The invention provides an azacyclo-compound having the structure shown in the
chemical formula 1. In the formula 1, X1 to X6 independently represent N or C atoms, at least one of X1 to X6 is an N atom, m and n independently represent 0, 1 or 2, m+n is greater than 1, R1 represents a
hydrogen atom, a C1-C10 linear or branched
alkyl group, a substituted or unsubstituted
phenyl group, a diphenyl group, a
terphenyl group, a pyridyl group, a naphthyl group or an anthracenyl group, Ar is selected from a dimethyl
fluorene group, a
phenyl group and a carbazolyl group, and Ar1 and Ar2 independently represent a substituted or unsubstituted
benzimidazole group. The azacyclo-compound has a high
refractive index, when the azacyclo-compound is used as a CPL cap layer of an organic light-emitting and
display device (such as an
OLED), light extraction efficiency and luminous efficiency of the top emission organic photoelectric device can be improved, and the
angular dependence of
OLED device illumination is reduced. The azacyclo-compound has a small
extinction coefficient in the blue region and almost no absorption of
blue light and improves luminous efficiency.