The present invention relates to the field of ceramic products and production methods thereof, in particular to a low-temperature primary-fired ceramic with an opaque glaze surface and a preparation method thereof, characterized in that: the raw materials of the bottom glaze layer include the following components in parts by weight 5-6 parts of industrial iron oxide, 5-10 parts of wood ash, 3-5 parts of flint, 10-12 parts of quartz, 10-15 parts of orthoclase, the raw materials of the surface glaze layer are in parts by weight, including the following groups Parts: 10-15 parts of molten powder, 15-18 parts of quartz, 10-15 parts of feldspar, 21-25 parts of albite, 2-3 parts of cooked talc, 8-10 parts of calcite, 2-3 parts of zircon and 1‑2 parts of zinc oxide. The low-temperature once-fired ceramics with an opacified glaze surface and the preparation method provided by the present invention reduce the firing temperature, have good opacification effects, rich glaze shapes, effectively save fuel, have good blank glaze adaptability, and have high strength and hardness of the blank glaze. .