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Synthesis and surface modification method of lithium excessive laminar oxide anode material

The invention relates to a synthesis and surface modification method of a lithium rich anode material Li1+xM1-xO2 (M is one or more of Ni, Co and Mn, and X is more than or equal to 0 and less than or equal to 1 / 3) for a lithium ion battery. The method comprises the following steps of: synthesizing a precursor by using a carbonate precipitation method, mixing the precursor and a lithium salt, and calcining for 2 to 20 hours at the temperature of between 800 and 1,100 EG C to obtain a lithium rich material, wherein the prepared lithium rich material has controllable particle size and higher reversible capacity; and dissolving persulfate or sulfate in an amount which is 5 to 80 mass percent of the lithium rich material into deionized water, adding the lithium rich material, stirring for 2 to 100 hours at the temperature of between 25 and 80 DEG C, heating the materials to the temperature of between 100 and 500 DEG C in a muffle furnace, calcining the materials for 2 to 20 hours, fully filtering the obtained materials, and washing off impurities to obtain the surface modified anode material Li1+x-yM1-xO2. The synthesized lithium rich material has controllable particle size; the first charge / discharge efficiency of the lithium rich material and the discharge specific capacity and the cyclical stability under high magnification can be improved; and the method is simple, low in cost, convenient for operation and suitable for industrialized production.
Owner:GUANGZHOU HKUST FOK YING TUNG RES INST

Preparation method of sodium-ion battery cathode material Na3V2(PO4)3

The invention discloses a preparation method of a sodium-ion battery cathode material Na3V2(PO4)3. The method comprises the following steps: (1) mixing a sodium salt, a vandic salt, phosphate, a complexing agent, a high-molecular compound and a solvent to obtain a Na3V2(PO4)3 spinning solution; (2) carrying out electrostatic spinning on the Na3V2(PO4)3 spinning solution to obtain a Na3V2(PO4)3 spinning precursor; and (3) collecting the Na3V2(PO4)3 spinning precursor, carrying out thermal treatment on the Na3V2(PO4)3 spinning precursor in an inert atmosphere and cooling the Na3V2(PO4)3 spinning precursor to obtain the sodium-ion battery cathode material Na3V2(PO4)3. According to the sodium-ion battery cathode material Na3V2(PO4)3 prepared by the method disclosed by the invention, high-capacity charging and discharging of the battery can be realized; and the cycle stability of the battery can be improved.
Owner:BEIJING INSTITUTE OF TECHNOLOGYGY

Positive electrode material for potassium ion battery and preparation method thereof, and potassium ion battery

The invention discloses a positive electrode material for a potassium ion battery and a preparation method thereof, and the potassium ion battery. The positive electrode material has a chemical formula of K<x>P[R(CN)<6>], wherein x is no less than 0 and no more than 2, P is a transition metal ion, and R is Fe<2+> or Fe<3+>. The preparation method comprises the following steps: dissolving potassium ferricyanide or potassium ferrocyanide and a transition metal salt to prepare a uniform solution; then carrying out a hydrothermal reaction; separating a precipitate produced in the hydrothermal reaction; and carrying out washing and vacuum drying so as to obtain the positive electrode material. The preparation method in the invention is simple in process, easy to operate, low in cost for required raw materials and suitable for large-scale industrial production. The prepared positive electrode material has an open three-dimensional network frame structure, and great interstitial sites allow potassium ions to shuttle and to be stored, so the potassium ion battery assembled from the positive electrode material has high discharge capacity, long cycle life, and high energy density and power density.
Owner:XI AN JIAOTONG UNIV

High-energy-density lithium ion battery and preparation method thereof

The invention relates to a high-energy-density lithium ion battery and a preparation method thereof. The high-energy-density lithium ion battery comprises a positive pole piece, a negative pole piece and a membrane, wherein an active substance on the positive pole piece is nickel cobalt lithium manganate, namely Li<1+a>Ni<x>Co<y>Mn<z>O2; an active substance on the negative pole piece is a silicon-carbon material. The preparation method of the high-energy-density lithium ion battery comprises the following steps: manufacturing the positive pole piece with the active substance, nickel cobalt lithium manganate, namely Li<1+a>Ni<x>Co<y>Mn<z>O2; manufacturing the negative pole piece with the silicon-carbon material as the active substance; coiling or laminating the positive pole piece, the negative pole piece and the celgard membrane to prepare a power battery core. The lithium ion battery provided by the invention is high in energy density, high in coulombic efficiency and high in cycling stability. The preparation method has the advantages of simple process, low cost and easiness for industrialized production.
Owner:CHERY AUTOMOBILE CO LTD

Metal zinc negative electrode with uniform mesoporous structure coating and preparation method and application thereof

The invention discloses a metal zinc negative electrode with a uniform mesoporous structure coating and a preparation method and application thereof, belonging to the technical field of aqueous zinc ion batteries. The metal zinc negative electrode comprises a zinc negative electrode and a clay slurry layer, and is prepared by pre-embedding zinc. The raw material powder of the clay slurry includes1-20wt% of polyvinylidene fluoride and 80-90wt% of clay material. The aqueous zinc ion battery negative electrode coating presented in the invention can play a role of a protective layer, isolate thedirect contact between the zinc negative electrode and the electrolyte to a certain extent, reduce the side reaction between the electrode and the electrolyte and improve the cycle stability. The layered porosity of the material itself can prevent dendrites from being generated and penetrating a diaphragm in the cycle process, alleviate the volume expansion of the negative electrode, reduce the occurrence of short circuit of the battery and improve the safety performance.
Owner:CENT SOUTH UNIV

Preparation method of silicon-carbon composite material

The invention relates to a preparation method of a silicon-carbon composite material. The preparation method comprises the following steps of: S1, preparing a carbon-coated nano silicon-based oxide, namely separately weighing silicon particles and a carbon source aqueous solution and uniformly mixing the two in a silicon-carbon molar ratio of (5-15) to 1 to form a suspension; transferring the suspension to a container, cooling the container to room temperature and taking the container out after a hydrothermal reaction at a first predetermined temperature for a first predetermined time, and washing and drying the suspension in vacuum to obtain the carbon-coated nano silicon-based oxide; and S2, preparing the silicon-carbon composite material, namely grinding and mixing the carbon-coated nano silicon-based oxide obtained in the S1 with metal magnesium powder in a mass ratio of 1 to (0.6-1.6) to form a mixture, and then mixing the mixture in an inorganic salt; filling the container with the mixed mixture and the inorganic container, putting the container in inert gas, raising the temperature to a second predetermined temperature at a predetermined temperature raising rate, keeping the second predetermined temperature for a second predetermined time, cooling the mixture, cleaning impurities, and then drying the mixture in vacuum to obtain the silicon-carbon composite material.
Owner:OPTIMUM BATTERY CO LTD

Core-shelled structured lithium ion battery positive composite material and its preparation method

The invention discloses a core-shell structured lithium ion battery positive composite material and its preparation method. The composite material includes a LiFePO4 nanometer core and a Li3V2(PO4)3 shell, the Li3V2(PO4)3 shell is uniformly coated on the periphery of the LiFePO4 nanometer core, and the periphery of the Li3V2(PO4)3 shell is coated with amorphous carbon. The positive composite material has the advantages of high specific capacity, high energy density, good cycle stability, good rate performance and the like. The preparation method comprises the following steps: stirring an iron source compound, a vanadium source compound, a phosphorus source compound, a lithium source compound, a chelating agent and a carbon source in deionized water, and sintering the obtained mixture to obtain the composite material. The preparation method has the advantages of simple process, easy operation, low cost, environmental protection, and suitableness for large-scale and industrialized production.
Owner:CENT SOUTH UNIV

Silicon negative electrode material with fluff structure and preparation method of silicon negative electrode material

The invention discloses a silicon negative electrode material with a fluff structure and a preparation method of the silicon negative electrode material. The silicon negative electrode material with the fluff structure comprises a silicon-based active material, carbon nanotubes, a carbon layer and a fast ion conductor layer, wherein the carbon nanotubes grow on the surface of the silicon-based active material in situ to form a fluff structure, the surfaces of the silicon-based active material and the carbon nanotubes are coated with the carbon layer, the surface of the carbon layer is coated with the fast ion conductor layer, the carbon layer grows in the axial direction of the carbon nanotubes, and it is ensured that the material still has the fluff structure finally. According to the invention, through the fluff structure on the surface thereof, more conductive channels are provided; reliable conductive contact of the silicon material before and after volume expansion is guaranteed,so that volume expansion is buffered better, cracking of a coated film is avoided, ionic conductivity can be improved greatly by controlling graphitization degree of the carbon nanotubes and matchingwith the fast ion conductor layer, and the material has the characteristics of high conductivity, long cycle, high rate and the like.
Owner:LANXI ZHIDE ADVANCED MATERIALS CO LTD

High-performance natural graphite-MnO composite electrode material and preparation method thereof

The invention relates to a high-performance natural graphite-MnO composite electrode material and a preparation method of the high-performance natural graphite-MnO composite electrode material. The preparation method comprises the following steps that: a mixture of MnO2 and natural graphite is generated by virtue of reaction between KMnO4 solution and the natural graphite, wherein one part of the generated MnO2 goes into the natural graphite to form an intercalated structure, while the other part of the MnO2 is deposited on the surface of the natural graphite; next, the mixture is calcined in an inert atmosphere, and the MnO2 is reduced into MnO by utilizing the reducing property of the natural graphite, and therefore, the natural graphite-MnO composite material is formed. In the preparation method, the natural graphite is used as either a main body material or a reducing agent, the process is simplified, and the obtained composite material is excellent in properties. The natural graphite layers do not collapse as being supported by MnO among the natural graphite layers, the interlayer spacing of the natural graphite is expanded, so that lithium ions can be deintercalated quickly without affecting the structure of the natural graphite, and therefore, the cycle performance of the natural graphite composite electrode material can be improved favorably; the MnO deposited on the surface of the natural graphite is helpful to capacity improvement. The natural graphite composite electrode material with high capacity and good cycle performance can be obtained by combining the natural graphite and MnO.
Owner:HUBEI ZHONGYI TECH

A method for preparing a lithium-rich manganese-based cathode material coated with lithium titanium phosphate

ActiveCN109119624ARelieve ruptureEase phase transitionSecondary cellsPositive electrodesAir atmosphereManganese
A method for preparing a lithium-rich manganese-based cathode material coated with lithium titanium phosphate comprises the following steps: (1) mixing and grinding a lithium-rich manganese-based precursor with a lithium source, calcining in an air atmosphere, and cooling; 2, dispersing the lithium-rich manganese-based cathode material in an anhydrous organic solvent I and uniformly stirring; thenadding a titanium source, uniformly stirring to obtain a black suspension a; 3, weighing a lithium source and phosphorus source, adding the lithium source and phosphorus source into an anhydrous organic solvent II, uniformly stirring to obtain a mixed suspension b; 4) adding the mixed suspension b into the black suspension a for reaction, evaporating in an oil bath to obtain dry gel powder; 5, calcining the dry gel powder under a reducing atmosphere to obtain the material. As the surface coating layer, the lithium titanium phosphate of the invention can not only alleviate the cracking and lamellar-snipel phase change of the secondary particles, but also can improve the positive pole-electrolyte interface kinetics, and thus the lithium-rich manganese-based cathode material composite coatedwith lithium titanium phosphate have excellent cycle stability.
Owner:CENT SOUTH UNIV

Modified high-voltage positive electrode material and preparation method and application thereof

The invention discloses a modified high-voltage positive electrode material as well as a preparation method and application thereof. The modified high-voltage positive electrode material comprises a high-voltage positive electrode material core and a conductive polymer shell layer coating the surface of the high-voltage positive electrode material core, the preparation method comprises the following steps: carrying out in-situ reaction by adopting a high-voltage positive electrode material, a conductive polymer monomer, a catalyst and an initiator or carrying out direct coating by adopting thehigh-voltage positive electrode material, a conductive polymer and a coupling agent. The modified high-voltage positive electrode material can gradually react with an electrolyte in a battery througha controllable electrochemical activation process to form a new surface compact coating layer, the surface impedance of the battery can be effectively reduced, the ion transmission performance is improved, the rate capability of the material is improved, and the preparation method is simple to operate, high in controllability, non-toxic, harmless, few in by-product and suitable for industrial production.
Owner:NAT UNIV OF DEFENSE TECH

Alpha-MoO3-x nanobelt and preparation method thereof as well as electrode material and energy storage device

The invention discloses an alpha-MoO3-x nanobelt and a preparation method thereof as well as an electrode material and an energy storage device. The preparation method of the alpha-MoO3-x nanobelt comprises the following steps: taking molybdenum powder and dissolving the molybdenum powder in a hydrogen peroxide solution, adding a reducing agent, sufficiently mixing, transferring the obtained mixture into a reaction kettle for reacting to prepare the alpha-MoO3-x nanobelt. The prepared alpha-MoO3-x nanobelt has abundant and uniformly-distributed oxygen vacancies, and is extremely excellent in morphology and excellent in conductivity; and the alpha-MoO3-x nanobelt can be prepared into the electrode material with extremely excellent electrochemical properties such as capacity, rate performance and cycling performance, so that the electrochemical properties of the energy storage device can be improved.
Owner:SHENZHEN GRADUATE SCHOOL TSINGHUA UNIV

Positive electrode material for lithium ion cells and preparation method thereof

The invention relates to a positive electrode material for lithium ion cells and a preparation method thereof. The material provided by the invention is porous vanadic anhydride with an amorphous carbon layer on the surface of vanadic anhydride, wherein the weight friction of vanadic anhydride is 80-99.9% and the weight friction of carbon is 0.1-20%. In comparison with the prior art, the preparation method provided by the invention has advantages of simple technological process, short reaction time, low production cost and the like.
Owner:CHANGZHOU POWERGENIE MATERIALS

Porous multi-hollow flexible composite nanofiber membrane material and preparation method thereof

The invention relates to a porous multi-hollow flexible composite nanofiber membrane material and a preparation method thereof. According to the method, a porous multi-hollow flexible composite nanofiber membrane is prepared through coaxial electrostatic spinning, wherein an outer layer solution for coaxial electrostatic spinning consists of a sacrificial high-molecular polymer, a retained high-molecular polymer and a solvent A, and an inner layer solution for coaxial electrostatic spinning is composed of a sacrificial high-molecular polymer, a material capable of generating a substance with semiconductor characteristics and low surface energy in the spinning process, and a solvent B; and then the sacrificial high-molecular polymer in the porous multi-hollow flexible composite nanofiber membrane is removed to obtain the membrane material formed by stacking porous multi-hollow nanofibers, wherein the porous multi-hollow nanofibers are provided with a plurality of hollow pipelines and three-dimensional penetrating through hole micro-nano structures with the hollow surfaces. The membrane material disclosed by the invention has relatively high flexibility and mechanical strength, and the problems of fragility, low mechanical strength and the like of a porous composite fiber material and a single hollow fiber material are solved.
Owner:DONGHUA UNIV

Potassium ion battery negative electrode active material, potassium ion battery negative electrode material, potassium ion battery negative electrode, potassium ion battery and application thereof

The invention provides a potassium ion battery negative electrode active material, a potassium ion battery negative electrode material, a potassium ion battery negative electrode, a potassium ion battery and an application thereof, belonging to the technical field of potassium ion batteries. The potassium ion battery negative electrode active material provided by the invention comprises a ruthenium pentoxide composite material, wherein the ruthenium pentoxide composite material comprises a ruthenium pentoxide composite material containing a doping ions and / or a coating layer. The ruthenium pentoxide composite material has excellent potassium ion transport channels, can realize rapid insertion and de-intercalation of potassium ions, has stable crystal structure, adopts the reaction mechanism of intercalation and pseudocapacitance dual mechanism, prepares the potassium ion battery with the advantages of long cycle life, high specific capacity and low cost, can solve the problem of priceincrease caused by insufficient lithium resources, avoids the problems of expansion and pulverization of the alloy-type negative electrode of the potassium ion battery, slow dynamics of the intercalated carbon material and the like, and can be widely applied to electric tools, electronic equipment, electric vehicles or energy storage equipment.
Owner:SHENZHEN INST OF ADVANCED TECH

Positive electrode plate and lithium ion battery

The invention provides a positive electrode plate and a lithium ion battery. The positive electrode plate comprises a positive current collector and a positive slurry deposited on the surface of the positive current collector. The positive current collector is a foamed aluminum foil. The positive slurry comprises, in percentage by weight, 92%-98% of positive active substance, 0.05%-2% of conductive agent, 1%-2.5% of PVDF and 0.05%-2% of single-walled carbon nanotube. The lithium ion battery comprises a positive electrode plate and the negative electrode plate. The positive electrode plate comprises a positive current collector and a positive slurry deposited on the surface of the positive current collector. The negative electrode plate comprises a negative current collector and a negative slurry deposited on the surface of the negative current collector. The positive slurry comprises, in percentage by weight, 92%-98% of positive active substance, 0.05%-2% of conductive agent, 1%-2.5% of PVDF and 0.05%-2% of single-walled carbon nanotube. The negative slurry comprises, in percentage by weight, 93%-96% of positive active substance, 0.05%-2% of conductive agent, 1%-3% of LA133.
Owner:OPTIMUM BATTERY CO LTD

Zinc ion battery positive electrode active material, positive electrode material, zinc ion battery positive electrode, zinc ion battery and preparation method and application thereof

The invention discloses a zinc ion battery positive electrode active material, a positive electrode material, a zinc ion battery positive electrode, a zinc ion battery and a preparation method and application thereof, and relates to the technical field of zinc ion batteries. The zinc ion battery positive electrode active material comprises niobium oxide or a composite material thereof. According to the invention, the niobium oxide or the composite material of the niobium oxide is applied to the positive electrode active material of the zinc ion battery. The niobium oxide or the niobium composite material has a rapid zinc ion transmission channel, so that the rapid intercalation and deintercalation of zinc ions can be realized. The prepared zinc ion battery has the advantages of long cyclelife, high specific capacity and low cost. The problems of limited lithium resource reserve and high cost of the existing lithium ion battery are solved. The problems of low capacity, poor stability of a positive electrode structure, slow intercalation dynamics and the like of the existing zinc ion battery positive electrode active material are solved.
Owner:SHENZHEN INST OF ADVANCED TECH

Ultrahigh specific capacity mesoporous Co3O4 nanosheet electrode material and preparation method thereof

The invention provides an ultrahigh specific capacity mesoporous Co3O4 nanosheet electrode material and a preparation method thereof. The preparation method comprises the following steps that 1) foam nickel is adopted to act as the three-electrode system of a working electrode, the mixed aqueous solution of Co(NO3)2 and KCl acts as an electrolyte solution, and a Co(OH)2 nanosheet is deposited on the surface of foam nickel through constant current so that a Co(OH)2 nanosheet precursor is acquired; and 2) the Co(OH)2 nanosheet precursor acquired in the step 1) is cleaned and dried, and then high temperature annealing is performed at temperature of 350-450 DEG C so that the mesoporous Co3O4 nanosheet electrode material is acquired. According to the preparation method of the ultrahigh specific capacity mesoporous Co3O4 nanosheet electrode material, the preparation method has the characteristics of being simple in technology, green and environment-friendly and low in cost, and the acquired Co3O4 nanosheet electrode material has relatively high specific capacity.
Owner:SOUTH CHINA NORMAL UNIVERSITY

Composite lithium-rich manganese-based cathode material and preparation method thereof

ActiveCN106711412AUniform thicknessFacilitate migration and diffusionCell electrodesSecondary cellsHigh rateMass ratio
The invention relates to a composite lithium-rich manganese-based cathode material and a preparation method thereof, belonging to the field of chemical energy storage batteries. The cathode material is a composite material with a core-shell structure; a NaZr2(PO4)3 coating layer with uniform deposition thickness is prepared on the surface of the lithium-rich manganese-based cathode material by a complexing method; and by changing the mass ratio of the NaZr2(PO4)3 to lithium-rich manganese-based cathode material, coating layers different in morphology, structure and arrangement can be obtained. With the NaZr2(PO4)3 coating layer, the relocation diffusion of Li<+> is improved in different degrees, which shows the improvement of electrochemical performance in varying degrees; and moreover, the composite lithium-rich manganese-based cathode material can realize high-rate charge / discharge of a battery so as to enhance the cycling stability of the battery.
Owner:BEIJING INSTITUTE OF TECHNOLOGYGY

Metal lithium composite negative electrode material and preparation method thereof

The invention relates to the field of lithium ion batteries, in particular to a metal lithium composite negative electrode material and a preparation method thereof. The preparation method is furtherbased on electroplating process and includes: taking a carbon nanotube thin film as an electroplating substrate, and electroplating a metal coating with certain thickness to improve electronic conductivity of the material; distributing metal lithium particles in the hollow inside of a non-lithium metal coating-carbon nanotube compound and / or gaps in the non-lithium metal coating-carbon nanotube compound in a non-lithium metal coating-carbon nanotube composite thin film to obtain the metal lithium composite negative electrode material. The advantages of high strength of carbon nanotubes and high conductivity of hollow structure and the non-lithium metal coating are combined to support stabilizing and quick disembedding of the metal lithium active material so as to improve cycling stabilityof the material.
Owner:UNIV OF ELECTRONIC SCI & TECH OF CHINA

A kind of preparation method and application of large particle sodium chromite material

The invention relates to a preparation method and application of a large particle sodium chromite material, belonging to the technical field of sodium ion batteries. In the method of the invention, sodium dichromate is put into a crucible, and roasted under a reducing atmosphere, the roasting temperature is controlled at 800-900 DEG C, and the holding time is 3-24 hours. After the roasting is completed, it is cooled with the furnace, and the product obtained is NaCrO 2 Material. The large particle NaCrO prepared by the method of the present invention 2 The particle size is 10-1000 μm, with excellent electrochemical performance and high tap density; the preparation process is simple, the raw material is cheap, the product is single, low consumption and environmental protection, and it is convenient to realize large-scale production. The prepared sodium chromite The material is used as a positive electrode material in a sodium-ion battery, and the resulting sodium-ion battery has high specific capacity, good rate performance and excellent cycle stability.
Owner:CENT SOUTH UNIV

Sodium ion battery negative electrode material and preparation method thereof

The invention discloses a sodium ion battery negative electrode material and a preparation method thereof. The preparation method comprises the steps that spiral nanometer carbon fibers are prepared at low temperature through a chemical vapor deposition method, then the spiral nanometer carbon fibers are carbonized and acidified in sequence, finally, a molybdenum source, a sulfur source and the acidified spiral nanometer carbon fibers are mixed, and then the mixture is put into a reaction kettle for hydrothermal reaction, and then is subjected to centrifuging, freeze-drying and annealing to obtain the sodium ion battery negative electrode material. The sodium ion battery negative electrode material prepared by the method has good conductivity and cycling stability.
Owner:SICHUAN UNIVERSITY OF SCIENCE AND ENGINEERING

Regenerated ternary cathode material and preparation method thereof

The invention relates to the field of waste and old lithium battery recovery, and provides a regenerated ternary cathode material and a preparation method thereof, wherein a method for preparing the regenerated the ternary cathode material comprises the following steps of extracting a devitalized ternary cathode material; dissolving the devitalized ternary cathode material by an acetic acid solution to obtain a first mixed solution; mixing the first mixed solution with an oxalic acid solution to obtain a first suspension solution; filtering the first suspension solution to obtain a first precipitate and a second mixed solution; after the second mixed solution and a sodium hydroxide solution are mixed and the pH is regulated to an alkaline state, mixing obtained materials with sodium carbonate to obtain second suspension; filtering the second suspension to obtain a third mixed solution and a second precipitate; mixing the first precipitate, the second precipitate, ethyl alcohol, saccharose and long chain organic substances to obtain a mixture; performing ball milling and ignition on the mixture to obtain precursor powder; performing high-temperature calcination on the precursor powder to obtain a short-rod-shaped regenerated ternary cathode material. The regenerated ternary cathode material has a one-dimensional diffusion passage; in the charging and discharging process, the lithium ion migration path is short; the excellent electric chemical performance is realized.
Owner:上海鎏明科技有限公司

A kind of lithium cobalt phosphate cathode material and preparation method for lithium ion battery

The invention relates to the technical field of lithium ion batteries, and provides a lithium cobalt phosphate positive electrode material for a lithium ion battery and a preparation method thereof. According to the invention, doping is performed on the lithium cobalt phosphate by Fe3+; modified multi-walled carbon nanotubes are added during the preparation of precursor particles so that the carbon nanotubes partially coat the surfaces of the particles, and are partially embedded in the particles; then sintering is performed to obtain composite particles where the carbon nanometers are interpenetrated with the Fe3+ doped lithium cobalt phosphate; then polypyrrole is synthesized in situ on the surfaces of the composite particles; high temperature treatment is further performed to convert the polypyrrole into a nitrogen-doped carbon layer; and the carbon nanotubes on the surfaces of the lithium cobalt phosphate particles are connected together to form a dense conductive network, therebyobtaining a lithium cobalt phosphate positive electrode material. Compared with the conventional method, by use of the preparation method of the invention, the electronic conductivity and ionic conductivity of the lithium cobalt phosphate positive electrode material can be significantly improved; the decomposition of the electrolyte is inhibited; the specific capacity is increased; and the cycle performance is improved.
Owner:GUIZHOU RONGBAI LITHIUM BATTERY MATERIAL CO LTD

Battery negative plate, preparation method thereof and lithium ion battery

The invention belongs to the technical field of lithium ion batteries, and relates to a battery negative plate, a preparation method thereof and a lithium ion battery. The negative plate comprises a negative current collector, a first active substance layer positioned on the negative current collector, and a second active substance layer positioned on the first active substance layer, wherein thefirst active material layer comprises a first active material, a first conductive agent and a first binder; the second active substance layer comprises a second active substance, a second conductive agent and a second binder; the capacity of the first active substance for storing lithium ions is greater than that of the second active substance for storing lithium ions; and the ability of the second active material to deintercalate lithium ions is greater than the ability of the first active material to deintercalate lithium ions. In the large-current charging and discharging process, the battery with the battery negative plate can rapidly deintercalate and intercalate lithium ions, the risk of surface lithium precipitation is remarkably reduced, and the power and safety of the battery areimproved.
Owner:RISESUN MENGGULI NEW ENERGY SCIENCE & TECHNOLOGY CO LTD

Negative electrode material, preparation method thereof and sodium ion battery containing negative electrode material

The invention discloses a negative electrode material, a preparation method thereof and a sodium ion battery containing the negative electrode material. The preparation method comprises the followingsteps that (1) an inorganic salt aqueous solution is prepared, then chitin or chitin derivative powder is added, a cosolvent is slowly added, and the materials are continuously stirred or ultrasonically treated to obtain uniform sol; (2) the sol obtained in step (1) is frozen and subjected to vacuum drying to obtain a fluffy precursor; (3) high-temperature calcination is conducted on the precursorobtained in step (2) in an inert atmosphere, inorganic salt fusion and evaporation characteristics are used in the carbonization process of the chitin or the chitin derivative powder, and the poroushard carbon material is prepared in situ. The negative electrode material is of a cross-linked hole structure, and is large in specific surface and rich in nitrogen element. The high electron conductivity of the material is ensured by rich nitrogen elements, meanwhile, a three-dimensional cross-linked network is beneficial to rapid disembedding of sodium ions in the material, high-capacity and high-rate charging and discharging of the battery are realized, and the cycling stability of the battery is improved.
Owner:BEIJING INSTITUTE OF TECHNOLOGYGY

A kind of preparation method of sodium ion battery cathode material na3v2(po4)3

The invention discloses a preparation method of a sodium-ion battery cathode material Na3V2(PO4)3. The method comprises the following steps: (1) mixing a sodium salt, a vandic salt, phosphate, a complexing agent, a high-molecular compound and a solvent to obtain a Na3V2(PO4)3 spinning solution; (2) carrying out electrostatic spinning on the Na3V2(PO4)3 spinning solution to obtain a Na3V2(PO4)3 spinning precursor; and (3) collecting the Na3V2(PO4)3 spinning precursor, carrying out thermal treatment on the Na3V2(PO4)3 spinning precursor in an inert atmosphere and cooling the Na3V2(PO4)3 spinning precursor to obtain the sodium-ion battery cathode material Na3V2(PO4)3. According to the sodium-ion battery cathode material Na3V2(PO4)3 prepared by the method disclosed by the invention, high-capacity charging and discharging of the battery can be realized; and the cycle stability of the battery can be improved.
Owner:BEIJING INSTITUTE OF TECHNOLOGYGY

Nanosheet-shape potassium ion battery cathode material, preparation method thereof and potassium ion battery

The invention discloses a nanosheet-shape potassium ion battery cathode material, a preparation method thereof and a potassium ion battery. The molecular formula of the nanosheet potassium ion batterycathode material is K2CuxZn1-x[Fe(CN)6], wherein x satisfies the relation of 0<=x<=1. The preparation method of the nano-platelet potassium ion battery cathode material comprises the following steps:dissolving potassium ferrocyanide in a deionized water solution to obtain a solution A; dissolving soluble copper salt and soluble zinc salt in an alcohol solution, and conducting heating while stirring to obtain a solution B; dropwise adding the solution B to the solution A, and performing a precipitation reaction under ultrasonic assistance to obtain a precipitated product; and washing and drying the precipitated product to obtain the nano-platelet potassium ion battery positive electrode material. The preparation method is simple, and short in cycle; the prepared material can be used without other treatment processes; the prepared K2CuxZn1-x[Fe(CN)6] has good crystallinity; and the nanosheet shape effectively shortens the potassium ion transport path, so that the assembled potassium-ion batteries have high first-time coulombic efficiency and long cycle life.
Owner:HEFEI NORMAL UNIV

Composite nano material and preparation method and application thereof

The invention provides a nano composite material and a preparation method and application thereof. The preparation method comprises the steps that acidified carbon nanotubes serve as a raw material; firstly, polyethyleneimine is used for modification treatment to prepare modified carbon nanotubes; then the modified carbon nanotubes react with epoxidized cellulose, and a carbon nanotube-cellulose compound is generated; and finally, the carbon nanotube-cellulose compound is sequentially subjected to nitrogen doping and phosphorus and copper doping to acquire the composite nano material. The composite nano material can be used as a battery negative electrode material, and is high in electric capacity, excellent in cycle performance and good in electrical property.
Owner:杭州鼎友五金机械制造有限公司

Novel surface carbon modified layered lithium-rich ternary positive electrode composite material and preparation method thereof

The invention discloses a novel surface carbon modified layered lithium-rich ternary positive electrode composite material and a preparation method thereof. The invention uses a template method to prepare the surface carbon modified layered lithium-rich ternary material, and solves the problem of structural stability of the layered lithium-rich ternary material. The synthesized material has a highspecific capacity and good cycle stability as a lithium ion battery positive electrode material.
Owner:ZHEJIANG UNIV OF TECH
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