449 results about "Microwave assisted" patented technology

The invention relates to the technical field of sole processing, in particular to a sole composite processing method, which comprises the following steps: according to the rigidity requirement of an arch support area, preparing high-density slurry in which silicon nitride ceramic powder accounts for 30-40%, forming # imgabs0 # crystal phase through microwave-assisted sintering, and controlling the porosity to be 10-20%; according to the energy rebound requirement of the forefoot buffer area, graphene oxide / carboxymethyl cellulose aerogel powder is added into the slurry until the concentration is 25%, and the porosity is increased to 40-60% by combining the honeycomb porous network design; a nano silicon dioxide reinforcing agent is introduced into a wear-resistant area of the heel to 15%, a diamond-like carbon coating is formed through plasma surface treatment, and the porosity is limited to be 5-15%. According to the invention, silane is encapsulated by adopting polyurea microcapsules, and is released only when the material is damaged, so that dynamic self-repairing is realized, the shoe sole is endowed with dynamic repairing capability, and the service life is prolonged.

The invention relates to a preparation technology of a gel polymer lithium ion battery cell electrolyte, and belongs to the field of battery preparation technologies, the preparation technology comprises the following steps: mixing methacrylate monomers and silane monomers according to a mass ratio of 3: 1-5: 1, adding 1-3% of an initiator, and carrying out prepolymerization at 60-80 DEG C for 1-3 h to prepare a prepolymer solution; mixing with a non-aqueous solvent containing lithium hexafluorophosphate according to a mass ratio of (1: 4)-(1: 6) to form a precursor mixed solution, and controlling the injection rate to be 1.5-2.5 g / Ah to a gap between a battery cell pole piece and a diaphragm; after standing for 2-4 hours at the vacuum degree of less than or equal to-0.08 MPa, curing for 3-6 hours at the temperature of 60-70 DEG C to form a gel polymer electrolyte; the wettability is improved through pole piece surface hydrophilic treatment, 1-5% of vinylene carbonate is added to optimize an SEI film, the prepolymerization temperature fluctuation is controlled to be smaller than or equal to + / -2 DEG C through microwave-assisted heating, the pressure of 0.2-0.5 MPa is applied after injection to promote uniform permeation, a polyvinylidene fluoride coating of 5-10 microns is coated after curing to enhance protection, and the interface performance is ensured through an alternating-current impedance test.

The invention relates to the technical field of glass strengthening, in particular to a microwave-assisted glass strengthening process which comprises the following steps: (1) a preheating stage: preheating glass to 300-350 DEG C for 30-60 minutes by adopting microwaves; (2) superficial layer exchange stage: putting the glass into first fused salt, strengthening for 1-2 hours at the temperature of 390-410 DEG C, and simultaneously adopting low-frequency microwave to assist in strengthening; and (3) a deep exchange stage: putting the glass into second fused salt, strengthening at the temperature of 420-430 DEG C for 3-4 hours, and meanwhile, adopting high-frequency microwaves to assist in strengthening. According to the method, the temperature difference between the surface and the interior is reduced by adopting microwave-assisted glass strengthening and microwave penetrability heating, and microcracks caused by local overheating can be avoided, so that the uniformity of an ion exchange layer is improved, and the method is suitable for strengthening various special-shaped glass; microwaves directly act on reactants, so that the ion exchange time can be shortened by 40-60%, the energy consumption is reduced, and the efficiency is improved.

The invention relates to the field of caprolactam production, and discloses a green and efficient production process and device. The process comprises the following steps: continuously oximating cyclohexanone and hydroxylamine in a microreactor under the catalysis of mesoporous silica solid acid; carrying out gas phase rearrangement on cyclohexanone-oxime in the presence of a ZSM-5 molecular sieve under the assistance of microwaves; coupling, rectifying and purifying the crude product through a four-stage molecular sieve membrane; and performing catalytic cracking on the by-product to obtain N2 / H2O and recycling. The device comprises a micro-reaction unit, a microwave-radial reactor, a membrane coupling rectifying tower group and a tail gas cracking unit. Zero emission of ammonium sulfate is achieved, the product purity is larger than or equal to 99.95%, and energy consumption is reduced by 45%.

The invention relates to the technical field of grain and oil processing, in particular to a flaxseed microwave-assisted wall breaking and nitrogen protection cold pressing process. The method comprises the following steps: putting flaxseeds into a microwave bin, carrying out intermittent microwave treatment, and carrying out blank rolling treatment on the flaxseeds by adopting a double-helix blank rolling mill to obtain crude oil; and after degumming, deacidifying, decolorizing and deodorizing the crude oil, filtering the crude oil to obtain refined oil. According to the method, the flaxseed cell wall rupture rate is increased through microwave pretreatment, more grease can be released, the grease flow resistance can be reduced, the released grease can be rapidly separated from a fiber network and resorption is reduced through a nitrogen-assisted pressing mode, and after first-time cold pressing, oil cakes are subjected to secondary microwave treatment, so that the flaxseed oil yield is improved. The method can further destroy residual cell structures, and can prevent oil cake hardening caused by oxidation under the protection of nitrogen, so that the oil yield during secondary repressing is increased.

The invention relates to a purification method of high-purity diamond, and relates to the technical field of diamond purification. The purification method comprises raw material pretreatment, microwave-assisted ionic liquid stripping, solid-liquid separation and ionic liquid recovery, deep purification, separation and drying, and the raw material pretreatment comprises the following steps: crushing an impurity-containing coarse diamond raw material into particles of 2-5mm, then carrying out wet ball milling in ethanol for 4-6 hours, refining the particles to 50-200 microns, and carrying out microwave-assisted ionic liquid stripping on the particles to obtain refined particles; immersing the particles into a mixed solution of 10% diluted hydrochloric acid and 2% ammonium bifluoride, performing ultrasonic treatment for 2 hours, and performing centrifugal washing with ultrapure water until the particles are neutral; the microwave-assisted ionic liquid stripping method comprises the following steps: mixing the pretreated raw material with an ionic liquid according to a mass ratio of 1: (5-10), and carrying out microwave treatment for 10-30 minutes to obtain a reaction mixture. According to the purification method, diamond impurities are efficiently removed, meanwhile, the surface structure of the diamond can be protected against damage, waste liquid can be recycled, and the influence on the environment is small.

The invention relates to a textured KCu7S4 thermoelectric material and a preparation method thereof, and the method comprises the steps: sequentially adding a prepared KOH aqueous solution, CuCl2. 2H2O and Na2S. 9H2O into a high-pressure kettle, and fully stirring for dissolving; dropwise adding an N2H4.H2O aqueous solution into the mixed solution, fully stirring, sealing, transferring to a microwave chemical synthesis instrument, heating, keeping stirring, and reacting at a target temperature and self-generated pressure to generate a KCu7S4 nanowire preferentially growing along a [001] crystal orientation; and after the reaction is finished and natural cooling is carried out, a product is collected through centrifugation, full cleaning and vacuum drying are carried out, and then the KCu7S4 thermoelectric material with [001] preferred orientation in the direction perpendicular to the pressure direction is obtained through spark plasma sintering. According to the method, a surfactant and an organic solvent are not used, and macro, rapid, efficient and controllable preparation of the KCu7S4 nanowire is realized through a low-temperature, low-cost and low-energy-consumption microwave-assisted hydrothermal process.

The invention relates to the technical field of carbon black materials, and discloses special carbon black with high specific surface area and a preparation method thereof, and the special carbon black is prepared by pyrolysis and activation treatment of a precursor mixture, a catalyst and a template agent. The precursor mixture contains a biomass refined product, waste polymer pyrolysis oil and a copolymer template agent, and the performance is optimized through a rotating flow field high-temperature reactor and a microwave-assisted activation process. The carbon black has a hierarchical porous structure, the specific surface area reaches 2000-2500m < 2 > / g, the conductivity is improved by 1-2 orders of magnitude, and the chemical properties can be regulated and controlled through surface functionalization. The low-cost and sustainable production is realized, the mechanical strength, the conductivity and the adsorption performance are remarkably improved, and the requirements of the high-end field are met.

The invention relates to a preparation method of a microwave-assisted synthesized near-infrared electrochemical luminescence gold nanocluster and application of the gold nanocluster in miRNA (micro Ribonucleic Acid) detection. The preparation method comprises the following steps: under a stirring condition, adding a gold source and alkali into a Met solution to obtain a mixed solution, carrying out microwave irradiation reaction, and carrying out solid-liquid separation to obtain a Met-Au NCs solution; the preparation method comprises the following steps: activating a Met-Au NCs solution by using EDC and NHS, adding a DNA solution, mixing, and dialyzing to obtain a Met-Au NCs-DNA compound, namely the near-infrared electrochemical luminescence gold nanocluster. Compared with Au NCs prepared by a common mild method, the Met-stable Au NCs prepared by a microwave-assisted method has the advantage that the fluorescence and electrochemical luminescence efficiency at 835 nm is improved. The invention also provides a'signal closing 'ECL (electron cyclotron ligand) biosensor for high-sensitivity detection of the miRNA-107 (MicroRNA-107), and a method for detecting the miRNA-107 (MicroRNA-107). The sensor is simple to operate and good in repeatability, and has important scientific significance and application value for clinical early diagnosis of cancers.

The invention relates to a preparation method of small-molecular-weight sea cucumber oligopeptide, the prepared sea cucumber oligopeptide and application, and belongs to the technical field of skin care products. The preparation method of the small-molecular-weight sea cucumber oligopeptide comprises the following steps: preparing sea cucumber fine powder; adding the sea cucumber fine powder into ultrapure water, adding papain and EDTA (Ethylene Diamine Tetraacetic Acid), and carrying out enzymolysis under the assistance of microwaves; adding trypsin and calcium ions, and carrying out enzymolysis under the assistance of microwaves; adding neutral protease and zinc ions, and performing enzymolysis under the assistance of microwaves to obtain final sea cucumber enzymatic hydrolysate; and decolorizing, separating and purifying, and freeze-drying to obtain the powdery small-molecular-weight sea cucumber oligopeptide. According to the preparation method of the small-molecular-weight sea cucumber oligopeptide, microwave heating and enzymolysis reaction are combined, the hydrolysis degree of a peptide chain is regulated and controlled by controlling an enzyme hydrolysis sequence and enzymolysis conditions, the small-molecular-weight sea cucumber oligopeptide with relatively concentrated and moderate molecular weight is prepared, and good biological activity of the sea cucumber oligopeptide is kept.

The present invention relates to the technical field of lithium-ion battery recycling and utilization, and specifically discloses a method for recycling and regenerating positive electrode materials from waste ternary lithium-ion batteries. The present invention uses a ternary deep eutectic solvent combined with microwave-assisted leaching to efficiently leach waste lithium-ion battery positive electrode materials, and then combines subsequent precipitation and adjustment of the molar ratio of metal elements to regenerate the positive electrode materials. The obtained recycled and regenerated positive electrode materials have good electrochemical properties. The technical solution provided by the present invention effectively solves the problems of high cost and complicated process flow of the existing method for recycling metals from waste ternary lithium-ion batteries, and the problem that when the recovered metals are used to prepare lithium battery positive electrode materials, the purity is insufficient, resulting in poor effect of the regenerated positive electrode materials. It provides a new idea for the treatment of waste ternary lithium-ion batteries.

The invention provides a heavy oil thermal-flow coupling development experimental device and method based on microwave-assisted gravity drainage, and belongs to the field of oil-gas field development. The experimental device comprises a three-dimensional oil reservoir simulation system, a microwave-assisted heating system, a horizontal well injection-production regulation and control system and a multi-field monitoring system; the microwave auxiliary heating system comprises a microwave generation regulation and control system, a microwave transmission system and a shaft integrated microwave radiator, the microwave generation regulation and control system comprises an industrial grade microwave generator, a power regulator and a PLC, and the microwave transmission system comprises a microwave coaxial cable and a microwave waveguide tube bundle; and the microwave generator is continuously connected with the microwave waveguide tube bundle and the shaft integrated microwave radiator. According to the heavy oil thermal-flow coupling development experimental device and method based on microwave-assisted gravity oil drainage, the technical problems that an existing deep heavy oil thermal recovery experimental device cannot reproduce a'thermal-flow-force 'multi-field coupling environment, the microwave heating adaptability is poor, and the experimental scale and the field deviation is large are solved. The heavy oil thermal-flow coupling development experimental device and method based on microwave-assisted gravity oil drainage solve the technical problems that an existing deep heavy oil thermal recovery experimental device cannot reproduce the'thermal-flow-force' multi-field coupling environment.

The invention belongs to the technical field of road maintenance, and discloses a road concrete pavement layer self-adaptive crushing method based on microwave-assisted resonance, and the specific technical scheme is as follows: a microwave heating device is used for pretreating a cut and divided crushing area, and a concrete layer is weakened through a heating effect of microwave radiation to realize separation of a pavement layer; when it is judged that the temperature of the concrete in the heating area reaches the needed temperature through the thermal infrared imager, the inherent frequency of the concrete is calculated, a calculation result is fed back to the resonance crushing device, and the resonance crushing device enables the pavement layer to generate forced vibration to be crushed by generating excitation frequency; the novel method for crushing the concrete pavement layer based on microwave-resonance energy coupling has the characteristics of being accurate, controllable, efficient, applicable to multiple scenes and the like, and can be matched with an acoustic emission system to realize closed-loop control of concrete crushing, so that the working environment of the concrete pavement layer is greatly improved, and the service life of the concrete pavement layer is prolonged. And the maintenance frequency of the equipment is greatly reduced while the crushing efficiency is improved.

The invention relates to the field of high polymer material recycling, in particular to a technology for manufacturing a conveyor belt by recycling polytetrafluoroethylene. According to the process, the recycled polytetrafluoroethylene material is classified and collected according to sources and the like, impurities are removed through magnetic separation and electrostatic separation, and then microwave-assisted cleaning and activation are performed; then, a bio-based additive, a degradable polymer, a photocatalytic self-cleaning material and the like are adopted for modification treatment, so that the multi-aspect performance of the material is improved; then, the material is processed into the shape of a conveyor belt through a water-assisted injection molding or hot press molding process, and after molding, post-treatment is carried out through plant extract coating protection, recoverable and easy-to-disassemble design. The process is suitable for the requirements of conveyor belts in multiple fields, resource recycling is achieved, environmental protection and economic benefits are achieved, and the manufactured conveyor belt is excellent in performance and can meet the requirements of different working conditions.

The invention discloses a preparation method and application of a wind cap of a circulating fluidized bed gasifier, the wind cap is arranged at the bottom of a gasifier body, the wind cap mainly comprises a wind cap gas inlet, a wind cap gas outlet and a wind cap gas flow channel, and the wind cap gas flow channel is composed of a Tesla valve fluid channel. The air cap is prepared from modified fly ash through a combined method of freezing ball-milling nano modification, 3D printing coupling microwave-assisted sintering and salt bath chromizing strengthening. According to the method, a large amount of solid waste of fly ash can be consumed to realize carbon emission reduction, the efficiency of the circulating fluidized bed can be improved through structural optimization, meanwhile, the preparation cost of the hood can be reduced, and the method has relatively high application and popularization values.

This disclosure describes an apparatus that enables rapid transitions during microwave-assisted magnetic recording (MAMR) of storage media. In various aspects, the apparatus incorporates a driver circuit configured to provide a controlled bias current through separate source and sink output terminals, which respond to feedback signals. An MAMR sensor connects between the source and sink output terminals and generates microwave fields when receiving the controlled bias current from the driver circuit. A common-mode feedback (CMFB) loop connects to the source and sink output terminals, detects common-mode voltage (CMV), and delivers feedback signals to the driver circuit to maintain CMV regulation of the MAMR sensor. A differential voltage regulation loop connects to the source and sink output terminals, providing feedback signals that maintain the MAMR sensor voltage differential at a reference value. The apparatus controls the magnetic recording process of the MAMR sensor with rapid transition times.

The invention discloses equipment and a process for efficiently and continuously extracting astaxanthin by a low-frequency microwave-assisted eutectic solvent method, and belongs to the technical field of bioactive substance extraction. The method for extracting astaxanthin by the low-frequency microwave-assisted eutectic solvent method comprises the following steps: performing low-frequency microwave pretreatment on a eutectic solvent to obtain a high-temperature pretreated eutectic solvent; cooling the pretreated eutectic solvent, then mixing the pretreated eutectic solvent with crustacean byproducts, performing eutectic solvent extraction treatment, performing ultrasonic-assisted extraction in the process, and then performing solid-liquid separation to obtain filtrate; mixing the filtrate with an extraction solvent, and extracting to obtain an extraction solvent phase containing astaxanthin and a eutectic solvent phase; and removing the extraction solvent in the extraction solvent phase containing the astaxanthin to obtain an astaxanthin product.

The invention relates to the field of comprehensive utilization of biomass resources and preparation of high polymer materials, in particular to a green preparation method of high-deacetylation-degree chitin capable of recycling reaction waste liquid. The invention aims to solve the problems of serious environmental pollution, resource waste, low product purity and incomplete waste liquid recycling in chitin extraction. The method comprises the following steps: by taking crustacean biomass as a raw material, firstly carrying out high-voltage pulse electric field pretreatment to crush the tissue structure of the raw material and improve the reaction activity, and then heating and extracting in a choline chloride-lactic acid deep eutectic solvent system to realize efficient removal of proteins and inorganic salts in the raw material; according to the method, the chitin and the alkali liquor are subjected to a rapid deacetylation reaction by adopting microwave assistance and cooperating with the action of the phase transfer catalyst; according to the method, a waste liquid graded recycling system is adopted, hydrochloric acid in waste acid liquid generated by decalcification is recycled through electrodialysis, alkali liquid is recycled through ultrafiltration-nanofiltration double-membrane combination, deep eutectic solvent components are recycled through reduced pressure distillation, and recycling of acid, alkali and a solvent is achieved.

The invention discloses a method for preparing nano copper powder based on a microwave-assisted reduction method and application. The method comprises the following steps: a) preparing a copper ion solution; b) adding a dispersing agent and a surfactant; c) adding a reducing agent; d) microwave heating reaction; e) separating and purifying a product; and f) drying. According to the method, directional reduction and morphology regulation and control of copper ions are achieved through the synergistic effect of a microwave field and chemical reduction, the specific surface area of the obtained product reaches 25-35 m < 2 > / g, the oxygen content is lower than 0.8 wt%, and excellent performance is shown in the fields of electronic packaging and conductive ink; the method has the characteristics of short reaction time (shortened by 90% compared with the traditional method), low energy consumption (less than 0.5 kWh / kg), no harmful by-product and the like, and meets the requirements of green chemical industrial production.

The invention relates to the technical field of oilfield development, in particular to a thick oil viscosity reducer and a preparation method and application thereof. A unique novel nitrogen and sulfur heterocyclic ring-containing monomer is synthesized through multiple steps; the tail end of the amphiphilic block copolymer is silanized, and the nano graphene quantum dots are subjected to microwave-assisted modification. The composite material comprises intelligent response type microcapsules and ionic liquid modified clay. All the components are synergistic, the viscosity can be effectively reduced, and the viscosity reduction effect can be intelligently adjusted under different conditions. The viscosity reduction rate of the thick oil viscosity reducer is high and can reach 70%-90%; the adaptability to complex environment is high, and the preparation process is simple and environment-friendly; and the mining efficiency can be improved, the energy consumption is reduced, the equipment abrasion is reduced, and the economic and environmental benefits are remarkable.

The invention discloses a preparation method of high-capacity X7R type barium titanate-based dielectric ceramic powder, and relates to the field of preparation of barium titanate-based electronic materials, and the preparation method comprises the following steps: pre-synthesizing a rare earth-transition metal composite dopant by adopting a sol-gel method; mixing the obtained rare earth-transition metal composite dopant with a 100-250 nm solid-phase nano barium titanate main material, and adding a glass phase sintering aid; a staged pre-sintering process is adopted; ball-milling the pre-sintered powder by a high-energy ball mill, and sintering in a microwave-assisted atmosphere sintering furnace by adopting a microwave-assisted atmosphere sintering process; according to the design of the composite dopant, atomic-scale uniform doping of rare earth and transition metal is achieved through a sol-gel method, and the problem of component segregation caused by traditional mechanical mixing is solved; a staged pre-sintering process is adopted and is different from traditional single-stage pre-sintering, organic matters are removed in a low-temperature stage to avoid carbon residues, and the grain size is accurately controlled in a high-temperature stage; a contrast experiment shows that the dielectric constant is increased by 15%.

The invention discloses a microwave-assisted laser communication method, which comprises the following steps of: adopting time slot allocation in a task preparation stage, performing transmission of first message information and mutual identification among nodes by utilizing microwaves, and not considering the priority of the first message information in transmission; time slot allocation is adopted in the pointing link establishment stage, and the second message information is transmitted based on the priority of the second message information by utilizing microwaves so as to establish a link and track the node.

The invention belongs to the technical field of waste lithium ion battery recycling, and particularly relates to a method for selectively extracting lithium in a waste lithium battery positive electrode material through microwave-assisted DES. The method comprises the following steps: carrying out ball milling and screening on the waste lithium ion battery positive electrode material to obtain pretreated positive electrode powder; mixing choline chloride and ethylene glycol, heating, stirring and uniformly dissolving to obtain a deep eutectic solvent; and adding the obtained positive electrode powder into a deep eutectic solvent, carrying out microwave heating to 200-230 DEG C, stirring and leaching, filtering the leached mixed solution, taking the filtrate, adding alkali liquor to adjust the pH value to 10-12, filtering to remove the precipitate, heating and concentrating the filtrate, then adding a Na2CO3 solution, precipitating, filtering, taking the solid phase, washing and drying to obtain the lithium carbonate. The method disclosed by the invention can be used for efficiently and selectively leaching and recycling lithium in the positive electrode material of the waste lithium battery.

Partially oxidized carbonaceous materials characterized by substantially homogenous, partially oxygenated surfaces thereof are enabled via microwave-assisted methods that are simple and fast. The exemplary methods include combining carbonaceous material(s), at least one mild oxidizer, at least one nucleophile, and an aqueous solvent system to obtain a mixture; and exposing the mixture to microwave radiation for a predetermined time to produce partially oxidized carbonaceous materials. The predetermined time may be in a range from about 5 seconds to about 2 hours, and the power of the microwave energy may be in a range from about 100 w to about 1700 W. The partially oxidized carbonaceous materials are characterized by a homogeneous distribution of oxygen content in surfaces thereof, in nonzero amounts up to about 10 at %, and a standard deviation of surface oxygen content in a range from about 0.1 at % to about 1.0 at %.

The application relates to the field of high polymer composite materials, and particularly discloses a high-strength and high-toughness wood-plastic composite material based on carboxyl-functionalized ionic liquid modified lignin and a preparation method thereof. The carboxyl-functionalized ionic liquid is covalently grafted with the phenolic hydroxyl group of lignin to form a chemical bond, and the long-chain structure of the carboxyl-functionalized ionic liquid forms physical entanglement at the interface of the wood-plastic composite material, so that the interface bonding strength is improved through the double effects, the tensile property and the bending property are significantly improved, the impact strength can be effectively restored or even improved through improved microwave-assisted homogeneous reaction parameters, and the dilemma of "strengthening and being brittle" is solved.

The invention discloses a bidirectional coupling numerical simulation method for a translation heating process of regular or irregular food in a microwave cavity, and belongs to the technical field of microwave heating. According to the invention, liquid nitrogen is adopted for freezing and homogenizing food samples, so that the accuracy of food electric heating characteristic parameters can be improved; the prediction precision of microwave heating numerical simulation can be improved by adopting a bidirectional coupling translational motion mode. The method for accurate modeling of regular food and platform or round corner approximate modeling of irregular food corners can effectively conform to the finite element and finite time domain difference principle. Aiming at microwave-assisted heating models of various heat sources, the fluid power grid division mode provided by the invention can effectively reduce false cooling phenomena occurring at the initial stage of heating translational motion operation, and is more suitable for the actual microwave-assisted heating treatment process. According to the invention, the time and economic cost of sample testing can be greatly reduced, and accurate prediction of microwave processing temperature changes of regular food and irregular food can be realized.

The invention belongs to the field of coal and oil and gas resource development, and particularly discloses an in-situ mining simulation experiment method and device for microwave fragmentation and pyrolysis of oil-rich coal, and the method comprises the following steps: S1) processing and manufacturing an oil-rich coal sample or a coal rock combination; s2) putting the sample into a sealed wave-transparent reaction chamber of a microwave irradiation cabin, and simulating the stress state of the coal seam through a microwave wave-transparent pressure head by utilizing a servo control device; s3) simulating a coal bed gas environment through gas injection of an atmosphere device; s4) carrying out microwave irradiation and collecting a pyrolysis gas-liquid product, and meanwhile, obtaining experimental data in the irradiation process; and S5) cleaning and dissolving the pyrolysis liquid product to obtain the tar quality and analyze the components of the tar, screening the sample to obtain a grain composition curve, comparing the calorific values of the coal sample before and after the experiment, and evaluating the effects of microwave fragmentation pyrolysis of the coal sample and oil gas extraction by combining experimental data. Quantitative reference and basis can be provided for selection of microwave conditions in microwave-assisted in-situ mining.

The invention relates to the technical field of carbon nanosheet preparation, and discloses a carbon nanosheet precursor ratio intelligent decision-making method based on machine learning. Data collection: collecting data samples of different mass ratios, corresponding preparation parameters and performance indexes of the carbon nanosheets of the citric acid and the urea in the process of preparing the carbon nanosheets by the microwave-assisted method; 2, data preprocessing: preprocessing the collected data samples, including data cleaning, normalization and feature selection, so as to improve data quality and applicability; according to the intelligent decision-making method for the carbon nanosheet precursor proportion based on machine learning, the proportion of citric acid and urea is accurately regulated and controlled through a machine learning model based on historical data and real-time feedback, so that the structure and performance of the carbon nanosheet are better, and the detection sensitivity of an electrochemical sensor to substances such as heavy metal ions Cu is improved; the detection limit is reduced, the anti-interference capability is enhanced, and stable and accurate detection in a complex water environment is ensured.

The invention discloses a waste sulfuric acid treatment method, and relates to the technical field of environmental engineering, the waste sulfuric acid treatment method comprises: a pretreatment module configured with a multi-stage filtering device and a pH adjusting tank and used for removing suspended solids in waste acid and adjusting the acid concentration; a vanadium-titanium-cerium composite catalyst is arranged in the catalytic cracking reactor, sulfuric acid is decomposed at a set temperature under microwave-assisted heating to generate SO2 gas, and meanwhile heat energy is supplied to the pretreatment unit through a waste heat recovery device; the electrochemical separation module comprises a bipolar membrane electrodialyzer and a pulse electrode array and is used for separating and recovering metal ions Fe < 3 + > and Cu < 2 + > from the cracking raffinate and regenerating sulfuric acid with a set concentration; and the intelligent control center integrates an AI algorithm and an Internet of Things sensor, and dynamically optimizes the cracking temperature, the membrane voltage and the material flow. According to the invention, intelligent sorting, directional conversion and closed-loop recovery are taken as the core, and the problems of high energy consumption, difficulty in differential treatment and heavy pollution in waste sulfuric acid treatment are solved.

The utility model discloses a biomass fuel rapid cracking device based on microwave assistance, which comprises a cracking tank, a plurality of groups of magnetrons used for cracking biomass fuel are fixedly mounted at the top of the cracking tank, and a control assembly used for controlling the magnetrons is mounted at the top of the cracking tank. The bottom of the cracking pipe is connected with a baffle plate through a hinge, the baffle plate is used for sealing a discharge port of the cracking tank, and a fixing piece is arranged on the surface of the cracking tank and is used for fixing the baffle plate, the control assembly and the magnetron are arranged, and the control assembly controls the magnetron to generate microwaves to heat biomass fuel; microwaves can directly act on material molecules or atoms, a long-time preheating process is not needed, materials can be rapidly heated, the efficiency is very high, the cracking speed of biomass fuel is increased, the microwaves have very high penetrability and can directly reach the interior of the biomass fuel, and therefore it is guaranteed that the cracking speed of the biomass fuel on the upper side and the cracking speed of the biomass fuel on the lower side are kept consistent.