The invention discloses a whole-process low-nitrogen combustion technology applied to a cement kiln for reduction of the cement kiln NOx discharge quantity. Preheaters, a decomposing furnace, a rotary kiln, a coal injection pipe, a tertiary air pipe as well as pulverized coal and raw material feeding of a kiln system are taken as a whole for systematic control, a user starts from inhibition of generation of NOx and reduction of generated NOx to scientifically and reasonably adjust and control the quality of the rotary kiln, the quality of decomposing furnaces, the quality of fuel, the mass of the fuel, reasonable distribution of a combustion device and combustion-supporting air and the like, and the temperature field and the atmosphere field of the kiln are systematically controlled. The technology mainly comprises a cooling machine (1), the rotary kiln (2), a kiln head pulverized coal combustion device (3), the decomposing furnace (4), a kiln tail pulverized coal combustion device (5), the tertiary air pipe (6), an air dividing pipe (7) of the tertiary air pipe (6), a fourth-stage suspending preheater (8), a fifth-stage suspending preheater (9) and a discharging pipe (10), wherein the rotary kiln (2) comprises an oxidation zone (11) and a reduction zone (12), and the decomposing furnace (4) comprises an oxidation zone (13) and a reduction zone (14).