This invention relates to the field of atmospheric
trace gas detection technology, specifically disclosing an ultra-high sensitivity online detection
system and method for atmospheric BrO radicals. The ultra-high sensitivity online detection
system for atmospheric BrO radicals includes an
optical cavity, a 340 nm
ultraviolet light source, an
ultraviolet optical fiber, an
ultraviolet spectrometer, and a sampling unit. The
optical cavity has an inlet and an outlet, and contains an ultraviolet
optical resonance region.
Ultraviolet light emitted from the
ultraviolet light source is reflected multiple times in the ultraviolet
optical resonance region and then transmitted into the ultraviolet
optical fiber. The ultraviolet
optical fiber is used to superimpose all
transmitted light in the ultraviolet band and transmit it to the ultraviolet
spectrometer. The sampling unit is used to directly input the gas to be measured into the
optical cavity, or to selectively remove BrO radicals from the gas to be measured before inputting it into the optical cavity. This invention achieves ultra-high sensitivity online point detection of BrO radicals in the
atmosphere. Compared with existing technologies at home and abroad, its BrO
detection limit is better than 1 pptv, reaching the sub-pptV level, demonstrating excellent
detection performance.