The invention belongs to the technical field of environment protection, and relates to a device and a process for
temperature difference crystallizing
ammonia process desulfurization, which is especially suitable for the
ammonia process modification and newly-built desulfurization of the original
calcium process desulfurization device. The device comprises a desulfurization
tower, a densifying device, a gas-liquid
heat exchanger, a
circulating pump, a concentration
circulating pump, a
magma pump, a concentration
crystallization tank and a
drying system, wherein the desulfurization
tower, the
circulating pump, the
magma pump and the
drying system adopt the devices in the original
calcium process desulfurization; the lower part of the densifying device is provided with a gas
distributor, and the upper part thereof is provided with spray heads which are arranged in 2-3
layers; spray heads in the desulfurization
tower are arranged in 2-4
layers, a liquid supplementation
pipe is connected with the spray heads at the lowest layer in the desulfurization tower; the concentration
crystallization tank is a tank with a conical bottom part; and the upper part of the concentration
crystallization tank is provided with a pipeline to be connected with the bottom of the densifying device, the middle of the concentration crystallization tank is provided with a pipeline to be connected with theconcentration circulating pump, and the bottom is provided with a pipeline to be connected with the
magma pump. The invention can farthest utilize the original devices on the premise of guaranteeing the normal desulfurization efficiency, thereby saving the investment, reducing the
energy consumption and eliminating the secondary
pollution.