Cracking catalyst for petroleum hydrocarbon, and preparation method
A technology for cracking catalysts and petroleum hydrocarbons, which is applied in cracking, petroleum industry, catalytic cracking, etc. It can solve problems such as gasoline olefins that are not mentioned, and achieve the effects of reducing production costs and shortening the process flow
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Embodiment 1
[0035] (1) 10 kg REHY molecular sieve (RE 2 o 3 Content 9.0% by weight, Na 2 O content 4.5% by weight, silicon-alumina ratio is 5.2, Qilu Petrochemical Company Catalyst Factory production, the same below) joins 70 kilograms of phosphorus-containing 0.4 weight % (in P 2 o 5 meter) ammonium phosphate solution, the temperature was raised to 60°C, stirred for 2 hours, and filtered. After the molecular sieve filter cake was dried at 120°C, it was calcined at 600°C in air for 0.5 hours.
[0036] (2) 9.16 kg of kaolin with a solid content of 78% was added into 20.8 kg of decationized water for beating evenly.
[0037] (3) 2.76 kilograms of pseudo-boehmite with a solid content of 60% are beaten with 11 kilograms of decationized water, after stirring for 20 minutes, add 365ml of 36% hydrochloric acid (the specific gravity is 1.185 grams / ml) after acidifying for 120 minutes, slowly Add 8% SiO 2 Content modulus is 4.88 kilograms of water glass solutions of 3.1, stirs about 30 minut...
Embodiment 2
[0039] (1) 5 kg of REY molecular sieve (RE 2 o 3 Content 19 wt%, Na 2 O content 1.5% by weight, silicon-alumina ratio is 5.2, Qilu Petrochemical Company Catalyst Factory production, the same below) joins 40 kilograms of phosphorus-containing 0.35 weight % (in P 2 o 5 meter) ammonium phosphate solution, the temperature was raised to 80°C, stirred for 1 hour, and filtered. After the molecular sieve filter cake was dried at 120°C, it was calcined in air at 600°C for 1 hour.
[0040] (2) The same method as in Example 1 was used to prepare phosphorus-containing REHY.
[0041] (3) Add 4.25 kg of aluminum sol with an alumina content of 21% by weight into 8.85 kg of decationized water, start stirring, then add 11.45 kg of kaolin with a solid content of 78%, and beat evenly.
[0042] (4) 2.76 kg of pseudo-boehmite with a solid content of 60% was beaten with 11 kg of decationized water, after stirring for 20 minutes, after adding 294 ml of 98% sulfuric acid for acidification for 12...
Embodiment 3
[0044] (1) The same method as in Example 1 was used to prepare phosphorus-containing REHY.
[0045] (2) 5 kg of REDASY molecular sieve (RE 2 o 3 Content 2 wt%, Na 2 O content 1.3 weight %, silicon-aluminum ratio is 5.2, Qilu Petrochemical Company Catalyst Factory production, the same below) joins 40 kilograms of phosphorus-containing 0.3 weight % (in P 2 o 5 meter) ammonium phosphate solution, the temperature was raised to 80°C, stirred for 1 hour, and filtered. After the molecular sieve filter cake was dried at 120°C, it was calcined in air at 600°C for 1 hour.
[0046] (3) Kaolin slurry was prepared by the same method as in Example 2.
[0047] (4) 1.95 kg of pseudo-boehmite with a solid content of 60% was beaten with 7.8 kg of decationized water, after stirring for 20 minutes, after adding 278 ml of 36% hydrochloric acid for acidification for 120 minutes, slowly adding 8% SiO 2 Content modulus is 4.13 kilograms of water glass solutions of 3.1, stir about 30 minutes, ad...
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