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Quantum dot ink and preparing method thereof

A quantum dot and ink technology, applied in the field of quantum dot ink and its preparation, can solve the problem of comet dots, limited application, quantum dot ink viscosity, surface tension and boiling point can not better meet the needs of inkjet printing equipment and printing technology, etc. question

Inactive Publication Date: 2016-08-03
TCL CORPORATION
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Using this low-viscosity solvent, ink droplets are not easy to control during inkjet printing, and problems such as comet spots are prone to occur, which cannot better meet the requirements of inkjet printing technology
[0005] The viscosity, surface tension and boiling point of quantum dot inks in the prior art cannot well meet the requirements of inkjet printing equipment and printing processes, and in other published patents, in order to regulate the physical parameters of inks, these quantum dot inks Both contain other additives such as alcohol polymers
However, polymer additives with insulating properties are not easy to remove, and the introduction of such polymers tends to reduce the charge transport capability of the film, which has a negative impact on the optoelectronic performance of the device, limiting its application in the optoelectronic field.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0043] The mixed solvent is composed of 3,3,5-trimethylheptane (boiling point 156°C) and 2-methylpentanol (boiling point 148°C), wherein 2-methylpentanol accounts for 40% of the total weight of the solvent.

[0044] With stirring, the following components were added to an approximately 500 mL one-necked flask in the order of addition: 10 wt% oleylamine-stabilized red CdSe / ZnS quantum dots, 54 wt% 3,3,5-trimethylheptane solvent , 36wt% 2-methylpentanol solvent, and stirred the mixture for 30 minutes to obtain a quantum dot ink.

Embodiment 2

[0046] The mixed solvent is composed of octadecane (boiling point 316°C) and 2-ethylcyclohexanol (boiling point 165°C), wherein 2-ethylhexanol is 20% of the total weight of the solvent.

[0047] With stirring, the following components were added to an approximately 500 mL one-necked flask in the order of addition: 8 wt% oleylamine-stabilized green CdZnSe / CdZnS quantum dots, 73.6 wt% octadecane solvent, 18.4 wt% 2-ethane Cyclohexanol solvent, the mixture was stirred for 30 minutes to obtain a quantum dot ink.

Embodiment 3

[0049] The mixed solvent is composed of dodecane (boiling point 216°C) and 2,6-dimethyl-4-heptanol (boiling point 173°C), of which 2,6-dimethyl-4-heptanol is 35% of the total weight of the solvent %.

[0050] In the case of stirring, the following components were added to an approximately 500mL one-necked flask in the order of addition: 12wt% oleylamine-stabilized blue CdS / CdZnS quantum dots, 57.2wt% dodecane solvent, 30.8wt% 2, 6-dimethyl-4-heptanol solvent, the mixture was stirred for 30 minutes to obtain quantum dot ink.

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Abstract

The invention discloses quantum dot ink and a preparing method thereof. The quantum dot ink comprises, by mass, 0.01%-20% of quantum dots and 80%-99.99% of mixed solvent. The mixed solvent comprises at least one alkane organic solvent and at least one small-molecule alcohol organic solvent, wherein the small-molecule alcohol organic solvent is 1% to 80% of the total weight of the mixed solvent, the boiling point of the alkane organic solvent ranges from 150 DEG C to 320 DEG C, the boiling point of the small-molecule alcohol organic solvent is lower than that of the alkane organic solvent. The quantum dot ink prepared with the method has the high viscosity and the high surface tension, the requirement of an ink-spraying printing device and the requirement of the printing technology can be well met, and the organic solvent of the quantum dot ink can be removed in a vacuum evaporation or heat evaporation mode and the like to form a film of a quantum dot material.

Description

technical field [0001] The invention relates to the field of quantum dot inks, in particular to a quantum dot ink and a preparation method thereof. Background technique [0002] Semiconductor quantum dots have excellent characteristics such as high light color purity, high luminous quantum efficiency, adjustable luminous color, and long service life. These characteristics make quantum dot light-emitting diodes (QLED) with quantum dot materials as the light-emitting layer have broad application prospects in solid-state lighting, flat panel display and other fields, and have attracted extensive attention from academia and industry. [0003] Quantum dots can be dispersed in solvents to prepare printing materials such as quantum dot inks. Specifically, methods such as printing, pad printing, and spin coating can be used to manufacture quantum dot luminescent films. For example, using the drop-on-demand (DroponDemand) process similar to inkjet printing (InkjetPrinting), the quan...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D11/38C09D11/36C09D11/03C09D11/033
CPCC09D11/38C09D11/03C09D11/033C09D11/36
Inventor 谢相伟李雪
Owner TCL CORPORATION
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