Anti-microbial coating prepared from photon up-conversion material and preparation method thereof
A photon up-conversion and antibacterial coating technology, applied in the direction of luminescent materials, coatings, chemical instruments and methods, etc., can solve the problems of low ultraviolet light intensity and limit the application of titanium dioxide
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Embodiment 1
[0049] The present embodiment provides a kind of preparation method of antibacterial coating, comprises the following steps:
[0050] (1) Up-conversion material NaYF 4 : Yb 3+ , Er 3+ Synthesis
[0051] Mix 12 mL of yttrium nitrate, 20 mL of ytterbium nitrate and 9 mL of erbium nitrate together and keep stirring for 30 minutes, wherein the concentration of yttrium nitrate is 0.2 mol / L, the concentration of ytterbium nitrate is 0.01 mol / L, and the concentration of erbium nitrate is 0.01 mol / L; 20 mL of sodium nitrate with a concentration of 2 mol / L was added to the obtained mixture, and continued stirring for 30 minutes; then, 30 mL of ammonium fluoride with a concentration of 2 mol / L was added to the mixture obtained through the previous step, and continued Stir for 15 minutes; add 0.05mol / L ethylenediammonium tetraacetic acid to the above mixture as a stabilizer, the volume of addition is 20mL, and continue stirring for 40 minutes; put the mixture obtained in the previous ...
Embodiment 2
[0057] The present embodiment provides a kind of preparation method of antibacterial coating, comprises the following steps:
[0058] (1) Up-conversion material NaYF 4 : Yb 3+ , Er 3+ Synthesis
[0059] Mix 12 mL of yttrium nitrate, 20 mL of ytterbium nitrate and 9 mL of erbium nitrate together and keep stirring for 30 minutes, wherein the concentration of yttrium nitrate is 0.5 mol / L, the concentration of ytterbium nitrate is 0.1 mol / L, and the concentration of erbium nitrate is 0.01 mol / L; 20 mL of sodium nitrate with a concentration of 2 mol / L was added to the obtained mixture, and continued stirring for 30 minutes; then, 30 mL of ammonium fluoride with a concentration of 2 mol / L was added to the mixture obtained through the previous step, and continued Stir for 15 minutes; add 0.5mol / L ethylenediammonium tetraacetic acid to the above mixture as a stabilizer, and add a volume of 10mL, and continue stirring for 40 minutes; put the mixture obtained in the previous step int...
Embodiment 3
[0065] The present embodiment provides a kind of preparation method of antibacterial coating, comprises the following steps:
[0066] (1) Up-conversion material NaYF 4 : Yb 3+ , Er 3+ Synthesis
[0067] Mix 12mL of yttrium nitrate, 20mL of ytterbium nitrate and 9mL of erbium nitrate together and keep stirring for 30 minutes, wherein the concentration of yttrium nitrate is 0.3mol / L, the concentration of ytterbium nitrate is 0.03mol / L, and the concentration of erbium nitrate is 0.01 mol / L; Add 20 mL of sodium nitrate with a concentration of 2 mol / L to the resulting mixture, and continue to stir for 30 minutes; then, add 25 mL of ammonium fluoride with a concentration of 2 mol / L to the above mixture, and continue to stir for 15 minutes; Add 0.4mol / L ethylenediammonium tetraacetic acid as a stabilizer to the above mixture, the added volume is 10mL, and keep stirring for 40 minutes; put the mixture obtained in the previous step into the autoclave, and seal the autoclave , maint...
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