The invention relates to a method for extracting two secondary salts from a desulfurized salt-containing waste liquid of coke oven gas. The waste liquid treatment and secondary salt extraction process comprises the following steps: decolorizing, removing impurities, performing reduced pressure concentration on the salt-containing filtrate, separating ammonium thiocyanate, concentrating and crystallizing the ammonium thiocyanate ethanol filtrate, drying the ammonium thiocyanate product, separating ammonium sulfate, concentrating and crystallizing the ammonium thiosulfate filtrate, drying the ammonium thiosulfate product and the like. According to the invention, the desulfurized waste liquid is thoroughly treated, the products are high in recovery rate, no mixed salts or waste water is discharged, no secondary pollution is caused, and the process is clean and environment-friendly. Meanwhile, the invention also has the remarkable characteristics of high adaptability, high production elasticity, high resource utilization rate and the like.