-situ recycling of kitchen biogas residues is achieved.

Disclosed herein is a method for co-pyrolysis of a polyolefin and a rubber containing material comprising: operating at least a pyrolysis stage of a pyrolysis reactor at an operating temperature at or above the temperature at which pyrolysis of both the polyolefin and the rubber containing material commences and up to about 600° C. under a substantially inert atmosphere; feeding a mixture comprising the polyolefin and the rubber containing material into the pyrolysis reactor; co-pyrolysing the mixture in the pyrolysis reactor to produce a pyrolysis gas comprising volatile pyrolysis products of the polyolefin and the rubber, wherein the volatile pyrolysis product of the olefin comprises at least a short chain olefin and the volatile product of the rubber comprises at least a diene; and facilitating a gas phase reaction between the short chain olefin and the diene to produce a volatile gas comprising single-ring aromatic hydrocarbons.

The invention discloses a catalytic reaction system for zero-carbon fuel pretreatment and straw co-pyrolysis. The catalytic reaction system comprises a co-pyrolysis reaction furnace, a zero-carbon fuel pretreatment device, a straw treatment device, a condensation collection device and a heat energy recovery device, the co-pyrolysis reaction furnace is provided with a microwave generator, and the zero-carbon fuel pretreatment device and the straw treatment device are respectively communicated with the co-pyrolysis reaction furnace; the condensation collection device comprises a condensation box communicated with the co-pyrolysis reaction furnace through a smoke exhaust pipe, a condensation pipe arranged in the condensation box, an oil collection tank communicated with the condensation pipe and a gas collection tank communicated with the condensation box, and the heat energy recovery device comprises a water tank forming a circulation loop with the condensation pipe and one or more preheating water pipes led out of the circulation loop. And the heat exchange section of the preheating water pipe is arranged in the interior or the shell of the pretreatment device and the straw treatment device. Heat energy of oil gas is recycled, zero-carbon fuel and straw are preheated, the pyrolysis efficiency is improved, and meanwhile resource waste can be reduced.

The present invention relates to a method for the co-pyrolysis of biomass and mineral raw materials for activating the mineral raw materials and to the use of the resulting pyrolysis product in the construction industry, in horticulture and landscaping, as a carrier and filter material, in energy storage technology, and as a CO2 sink.

The invention relates to a high-first-effect quick-charge type nitrogen and phosphorus co-doped hard carbon negative electrode material, a preparation method thereof and a sodium ion battery. The preparation method comprises the following steps: crushing biomass by using a crusher to obtain biomass powder; deionized water is adopted to wash the biomass powder, and then the washed biomass powder is dried at a first preset temperature for a first preset time; uniformly mixing the pretreated biomass powder, an activating agent and a nitrogen doping agent according to a preset mass ratio; placing the mixed material in a first tubular furnace in an inert gas atmosphere for carbonization and calcination; cooling the calcined product to room temperature, taking out the calcined product, transferring the calcined product into an acid solution, stirring and cleaning, repeatedly washing the calcined product with deionized water until the calcined product is neutral, and drying the calcined product in a drying oven at a second preset temperature for a second preset time; the mode of high-temperature nitriding presintering and vapor phase phosphorus deposition is adopted, and element distribution uncontrollability, namely uneven distribution, of a traditional co-pyrolysis method is broken through.

The present application relates to a method for a resourceful treatment of waste carbon fiber wind turbine blades. The method comprises the following steps: (1) separating balsa wood from waste carbon fiber wind turbine blades, then pyrolyzing same, and modifying same with an alkali liquor, so as to obtain a pyrolyzed balsa wood catalyst; and (2) subjecting the waste carbon fiber wind turbine blades from which the balsa wood is separated and the pyrolyzed balsa wood catalyst obtained in step (1) to a microwave co-pyrolysis treatment, so as to obtain pyrolysis gas, pyrolytic oil and pyrolytic carbon. In the present application, by subjecting the tar generated during the process of microwave co-pyrolysis to in-situ catalytic cracking, the subsequent coking problem of a pyrolysis device is ameliorated; and compared with conventional pyrolysis conditions, the energy consumption of pyrolysis is reduced, and the content of pyrolytic oil is reduced, which are conducive to the rapid implementation of resource recycling during the subsequent treatment process of the waste carbon fiber wind turbine blades.

The application discloses a method for preparing a Fenton-like catalyst by co-pyrolysis of steel slag and orange peel and application thereof, and belongs to the technical field of catalytic materials. Biomass material is prepared by cleaning, drying, crushing and passing through a 100-mesh sieve, steel slag is prepared by crushing and passing through a 200-mesh sieve, the pretreated biomass powder and the steel slag powder are stirred and mixed according to different mass ratios, the obtained mixture is co-pyrolyzed at a high temperature of 600-900 DEG C, and then the co-pyrolysis product is cleaned, dried, ground and sieved to obtain a Fenton-like catalyst. The application uses cheap steel slag and orange peel as raw materials to prepare a composite material for a Fenton-like catalyst by co-pyrolysis, uses cheap orange peel as a modifier, strengthens the activation effect by introducing carbon material, fully utilizes beneficial components (such as metal oxides like iron oxides) in the steel slag, and fully improves the pore structure of the steel slag, so that a high-efficiency Fenton-like catalyst is prepared, and the purpose of treating waste with waste is achieved.