The invention belongs to the technical field of preparation of functional nano materials, and relates to preparation of an electrolytic water evolution
oxygen catalyst, and in particular relates to asulfur-doped NiFe(CN) 5NO electrolyze water
oxygen evolution catalyst by using a solvothermal preparing method and application thereof. The method comprises the following steps that equal volume of Na2Fe(CN)5 NO. 2H2O solution is added into a Ni(NO3).6H2O solution, and uniform stirring is performed, after leaving the solution to stand,
centrifugal separation, washing and
vacuum drying are carriedout on the precipitates, NiFe(CN)5NO nano-particles are obtained, and then the NiFe(CN)5NO nano-particles are ultrasonically dispersed in absolute ethyl
alcohol, a
sulfur source is added, after ultrasonically dispersing and uniformly stirring are performed, the mixture is transferred into a reaction kettle, wherein reaction time is carried out for 8-16 hours at the temperature of 120-200 DEG C, then naturally cooling is performed, a product S-NiFe(CN)5NO is obtainedthe after the
centrifugal separation, the washing and the
vacuum drying are performed on the product; the morphology of the prepared product is regular, and the particle size is about 40 micron; and the S-NiFe(CN)5NO has the advantages of excellent in electrocatalytic activity and good in stability when being used as an electrolytic
oxygen evolution reaction catalyst. According to the method, compared with a commercial
noble metal catalyst, the prepared electrolytic water
oxygen evolution reaction catalyst has better catalytic performance; and the preparation method is simple, the
controllability is good, the cost is low, and the industrial implementation is easy.