The invention provides a method for preparing a doping-type crystalline titanium dioxide photoelectrode at low temperature by virtue of a microwave auxiliary reaction supercharge method and belongs to a low-temperature synthesis method of a solar battery photoelectrode. The preparation method comprises the following steps: 1, adding a titaniferous precursor into alcohol, uniformly mixing, then adding an adulterant, stirring, then adding a hydrolysis inhibitor, and slowly dropwise adding deionized water, thus obtaining a mixed solution; 2, heating the mixed solution in a water bath, stirring, refluxing and reacting until the reaction is over, thus obtaining a titaniferous and element-doped colloid; 3, cooling the colloid to room temperature, then transferring the cooled colloid into a high-pressure vessel, adding a decomposition agent and then rapidly sealing the vessel; 4, placing the vessel into a microwave reaction device, rapidly heating, keeping stirring, filtering reaction products, washing with deionized water, and drying, thus obtaining doping-type crystalline titanium dioxide. The method provided by the invention has the advantages that the doping-type crystalline titaniumdioxide with grains of about 120nm can be prepared at low temperature; the dispersibility is better; the preparation process time is shorter; and long-term follow-up high-temperature crystallization treatment is not required.