653 results about "Chloromethane" patented technology

The invention belongs to the technical field of new materials, and discloses a polyolefin dissolving agent as well as a preparation method and application thereof. The cleaning agent is composed of modified long-carbon-chain imidazole dinitrile amine salt, modified long-carbon-chain imidazole long-carbon-chain anion salt, betaine salt, imidazole acetate, imidazole long-carbon-chain anion salt, quaternary ammonium long-carbon-chain anion salt, imidazole bis (fluorosulfonyl) imide salt, imidazole hexafluorophosphate and long-carbon-chain anion and cation liquid. Under the condition of 180-210 DEG C, polyolefin (PP or PE) with the molecular weight of 50-8 million can be dissolved by adopting the polyolefin dissolving agent disclosed by the invention, and effective extrusion can be realized by adopting a twin-screw extruder after dissolution. After PP / PE powder is dissolved by adopting the polyolefin dissolving agent disclosed by the invention, sheet casting or spinning is carried out, casting sheets or PP / PE fibers are washed by using ethanol / dichloromethane / hydrocarbon / tetrachloroethylene to remove ionic liquid, and a polyolefin diaphragm or polyolefin fibers can be prepared.

The invention relates to the technical field of repair materials, and particularly discloses an extracellular matrix fiber material as well as a preparation method and application thereof. The invention discloses a preparation method of an extracellular matrix fiber material. The preparation method comprises the following steps: taking animal tissues, and carrying out virus inactivation, decellularization and antigen removal, degreasing, drying, grinding and sterilization; the decellularization and antigen removal method comprises the following specific steps: sequentially soaking a sample with a surfactant solution for h; then, soaking treatment is carried out by adopting a salt-alkali solution which contains 0.05-3 mol / L of salt and has the pH value of 8-11; then carrying out soaking treatment by adopting a 0.1-1wt% enzyme solution; and in degreasing, one or more of normal hexane, trichloromethane, dichloromethane, methanol, ethanol, acetone, diethyl ether and ethyl acetate are used for soaking the sample. According to the technical scheme, the ECM powder particle material with high growth factor content is prepared.

The invention discloses a fluopyram preparation method, which comprises: S1, carrying out a heating reaction on 2-vinyl-3-chloro-5-trifluoromethylpyridine, ammonia water, a catalyst and a solvent, carrying out reduced pressure distillation after the heating reaction to recover the solvent so as to obtain a residue, and adding dichloromethane and triethylamine to the residue so as to obtain a reaction liquid; and S2, dropwise adding o-trifluoromethyl benzoyl chloride into the reaction liquid in an ice bath, then removing the ice bath, stirring at the room temperature, adding water into the reaction liquid obtained in the step S1, extracting an organic layer, drying with anhydrous magnesium sulfate, recovering the solvent under reduced pressure, and performing vacuum drying to obtain the fluopyram. The method has the advantages of high reaction yield, high product purity, recyclable and reusable solvent, simple and mild production process, and suitableness for mass production.

The invention belongs to the technical field of surface enhanced Raman spectroscopy, and particularly relates to a high-activity surface enhanced Raman scattering substrate as well as a preparation method and application thereof. Comprising the following steps: by utilizing a three-phase liquid-liquid interface self-assembly method, adding dichloromethane into an AuNPs dispersion liquid, uniformly mixing, adding a halide salt solution, uniformly mixing to form a mixed solution, then adding normal hexane into the mixed solution, standing, performing interface self-assembly until a gold nano-film is formed on a liquid surface, fishing out the gold nano-film, and drying to obtain the gold nano-film. The high-activity surface enhanced Raman scattering substrate is obtained. According to the method, the halide salt solution is innovatively introduced in the self-assembly process of the AuNPs, so that the assembly arrangement mode of the AuNPs is remarkably changed, the AuNPs are arranged more tightly, local surface plasma resonance coupling is enhanced, more hot spot areas are generated in a unit area, and the sensitivity of the self-assembly nano array SERS substrate is effectively improved.

The invention discloses an analysis method for simultaneously detecting organochlorine pesticide and polychlorinated biphenyl, which comprises the following steps of: simultaneously extracting organochlorine pesticide and polychlorinated biphenyl in a water sample by adopting a mixed extraction solvent, dehydrating, concentrating and fixing the volume of extract liquor, separating and measuring by adopting a gas chromatography-mass spectrometry method, and quantifying by adopting an internal standard method. When the mixed extraction solvent is n-hexane / dichloromethane with the volume ratio of 9: 1 and 1% by mass of polyethylene glycol 4000 is added, the recovery rates of water samples with the measured concentrations of 5.00 ng / L, 20.0 ng / L, 40.0 ng / L and 80.0 ng / L are 83.6%-95.4%, 91.2%-105.6%, 93.5%-104.7% and 92.8%-106.9% respectively, the relative standard deviations are 6.1%-9.2%, 3.3%-8.2%, 3.2%-6.3% and 3.4%-7.5% respectively, compared with the prior art, the extraction efficiency is remarkably improved, and the method has the advantages that the method is simple, the cost is low, and the method is suitable for industrial production. The accuracy and precision of the method completely meet the determination and analysis requirements for measuring complex water samples.

A method for catalyzing selective oxidation of 5-hydroxymethylfurfural by ion-doped birnessite belongs to the field of chemical engineering, and comprises the following steps: adding an ion-doped birnessite type catalyst into a solvent, and catalyzing 5-hydroxymethylfurfural to prepare 2, 5-furandicarboxaldehyde and 2, 5-furandicarboxylic acid in the atmosphere of air or oxygen at the temperature of 25-240 DEG C, wherein the solvent is water, methanol, ethanol, acetonitrile, dichloromethane, N, N-dimethylformamide, N, N-dimethylacetamide and the like. The method is simple, few in by-products and environmentally friendly. By adopting ion-doped birnessite as the catalyst, the method has the advantages of economy, environmental protection, mild conditions, high selectivity, easiness in recovery of the catalyst and the like; the ion-doped birnessite catalyst can efficiently and highly selectively catalyze oxidation of 5-hydroxymethylfurfural to prepare 2, 5-furandicarboxaldehyde, catalytic materials are easy to separate, the production cost is low, and the ion-doped birnessite catalyst has remarkable technical and economic effects and application prospects.

The invention relates to the technical field of synthesis of chemical products, in particular to a synthesis method of acryloyloxyethyl trimethyl ammonium chloride. According to the method, a one-pot reaction system is adopted, ethyl acrylate and N, N-dimethylaminoethanol are taken as raw materials and are subjected to quaternization reaction with chloromethane under an alkaline condition, and efficient conversion is realized through the synergistic effect of a composite catalytic system and a polymerization inhibitor. The composite catalyst is constructed by compounding magnetic nanoparticles and a metal organic framework material, forms a multilevel structure through titanate crosslinking, and has high catalytic activity and magnetic separation and recovery characteristics. The method simplifies the traditional step-by-step process, has the advantages of simple and convenient one-pot operation, recyclable catalyst, high raw material utilization rate, environmental friendliness and the like, and is suitable for large-scale preparation of acryloyloxyethyl trimethyl ammonium chloride.

The invention belongs to the technical field of high polymer material detection, and discloses a quantitative detection method for potassium perfluorobutanesulfonate in a high polymer material and application of the quantitative detection method. According to the method, trichloromethane reflux extraction and methanol precipitation are adopted as pretreatment, and specific liquid chromatography-tandem mass spectrometry detection conditions are matched, so that excellent recovery rate and extremely low limit of quantitation are obtained, and the determination requirement of potassium perfluorobutanesulfonate in a high polymer material is met. In addition, the invention further provides a detection method for simultaneously detecting the content of the potassium perfluorobutanesulfonate and the content of the polytetrafluoroethylene in the high polymer material, the content of perfluorine in a sample is detected firstly, then the content of the potassium perfluorobutanesulfonate is detected by adopting the quantitative detection method, and the content of the polytetrafluoroethylene is calculated through the content of the potassium perfluorobutanesulfonate and the content of the polytetrafluoroethylene. The method provided by the invention is simple and easy to implement, high in accuracy and good in reproducibility.

The invention discloses a crystal compound, a preparation method thereof and application of the crystal compound in X-ray detection, imaging and anti-counterfeiting encryption, and belongs to the technical field of crystals. The molecular formula of the crystal compound is [Cu (totp) (CH3CN) 3] [Cu2I3 (totp) (PN)]. (CH3CN), wherein totp is tris (o-tolyl) phosphine; and PN is diphenyl-2-pyridine phosphine. The crystal compound disclosed by the invention is simple in preparation method, and has the characteristics of large mass attenuation coefficient of X-ray energy, high light yield and low detection limit when being used as a material of an X-ray detector. The compound also has the characteristic of structural transformation in solvents such as methanol, ethanol, acetone, dichloromethane, tetrahydrofuran and the like, and meanwhile, the conversion of luminescence color under the excitation of 365nm ultraviolet light and X rays is accompanied. The material can be applied to the aspects of scintillator materials, room-temperature X-ray radiation indirect detection materials, radiation detection dosimeters, X-ray scintillator medical imaging, anti-counterfeiting encryption and the like.

The invention relates to the technical field of waste gas treatment, and particularly discloses waste gas treatment liquid for treating large-air-volume low-concentration waste gas through a water-based method. The waste gas treatment liquid for treating the large-air-volume low-concentration waste gas through the water-based method comprises a surfactant, a defoaming agent, a dissolution accelerant and water. Wherein the surfactant can be selected from any one or more of polyoxyethylene alkyl ether, polyoxyethylene alkyl ether and polyoxyethylene fatty acid ester; the dissolution accelerant can be selected from any one or more of ethylene glycol monobutyl ether, diethylene glycol monobutyl ether and triethylene glycol monobutyl ether; the defoaming agent is any one or more of butanol, dimethyl silicone oil, silicone and polyether modified polysiloxane. When the waste gas absorption liquid obtained in the invention is used for treating waste gas, the absorption efficiency of methanol, butanol, benzene, toluene, xylene, ethyl acetate, dichloromethane and acetone is obviously improved, and the absorption efficiency of the waste gas absorption liquid on aromatic hydrocarbon, halogenated hydrocarbon, alcohol, ketone and ester pollutants is improved.

The invention relates to the technical field of lithium / sodium ion batteries, in particular to a preparation method of a highly graphitized coated carbon material based on phenolic resin, which comprises the following steps: uniformly mixing formaldehyde, resorcinol and a basic catalyst, and then catalyzing and curing; carrying out carbonization treatment on the uncarbonized phenolic resin based on a gradient heating method; mixing ethidene diamine, dichloromethane and carbonized phenolic resin, and heating in an oil bath; and placing the cured and coated graphitized phenolic resin in a tubular furnace for highly graphitizing. According to the preparation method of the highly-graphitized coated carbon material based on the phenolic resin, high ordering of a carbon layer is achieved through gradient heating graphitization, a carbon six-membered ring plane is promoted to expand, an ABAB stacked graphite structure is formed, the conductivity is effectively improved, a CVD coating and nitrogen doping synergistic technology is combined, a CVD reaction is formed through ethanediamine and dichloromethane, and the high-graphitization coated carbon material based on the phenolic resin is obtained. Functional groups such as pyridine-N and graphite-N are introduced to the surface of the carbon layer, so that the interface bonding force between the carbon layer and the matrix is enhanced, and the conductivity of the carbon layer is further improved.

The invention discloses an alkenyl epoxidation method, an epoxy resin monomer and application thereof, and belongs to the field of compound synthesis. Aiming at the problems of high halogen content and low preparation universality of the existing epoxy resin monomer, the invention provides an alkenyl epoxidation method which comprises the following steps: dissolving an aromatic compound in an organic solvent, adding an oxidant and a catalyst into the organic solvent, and extracting after complete reaction to obtain the epoxy resin monomer, the preparation method of the catalyst comprises the following steps: dispersing phosphotungstic acid in hydrogen peroxide to obtain an emulsion; adding a trichloromethane solution of cetylpyridinium chloride into the emulsion, and performing liquid separation after the reaction is completed to obtain a catalyst precursor; the catalyst is obtained. The specific catalyst is used, so that the subsequent reaction catalysis efficiency is higher, and the universality is higher; and no epoxy chloropropane is introduced in the whole process of the alkenyl epoxidation method, so that the halogen content of the finally prepared epoxy resin monomer is low, and the limitation barrier that the use of the conventional epoxy resin monomer is limited due to high halogen content is broken through.

The invention provides a synthesis method of an OLED polycyclic fused thiophene compound, and relates to the technical field of material synthesis, and the synthesis method comprises the following steps: providing and mixing 2-naphthalene sulfonic acid and dichloromethane, dropwise adding an N-bromosuccinimide solution into the mixture under the protection of inert gas, and reacting to obtain an intermediate A; dissolving the intermediate A, then adding sodium hydroxide, 4-bromophenylboronic acid, water and tetrakis (triphenylphosphine) palladium, and reacting to obtain an intermediate B; dissolving the intermediate B, adding sulfonic acid and phosphorus pentoxide, and reacting to obtain an intermediate C; adding the intermediate C into tetrahydrofuran, dissolving, adding lithium aluminum hydride under inert gas, and reacting to obtain a target compound. According to the method, the chemical reaction efficiency of the intermediate C is high, and the yield and LC purity of a target product are relatively high.

The invention provides a preparation method of triphenylchloromethane, and belongs to the technical field of medical intermediates. The preparation method comprises the following steps: preparing a suspension from pure benzene, a composite catalyst and an adsorbent, dropwise adding carbon tetrachloride to obtain a reaction solution, heating the reaction solution to 60-80 DEG C, treating with 808nm laser while stirring, and performing post-treatment to obtain the triphenylchloromethane. The composite catalyst catalyzes pure benzene and carbon tetrachloride to react to generate triphenylchloromethane, hydrogen chloride is released, the adsorbent can adsorb hydrogen chloride in situ, and acid corrosion and catalyst poisoning can be prevented while forward proceeding of the reaction is maintained; the composite catalyst and the adsorbent are used for realizing catalysis-adsorption synergistic promotion of forward proceeding of the reaction, so that the dosage of the catalyst is reduced, the reaction time is shortened, the output of wastewater is reduced, and the reaction yield and the purity of triphenylchloromethane are improved.

The invention belongs to the technical field of hydrophobic electromagnetic shielding materials, and particularly relates to an asymmetric electromagnetic shielding composite film and a preparation method and application thereof. The PNTs are polypyrrole nanotubes, after Na2MoO4. 2H2O and CH4N2S are added and subjected to a high-temperature reaction, a MoS2 flower-shaped shell structure can grow on the PNTs, the layered structure and the high specific surface area of MoS2 contribute to enhancing scattering and absorption of electromagnetic waves, and rich defect sites can induce dielectric polarization to achieve dielectric loss. Introducing the PNTs (at) MoS2 core-shell nanowire as an electromagnetic wave absorbent into a polylactic acid / dichloromethane system, then putting the system into a culture container in which a conductive filler is pre-paved, and standing and volatilizing at room temperature by adopting an ethanol solution as a volatile agent to finally obtain a three-layer asymmetric electromagnetic shielding composite film comprising the conductive filler, the PNTs (at) MoS2 structure and a polylactic acid matrix from bottom to top. And an asymmetric conductive gradient network is constructed, and the EMI shielding performance which mainly focuses on absorption is remarkably improved, so that the secondary radiation problem of electromagnetic waves is reduced.

The invention belongs to the field of chemical production, and particularly relates to a chloromethane cooling recovery system and a chloromethane cooling recovery method. The chloromethane cooling recovery system provided by the invention comprises a first condenser, a second condenser, a third condenser and a recovered chloromethane storage tank, a shell pass inlet of the second condenser is connected with a tube pass outlet of the third condenser, and a tube pass inlet of the third condenser is used for introducing liquid chloromethane. Chloromethane is cooled and recovered by using a liquid chloromethane vaporization heat absorption principle, so that the economical efficiency is good; in addition, due to the fact that the to-be-cooled object and the refrigerant are both methyl chloride, even if mutual leakage occurs in the heat exchange process, the quality of recycled methyl chloride cannot be affected, and raw material losses cannot be caused.

The invention relates to the field of antibacterial functional polymer materials, and discloses a quaternary phosphonium salt type isobutyl cationic polymer as well as a preparation method and application thereof. The preparation method of the polymer comprises the following steps: under a cationic polymerization condition and in the presence of a solvent and a catalyst, isobutene and alkyl styrene are contacted for cationic polymerization, a terminator is added for terminating to obtain a solution containing an isobutene-alkyl styrene copolymer, the solution and a halogenating agent are subjected to a halogenating reaction, and the isobutene-alkyl styrene copolymer is obtained. The preparation method comprises the following steps: preparing a halogenated isobutylene-alkyl styrene copolymer solution, contacting the halogenated isobutylene-alkyl styrene copolymer solution with an organic phosphine compound, carrying out an ionization reaction to obtain a slurry material containing solid particles, carrying out solid-liquid separation to obtain a solid phase, and washing and drying the solid phase with a solvent and deionized water to obtain the quaternary phosphonium salt type isobutylene cationic polymer. The solvent is selected from dichloromethane and / or trichloromethane. The polymer prepared by the method is high in purity, high in quaternary phosphonium salt group content and higher in antibacterial property.

The invention relates to a rapid thin-layer identification method for seven medicinal materials in ten-ingredient nerve-soothing granules. The method is characterized in that two test solutions of a trichloromethane layer and an n-butyl alcohol layer are obtained by a simple, convenient and rapid pretreatment method, the trichloromethane layer can be used for identifying schisandra chinensis, moutan bark and lotus plumule, and the n-butyl alcohol layer can be used for identifying pulp of dogwood fruit, fried gardenia, white paeony root and rhizoma anemarrhenae; the thin-layer identification method disclosed by the invention can be used for identifying 7 medicinal materials in 10 medicinal materials in the whole formula of the ten-ingredient nerve-soothing granules, and is convenient to operate, clear in spots and high in specificity.

The present invention discloses a preparation process of Grignard alcohol, which uses magnesium and methyl chloride as reaction raw materials, tetrahydrofuran as a solvent, and iodine crystals as an initiator. The Grignard reaction is carried out under nitrogen to generate a Grignard reagent, and then the Grignard reagent reacts with p-chlorobenzophenone by an addition reaction to generate Grignard alcohol. The magnesium includes pre-treated magnesium powder and magnesium strips. By simultaneously using magnesium powder and magnesium strips with specific mass ratios and size ratios and pre-treating them, the present invention can ensure the stable progress of the reaction and improve the reaction yield; in addition, by carrying out the treatment of removing water and peroxides from tetrahydrofuran, while ensuring the process safety, the yield of the Grignard alcohol product can be further improved.

The invention discloses a device for recovering monochlorodifluoromethane from a preparation system, which is characterized in that a residual liquid outlet is communicated with a recovery buffer tank (2) through a residual liquid storage tank (1), a liquid phase outlet of the residual liquid storage tank (1) is communicated with an inlet of an alkali liquor desorption tower (6) through a regulating valve (3), a material outlet of a dilute acid storage tank (5) is communicated with an inlet of the alkali liquor desorption tower (6), and a material outlet of the dilute acid storage tank (5) is communicated with a material outlet of the alkali liquor desorption tower (6). An alkali liquor outlet is communicated with a recovery buffer tank (2) through an alkali liquor desorption tower (6), a monochlorodifluoromethane outlet of the recovery buffer tank (2) is communicated with an inlet of a condensation collecting tank (9) through a compressor (8), and the condensation collecting tank (9) is communicated with a finished product storage tank (12) through a recovery pump (4), a water alkali washing system and a rectifying tower (11). The monochlorodifluoromethane stored in the recovery buffer tank (2) is conveyed to a water alkali washing system and then put into a rectifying tower (11) to be refined, and the obtained monochlorodifluoromethane finished product is stored in a finished product storage tank (12).

The application discloses a continuous system and method for converting low-value glyphosate by-products into high-value chemical products, comprising: pumping low-value glyphosate by-products and alkaline compounds into a constant-temperature conversion kettle for conversion and decomposition, and introducing nitrogen into the top of the constant-temperature conversion kettle to blow off and replace gaseous volatile products generated in the reaction; after gaseous products pass through a buffer tank to capture water vapor, the gaseous products enter a three-stage condenser to recover condensable components into a crude product receiving tank, and the non-condensable components are purified and impurities are removed by an acid absorption system and then utilized; liquid crude product is pumped into a low-temperature vacuum desolventizing kettle to realize separation of condensable components from liquid water, and then enters a two-stage condenser for deep dehydration and separation, and is recovered into a pure product receiving tank. The application realizes a new process for preparing high-purity N,N-diethylmethylamine, and forms a whole-process process system for converting low-value waste materials such as chloromethane, triethylamine and synthetic products thereof into high-value chemical products such as N,N-diethylmethylamine and ethylene.

The invention relates to a post-treatment method and system for chloromethane synthesis, and the post-treatment method comprises the following steps: cooling a chloromethane crude product prepared in a reaction stage through an economizer, and then carrying out gas-liquid separation in a gas-liquid separator, a connecting pipeline between the economizer and the gas-liquid separator is filled with a water flow which flows in a direction opposite to that of the material, so that the temperature of a gas-phase discharge hole in the top of the gas-liquid separator is controlled to be 90-120 DEG C; the separated liquid phase enters a hydrochloric acid buffer tank with a partition plate, and an oil phase and a water phase are separated out; and washing the separated gas phase with water by a water washing tower, and then drying to obtain a chloromethane product. The economizer, the gas-liquid separator with specific temperature control and the hydrochloric acid buffer tank with the partition plate are arranged between the reaction system and the water scrubber, so that three-phase separation of'oil phase silicide-water phase-gas phase 'is efficiently realized, and the oil phase silicide is separated from the chloromethane crude product and does not enter the water scrubber and other subsequent systems; therefore, the problem of pipeline blockage in a post-treatment system is solved.

The invention discloses a fluorescent probe for identifying D-galactosamine as well as a preparation method and an identification method thereof, and belongs to the technical field of chemical analysis and detection. The fluorescent probe takes BINOL as a skeleton, and the preparation method of the fluorescent probe comprises the following steps: sequentially synthesizing intermediates (R)-2, (R)-3 and (R)-4, dissolving (R)-4 in a mixed solution of absolute ethyl alcohol and dichloromethane, adding hydrochloric acid, reacting overnight, quenching, separating a water phase and an organic phase, removing a solvent under reduced pressure, and purifying by a silica gel column to obtain a yellow solid product (R)-5, namely the fluorescent probe. The fluorescent probe disclosed by the invention is simple to prepare and low in cost, the D-galactosamine (D-GalN) can be identified from various amino sugars and amino acids in acetonitrile, and the detection method is simple to operate, high in sensitivity and convenient in post-treatment.

The present application relates to a kind of preparation method of trifluoromethyl pyrazole compound, belong to the technical field of organic synthesis.The specific method is: (1) trifluoroacetyl ethyl acetate is first with hydrazine hydrate cyclization reaction and generates compound of formula III;(2) under the catalysis of base, compound of formula III is reacted with difluoromethylation reagent and generates compound of formula II;(3) compound of formula II is reacted with methylating agent and obtains compound of formula I;The difluoromethylation reagent is difluoro-monochloromethane or sodium difluoro-monochloroacetate;The methylating agent is chloromethane, bromomethane, iodomethane, dimethyl sulfate or dimethyl carbonate.The present application is prepared by changing reaction route, and the higher-priced raw material methylhydrazine is replaced, and isomer impurity is no longer generated in the product prepared.Not only raw material cost is reduced, but also the purity of product is improved.

The invention discloses a method for simultaneously analyzing polychlorinated biphenyls, polycyclic aromatic hydrocarbons and organochlorine pesticides in water, which comprises the following steps: simultaneously extracting polychlorinated biphenyls, polycyclic aromatic hydrocarbons and organochlorine pesticides in a water sample by using a mixed solvent of n-hexane and dichloromethane, merging while extracting, purifying, concentrating and fixing volume, and testing on a machine in two groups, the polychlorinated biphenyl and the organochlorine pesticide are independently used as a group, the polycyclic aromatic hydrocarbon is used as a group, when an extraction solvent adopts a mixed solvent of dichloromethane and n-hexane, the extraction efficiency is gradually increased along with the increase of the proportion of the n-hexane, and when the volume ratio of the n-hexane to the dichloromethane is 9: 1, the extraction recovery rate can reach 78.9%-111%. When 1% of polyethylene glycol 4000 is added in the mixed extraction process with the volume ratio of n-hexane to dichloromethane being 9: 1, the extraction efficiency is remarkably improved, the extraction efficiency recovery rate reaches 84.6%-112%, and it is indicated that the addition of polyethylene glycol 4000 has the remarkable improvement effect. Compared with the prior art, the extraction efficiency is remarkably improved, and the accuracy and precision of the method completely meet the determination and analysis requirements for measuring complex water samples.

The application relates to a method for synthesizing and refining electronic-grade hexachloroethyldisilane, and specifically, trichlorosilane raw material is mixed with protective gas into a raw material buffer tank, a mixed gas obtained through the mixing is subjected to a catalytic synthesis reaction under the irradiation of an ultraviolet light source, a product obtained through the reaction is subjected to condensation separation, gaseous trichloromethane returns to the raw material buffer tank to continuously participate in the synthesis reaction, the mixed liquid in the cold trap is warmed and vaporized, hexachloroethyldisilane is obtained through two-step refining, and the purity of the product hexachloroethyldisilane can reach the electronic grade. The application takes trichlorosilane as the initial raw material, the price of the raw material is low; the photo-catalysis is used as the synthesis process, the synthesis process is simple, the reaction yield is high, energy is saved, and the environment is protected; the two-step method is used for refining and purifying the product, the depth of the refining and the efficiency of the refining are high, large-scale production is suitable, the monopoly of foreign enterprises is broken, and the application has important significance.

The invention relates to a method for removing cyclohexane in a low-molecular brominated polystyrene recovery solvent, which comprises the following steps: adding the recovery solvent containing cyclohexane and dichloromethane into a reaction bottle, and then adding a certain amount of fuming sulfuric acid; stirring and reacting for a period of time at a certain reaction temperature; adding water for quenching, standing for layering, washing an organic layer to be neutral, and standing for layering; and rectifying the organic layer, and collecting corresponding fractions. The used fuming sulfuric acid contains excessive sulfur trioxide, the sulfonation capacity is higher, cyclohexane is sulfonated to generate sulfonic acid group cyclohexane, then the sulfonic acid group cyclohexane is removed through water washing, the removal rate is high, the operation is convenient and fast, the cost is low, and the method is suitable for industrial production.

The application discloses a preparation method and application of an alkaline zinc-based flow battery electrolyte, and comprises the following steps: firstly, dissolving a hydroxide solid in deionized water to obtain an alkaline aqueous solution; secondly, dissolving a zinc oxide solid in the alkaline aqueous solution obtained in the step (I) to obtain an alkaline aqueous solution containing a zincate; and finally, dissolving a sugar alcohol and a chloromethane in the alkaline aqueous solution containing the zincate obtained in the step (II) to obtain an alkaline electrolyte. By introducing different concentrations of the sugar alcohol and the chloromethane into the alkaline electrolyte containing the zincate, the double electric layer and the solvation structure of the zinc negative electrode are regulated, the self-corrosion and the hydrogen evolution side reaction problems of the zinc negative electrode under the strong alkaline (pH>14) condition are effectively inhibited, the alkaline electrolyte has good zinc compatibility, high stability and relatively fast reaction kinetics, and has great potential in the development and application of the alkaline zinc-based flow battery.

The present application belongs to the field of chemical production, and particularly relates to a chloromethane cooling and recycling system and a chloromethane cooling and recycling method. The chloromethane cooling and recycling system comprises a first condenser, a second condenser, a third condenser and a chloromethane recycling tank. The shell side inlet of the second condenser is connected with the tube side outlet of the third condenser, and the tube side inlet of the third condenser is used for passing in liquid chloromethane. The present application uses the vaporization endothermic principle of liquid chloromethane to cool and recycle chloromethane, and is good in economy. Moreover, since the to-be-cooled substance and the refrigerant are both chloromethane, even if mutual leakage occurs in the heat exchange process, the quality of the recycled chloromethane will not be affected and the loss of raw materials will not be caused.

The invention discloses a control method for stably recovering reaction heat of liquid-phase catalytic synthesis of chloromethane, which comprises the following steps: two-way shunting control of synthesis gas and reflux control of synthesis gas condensed acid, the first-way shunting control of the two-way shunting control of the synthesis gas comprises the following steps: enabling the synthesis gas to enter a first heat exchanger through a first control pipeline to vaporize methanol; according to the second-path split-flow control, the synthesis gas enters a second heat exchanger through a second control pipeline in a split-range control mode to be cooled; the first path of shunt control of the reflux control of the synthesis gas condensed acid is to form cascade control through the liquid level and the flow so as to return a liquid component into the synthesis reactor through a reflux pipeline, and the second path of shunt reflux control is to enable the liquid component to enter a hydrochloric acid storage tank through a discharge pipeline. The problem that in the prior art, steam needs to be additionally supplemented for methanol vaporization can be thoroughly solved, and long-time stable operation of the synthetic reaction can be guaranteed.