The invention discloses a ferrihydrite-graphene composite.A preparation method of the ferrihydrite-graphene composite comprises the following steps that 1, graphene oxide is taken and added to distilled water with 5-20 times of weight, and ultrasonic dissolving is carried out to form sol; 2, trivalent molysite is added into the sol, the mass of ferric ions in the sol accounts for 5% to 40% of the mass of solid solution matter, stirring is carried out, the pH of the sol is adjusted to range from 7 to 8 with metal aqueous alkali, and stirring continues to be carried out for 10 min to 60 min; 3, centrifugation is carried out, and sediment is separated and washed 2-5 times with deionized water; 4, the sediment is dried at the temperature of 40 DEG C to 50 DEG C, and smashing is carried out.The ferrihydrite-graphene composite can adsorb inorganic phosphorus and organic phosphorus in a polluted water body at the same time, the adsorption capacity is large, and compared with other water body dephosphorization methods, the ferrihydrite-graphene composite has the advantages of being easy and convenient to operate, low in cost, easy to control, easy to recycle, environmentally friendly and the like.