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Process for recovering heavy metallic salt and inorganic acid in pickling waste liquid

A heavy metal salt and acid recovery technology, which is applied in chemical instruments and methods, semi-permeable membrane separation, permeation/dialysis water/sewage treatment, etc., can solve incomplete resource recovery, reduce membrane service life, increase treatment costs, etc. problem, to achieve the effect of increasing the economic effect of the enterprise, increasing the processing cost, and reducing energy consumption

Active Publication Date: 2010-06-30
NANJING UNIV OF TECH +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The problems of this method are: resource recycling is incomplete, the dialysate in the diffusion dialysis and the concentrated solution in the nanofiltration process are not treated so that the metal salt cannot be recovered; the acid is concentrated by nanofiltration and reverse osmosis, which is relatively difficult A high concentration of acid will greatly reduce the service life of the membrane and increase the treatment cost; if the pickling waste liquid is a mixed acid system, the use of the purified and concentrated acid will be greatly limited, and its applicability will be greatly restricted. limit
[0006] To sum up, there is currently a lack of a process for the comprehensive treatment of metal waste acid solution, which can achieve the purpose of separate recovery of metal and acid without secondary pollution and can be well coupled with the original process

Method used

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  • Process for recovering heavy metallic salt and inorganic acid in pickling waste liquid
  • Process for recovering heavy metallic salt and inorganic acid in pickling waste liquid

Examples

Experimental program
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Effect test

Embodiment 1

[0025] Below in conjunction with accompanying drawing and example the present invention will be further described

[0026] Such as figure 1 Shown, treatment of hot-rolled stainless steel sulfuric acid deoxidized layer pickling wastewater. Among them, sulfuric acid cleaning waste liquid contains FeSO 4 60g / L, sulfuric acid 200g / L. Its method is:

[0027] Step 1: Use a corrosion-resistant pump to drive the waste acid into the alumina ceramic device (Jiangsu Jiuwu High-Tech Co., Ltd. ceramic membrane complete set of equipment, the alumina ceramic membrane pore size is 0.05μm) for filtration, and control the transmembrane pressure to 0.2MPa. The membrane surface velocity is 2m / s. Remove suspended solids to reduce the suspended solids of waste acid to 20NTU.

[0028] Step 2: The permeate of the ceramic membrane device passes through the dialysis side of the diffusion dialysis device (Diffusion dialysis device of Nanjing Jiusi High-tech Co., Ltd., the ion exchange membrane adop...

Embodiment 2

[0033] Such as figure 1 As shown, the aluminum surface cleaning waste liquid contains Al 2 (SO 4 ) 3 150g / L, sulfuric acid 250g / L. Its method is:

[0034] The first step: pump the waste acid into the ceramic membrane device (Jiangsu Jiuwu High-tech Co., Ltd. ceramic membrane complete set of equipment, the pore size of the zirconia ceramic membrane is 0.2 μm) for filtration through a corrosion-resistant pump, and control the transmembrane pressure to 0.4MPa. The membrane surface velocity is 3m / s. Remove the suspended solids to reduce the suspended solids of the waste acid to 10NTU.

[0035] Step 2: The permeate of the ceramic membrane device passes through the dialysis side of the diffusion dialysis device (Diffusion dialysis device of Nanjing Jiusi High-tech Co., Ltd., the ion exchange membrane adopts Japan Asahi Glass DSV anion exchange membrane), and at the same time, the water is passed into the recovery side. The permeate and water of the membrane device are in a rat...

Embodiment 3

[0040] Such as figure 1 As shown, the treatment of stainless steel passivation waste liquid contains 30g / L of iron ions, 140g / L of nitric acid, and 80g / L of hydrofluoric acid. Its method is:

[0041] The first step: pump the waste acid into the ceramic membrane device (Jiangsu Jiuwu High-tech Co., Ltd. ceramic membrane complete set of equipment, the pore size of the alumina ceramic membrane is 0.5 μm) for filtration through a corrosion-resistant pump, and control the transmembrane pressure to 0.5 MPa. The membrane surface velocity is 2.5m / s. Remove suspended solids to reduce the suspended solids of waste acid to 15NTU.

[0042] Step 2: The ceramic membrane permeate passes through the dialysis side of the diffusion dialysis device (Nanjing Jiusi High-tech Co., Ltd. diffusion dialysis device, the ion exchange membrane adopts the Japanese Asahi Glass APS anion exchange membrane), and at the same time passes the water into the recovery side, and the ceramic membrane device Perm...

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Abstract

The invention relates to a process for separating and recovering heavy metallic salt and inorganic acid in pickling waste liquid by a membrane method, which comprises the following concrete steps: filtering and removing solid suspended substances in pickling waste liquid through an inorganic ceramic membrane; separating acid from salt in the ceramic membrane penetrating liquid through diffusion dialysis; and heating the dialysis liquid of a diffusion dialyzer, then introducing the dialysis liquid into a nanofiltration membrane, and cooling and crystallizing the concentrated liquid of a nanofiltration device and then centrifuging the crystal of the concentrated liquid to obtain iron salt, wherein the penetrating liquid of the nanofiltration device passes through a reverse osmosis membrane device, the concentrated liquid of the reverse osmosis device returns to a pickling section, and the water discharged from the reverse osmosis device enters a diffusion dialysis section for recycling. The invention has the characteristics that the pickling waste liquid is completely used as resources, the recovery process is simple, the recovery ratio of metallic salt and acid is high, and water is recycled. The process of the invention can be coupled with various pickling sections to realize continuous and stable automated operation, and the supplemented acid amount can be quantitatively controlled according to the acid amount consumed by the crystallized metallic salt.

Description

technical field [0001] The invention relates to the field of resource utilization of waste water, in particular to a process for separating and recovering heavy metal salts and inorganic acids in pickling waste liquid by using a membrane method, so that the treated pickling waste acid and inorganic acid neutralized metal salts can be comprehensively utilized, reducing waste water disposal. Background technique [0002] In the process of industrial production, mining and smelting (such as iron and steel industry, titanium dioxide industry, hydrometallurgy industry, titanium industry, electroplating industry, rare earth industry, wood saccharification industry, gold mining and non-ferrous metal smelting industry, etc.), often Use inorganic acids (such as sulfuric acid, hydrochloric acid, nitric acid, hydrofluoric acid, etc.) to clean metal surfaces or dissolve ores. A large amount of spent acid solution containing various metal ions is then produced. Taking the iron and stee...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F1/44B01D71/02
Inventor 邢卫红杨刚王昆徐南平
Owner NANJING UNIV OF TECH
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