The invention discloses silicon-free liquid shampoo with hair care efficacy. The silicon-free liquid shampoo is prepared from, by weight, 8-15 parts of sodium laureth sulfate, 3-5 parts of dodecyl betaine, 0.5-2 parts of pentaerythritol stearate, 1-3 parts of tea saponin, 0.5-1.5 parts of ginger oil, 15-30 parts of Chinese herbal extract, 0.2-1.5 parts of citric acid, 0.2-1.0 part of vervain essential oil and 80-120 parts of water. The liquid shampoo is reasonable in formula, good in compatibility among all components, rich in foam, mild in performance, free of organic silicon, free of side effect on hair, rich and fine in foam, moderate in detersive power, easy to rinse and free of irritation to hair, skin and eyes, washed hair is bright, smooth and high in resilience, the hair can be combed well in both the dry and wet conditions, and the itching relieving and scrap removing effects are achieved.