273results about "Iron cyanides" patented technology

A method is provided for synthesizing a metal-doped transition metal hexacyanoferrate (TMHCF) battery electrode. The method prepares a first solution of AxFe(CN)6 and Fe(CN)6, where A cations may be alkali or alkaline-earth cations. The method adds the first solution to a second solution containing M-ions and M'-ions. M is a transition metal, and M' is a metal dopant. Subsequent to stirring, the mixture is precipitated to form AxMcM'dFez(CN)n.mH2O particles. The AxMcM'dFez(CN)n.mH2O particles have a framework and interstitial spaces in the framework, where M and M' occupy positions in the framework. Alternatively, the method prepares AaA'bMyFez(CN)n.mH2O particles. A and A' occupy interstitial spaces in the AaA'bMyFez(CN)n.mH2O particle framework. A metal-doped TMHCF electrode is also provided.

The invention relates to an edging cube-shaped cobalt-iron prussian blue nanometer material and a preparation method thereof. The preparation method comprises the following steps of firstly, stirring and dissolving a surfactant into water under the magnetic action; after dissolving, sequentially adding sodium citrate and cobalt salt to prepare a solution A; then, dissolving potassium ferricyanide solid into water to prepare a solution B; gradually dripping the solution A into the solution B while stirring; after dripping, continuing to stir for a period of time; standing and aging the reaction liquid for a period of time, naturally cooling, centrifuging, washing, and drying, so as to obtain the edging cube-shaped cobalt-iron prussian blue nanometer material. Compared with the prior art, the synthesizing method has the advantages that by changing the conditions, the edging cube-shaped cobalt-iron prussian blue nanometer material is prepared; the morphology and structure of the material are not reported in the literature; the preparation is simple, the implementing is easy, and the large-batch preparation effect is realized.

The invention discloses a prussian blue positive electrode material, a sodium ion battery, and a preparation method and application thereof. The molecular formula of the prussian blue positive electrode material is NaxM [Fe (CN) 6] y.nH2O, wherein M is transition metal, x is less than or equal to 2 and greater than or equal to 1.8; y is less than or equal to 1 and greater than or equal to 0.95; and n is less than or equal to 2 and greater than or equal to 0. The prussian blue positive electrode material has low lattice defect and stable performance; and the sodium ion battery prepared from thematerial is high in capacity and good in cycle performance. The preparation method comprises the following steps of: S1, adding an aqueous solution of weak acid into an aqueous solution of sodium ferrocyanide and transition metal ethylenediamine tetraacetic acid sodium salt to obtain a precipitate; and S2, drying the precipitate. The preparation method can be adopted to control the crystallization speed, and has advantages of simple process, low production cost, non-toxicity, harmlessness and short production period.

To provide a method of producing Prussian blue-type metal complex nanoparticles without necessarily requiring complicated steps and an excessive amount of raw materials, but allowing one to obtain nanometer-size fine particles having desired fine particle properties, and Prussian blue-type metal complex nanoparticles obtained by the method, a dispersion of the nanoparticles, a method of regulating the color of the nanoparticles, and an electrode and a transmitted light-regulator each using the nanoparticles; Prussian blue-type metal complex nanoparticles are produced by: mixing an aqueous solution containing a metal cyano complex anion having predetermined metal atom M_A as a central metal and an aqueous solution containing a cation of predetermined metal atom M_B, thereby precipitating the crystal of a Prussian blue-type metal complex having the metal atom M_A and the metal atom M_B; and then mixing the Prussian blue-type metal complex with an aqueous solution containing a metal cyano complex anion having the metal atom M_C as a central metal and/or an aqueous solution containing a cation of the metal atom M_D. The thus-obtained Prussian blue-type metal complex nanoparticles have a preferable electrochemical responsiveness, and the particles can be used for forming a thin film including them to construct a light-transmitted regulator.

The invention relates to a preparation method of a Prussian blue flower-like nano-structure electrode material. The preparation method comprises the following steps: 1) firstly, dissolving nickel chloride hexahydrate and anhydrous sodium citrate into de-ionized water; 2) dissolving sodium ferrocyanide decahydrate into de-ionized water; 3) pouring a solution of step 2) into a mixed solution obtained by step 1) and uniformly stirring to obtain a mixed solution; 4) standing the mixed solution obtained by step 3); 5) centrifuging and collecting sediment; washing the sediment for several times; drying in vacuum to obtain Prussian blue precursor powder; 6) adding the precursor powder into a sodium hydroxide solution and carrying out ultrasonic treatment; 7) centrifuging and collecting a product and washing; drying in vacuum to obtain light green powder, namely the Prussian blue flower-like nano-structure electrode material. The preparation method provided by the invention has the beneficial effects that the specific surface area is remarkably enlarged so that reaction sites of electrolyte and the electrode material are effectively increased and an ion diffusion distance is reduced; when the Prussian blue flower-like nano-structure electrode material is used as a positive electrode active material of a sodium ion battery, the material has the characteristics of high power and good cycling stability.

The invention relates to a high-performance super-capacitor electrode material Co-Fe type prussian blue nano cube as well as a preparation method and application thereof, and belongs to the technical field of electrode material preparation. According to the preparation method, inorganic cobalt salt and potassium ferricyanide are adopted as reaction raw materials, trisodium citrate is adopted as a complexing stabilizer, a liquid-phase precipitation reaction method is implemented, reaction conditions such as the use amount and the stand aging time of potassium ferricyanide are controlled, a Co-Fe type prussian blue nano cube material with good dispersibility and large specific area is prepared, and the size of the material is about 300nm. By adopting the Co-Fe type prussian blue nano cube material provided by the invention, the capacity of an electrochemical electric container is increased, properties such as the rapid charge and discharge property and the service life of the electric container are improved, the capacitance of the electric container is as high as 447F/g in constant current charge and discharge of 5A/g in a 1mol/L sodium sulfate solution, and the good rate capability is achieved.

The invention relates to a sodium nitroprusside synthesis processes, wherein potassium nitroprusside and copper sulfate pentahydrate are adopted as reaction raw materials and are subjected to a reaction under a suitable reaction condition to generate copper nitroprusside, the copper nitroprusside reacts with sodium bicarbonate to generate sodium nitroprusside, and concentration crystallization, centrifugation and vacuum drying are performed after the complete reaction to obtain the product. The synthesis process has characteristics of simpleness, easy operation, high product purity, and high yield, and is suitable for industrial production.

The invention provides a preparation method of a prussian blue type energy storage material, and specifically relates to a preparation method of a prussian blue type sodium-ion battery electrode material with high yield. The preparation method comprises the following steps: S1, dissolving divalent transition metal perchlorate and sodium ferrocyanide into water respectively to obtain a divalent transition metal perchlorate solution and a sodium ferrocyanide solution; S2, dissolving sodium perchlorate into water to obtain a sodium perchlorate solution; and S3, mixing the divalent transition metal perchlorate solution and the sodium ferrocyanide solution with the sodium perchlorate solution to obtain a mixed solution, and stirring and standing the mixed solution to obtain a sediment product;and separating and drying the sediment product to obtain the prussian blue type energy storage material. According to the preparation method, a great deal of loss of the prussian blue type material inthe cleaning process is avoided, and high-yield production can be realized. The preparation method is simple and high in yield, and is easy for industrial large-scale production.

An electrochemical battery is provided with an aluminum anode current collector and an antimony (Sb)-based electrochemically active material overlying the aluminum current collector. The Sb-based electrochemically active material may be pure antimony, Sb with other metal elements, or Sb with non-metal elements. For example, the Sb-based electrochemically active material may be one of the following: Sb binary or ternary alloys of sodium, silicon, tin, germanium, bismuth, selenium, tellurium, thallium, aluminum, gold, cadmium, mercury, cesium, gallium, titanium, lead, carbon, and combinations thereof. The aluminum current collector may additionally include a material such as magnesium, iron, nickel, titanium, and combinations thereof. In one aspect, the anode further composed of a coating interposed between the aluminum current collector and the Sb-based electrochemically active material. This coating may be a non-corrodible metal or a carbonaceous material. The cathode is may be composed of a number of different active materials including sodium-based Prussian Blue analogues.

The invention discloses a prussian-blue derivative Cd2[Fe(CN)6] nanorod and a preparation method thereof. The preparation method for the Cd2[Fe(CN)6] nanorod comprises: firstly adding proper amount of potassium ferrocyanide, polyethylene glycol (PEG-400), a cadmium salt and deionized water into a hydrothermal reaction kettle core, putting into a baking oven and performing 120 DEG C-180 DEG C constant-temperature reaction, and naturally cooling to room temperature after the reaction is finished; and performing centrifugation washing and drying on the prepared product, so as to prepare the Cd2[Fe(CN)6] nanorod. After the prepared Cd2[Fe(CN)6] powder is tested by an X-ray diffractometer and a scanning electron microscope, Cd2[Fe(CN)6] is a nanorod, is uniform in particle size distribution, and can be used as a material used for making electrochromic devices and a secondary battery electrode material.

The invention discloses a high-entropy Prussian blue material, and the molecular formula of the high-entropy Prussian blue material is NaxMIN[Fe(CN)6]zwH2O, wherein M is n different transition metal elements, n is greater than or equal to 5, yn is greater than or equal to 0.01 and less than or equal to 0.90, y1 + y2 + y3 + y4 + y5+... + yn = 1, w is less than or equal to 4.0, x is greater than or equal to 1.40 and less than or equal to 1.95, and z is greater than or equal to 0.90 and less than or equal to 0.98. The high-entropy Prussian blue material is of a monoclinic phase structure, the microstructure of the high-entropy Prussian blue material is large-size crystal particles, and the crystal particles are uniform in size, single in shape and regular in polyhedral morphology. The invention also provides application of the high-entropy Prussian blue material as a positive electrode material in a sodium-ion battery and a preparation method of the high-entropy Prussian blue material. A coprecipitation method is adopted, and the high-entropy Prussian blue material with high specific capacity, good rate capability and excellent cycle performance is obtained through selection of source materials, technological process design and selection and control of technological parameters in preparation.

The invention discloses a Prussian blue material, and a preparation method and an application thereof. The preparation method comprises the steps: mixing sodium ferrocyanide or a hydrate of sodium ferrocyanide with deionized water to obtain a solution I; mixing soluble ferrous salt, ascorbic acid and sodium citrate with deionized water to obtain a solution II; dropwise adding the solution I and the solution II into deionized water at the same time, and carrying out a coprecipitation reaction to obtain a suspension of a Prussian blue material; and aging and post-processing the suspension to obtain the micron-sized Prussian blue material with a cubic stepped structure. The prepared Prussian blue material is applied to a positive electrode of a sodium ion battery, so that the capacity and thecycling stability of the sodium ion battery can be remarkably improved.