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43results about How to "Improve plastic retention" patented technology

Silane coupling agent modified polycarboxylate superplasticizer and preparation method thereof

The invention discloses a silane coupling agent modified polycarboxylate superplasticizer and a preparation method thereof, belonging to the field of cement additives. The preparation method comprises the following steps: adding a certain amount of acrylic acid into a polyether macromonomer solution, and stirring uniformly; adding a double bond-containing silane coupling agent; stirring the solution to a clear state and continuously stirring; adding an oxidizing agent, an initiator solution and a small monomer solution while keeping the stirring state; after the stirring, curing for 1-2h; adding liquid caustic soda for neutralization and stabilizing the pH value at 6; and adding a silane coupling agent without double bond to obtain a finished product of silane coupling agent modified polycarboxylate superplasticizer. In the invention, a functional group with a siloxane structure is introduced into the main chain of polycarboxylate molecule, and an anchoring ability in chemical bonding strong interaction with cementing material particles is provided for the branch chain of the comb-shaped polycarboxylate superplasticizer; and with the increase of the anchoring ability, the adaptability and slump loss resistance of the superplasticizer can be remarkably enhanced, and the application of the superplasticizer in the field of mineral micropowder dispersion is expanded to a certain degree.
Owner:HAINAN TAIHOO TECH CO LTD

High-strength micro-expansion prestress anchoring grouting material and preparation method thereof

The invention discloses a high-strength micro-expansion prestress anchoring grouting material and a preparation method thereof. The material is prepared from a gelatinization component, a fine aggregate component, an expansion component, an active doped material, a water reducing component, a crack resistant component and a regulation component in a certain weight proportion. The preparation method specifically comprises the following steps: A, adding the gelatinization component, the expansion component, the active doped material, the crack resistant component and the water reducing component in a ball-mill in a designed mass ratio for commonly mixing and grinding, so as to obtain a even powder material; B, at room temperature and normal pressure, grinding until the Blaine specific surface of the material is not less than 350m<2>/kg; and C, evenly mixing and stirring the obtained in the step B with quartz sand prepared in a proportion at the room temperature and the normal pressure so as to obtain the grouting material. The method is practicable and is convenient for operation; the grouting material has high early strength and micro-expansion, thereby effectively compensating the hydration shrinkage of a cement-based material, obviously improving the adhesive strength of an anchor rod and a periphery base, effectively protecting the anchor rod from being corroded and prolonging the service of the anchor rod.
Owner:INST OF ROCK AND SOIL MECHANICS - CHINESE ACAD OF SCI

Preparation method of naphthalene-series water reducing agent

ActiveCN105236798ASolve the defect of poor plastic retention performanceHigh densityMethyl groupPhenol
The invention relates to a preparation method of a naphthalene-series water reducing agent. The method comprises the following steps: (1) methylnaphthalene and phenol are separately sulfonated, such that a sulfonated methylnaphthalene material and a p-hydroxybenzenesulfonic acid material are obtained; (2) the sulfonated methylnaphthalene material is subjected to a hydrolysis reaction; un-reacted methylnaphthalene or homologs thereof are removed through zeotropy; the rest of the sulfonated methylnaphthalene material enters a reaction in the step (3); (3) the sulfonated methylnaphthalene material obtained in the step (2) and the p-hydroxybenzenesulfonic acid material obtained in the step (1) are subjected to a condensation reaction with formaldehyde acidified with concentrated sulfuric acid, such that a condensed material is obtained; and (4) alkali liquid is added into the condensed material obtained in the step (3), such that a neutralization reaction is carried out, until the pH value is 7.5-9; and the naphthalene-series water reducing agent is obtained when the reaction is finished. The naphthalene-series water reducing agent provided by the invention has the excellent performances of good adaptability to cement, good concrete workability, high plasticity-maintaining performance, low concrete gradual loss, high water reducing rate, and the like. The preparation method has the advantages of simple process and easy-to-control reaction conditions. With the method, naphthalene-series water reducing agent production cost can be reduced.
Owner:ZHEJIANG JISHENG CHEM BUILDING MATERIALS

Preparation method of super-sustained release ester-ether crosslinking polycarboxylic acid water reducer

A preparation method of a super-sustained release ester-ether crosslinking polycarboxylic acid water reducer is provided. The method which combines synthesis of an ester water reducer and synthesis of an ether water reducer allows the polycarboxylic acid water reducer synthesized from large monomers containing different chain lengths and simultaneously containing long side chains and short side chains to be researched and developed, and the method which can guarantee good dispersity and good fluidity keeping ability brings conveniences for the concrete construction process. In the esterification reaction process, hydroxyethyl methacrylate is introduced to increase active hydroxy side chains, and the activity of methacrylic acid is effectively controlled, so the esterification rate of a reaction system is high, product performances are high, and the synthetic method of optimized ester polycarboxylic acid water reducer intermediates is researched and developed through utilizing above principles. A certain synergistic effect is reached by introducing high activity ester monomers in the copolymerization process and combining the long side chains and the short side chains of produced polycarboxylic acid, so performances of the ester-ether crosslinking polycarboxylic acid water reducer of the invention are better than the performances of common ester and ether polycarboxylic acids, and the water reducing rate and the fluidity keeping ability are improved.
Owner:湖南加美乐素新材料股份有限公司

Fly ash microsphere-doped C70 high-performance graphene oxide concrete and preparation method thereof

The invention discloses a fly ash microsphere-doped C70 high-performance graphene oxide concrete and a preparation method thereof. A graphene oxide mortar comprises, by mass, 391.85 parts of cement, 166 parts of water, 570 parts of natural river sands, 1205 parts of broken stones, 69.15 parts of fly ash microspheres, 9.22 parts of a polycarboxylate superplasticizer and 17.288 parts of a graphene oxide solution raw material. A preparation method of the graphene oxide mortar includes the following steps: proportioning of above raw materials, mixing of the raw materials, pouring, forming and curing. The preparation method is simple and is easy to operate. The slump of the C70 high-performance concrete prepared in the invention meets engineering requirements, and the C70 high-performance concrete has an excellent chloride ion penetration resistance. The price of the fly ash microsphere-doped C70 high-performance graphene oxide concrete prepared in the invention is half of that of similar products prepared through other technologies; and the cement consumption of the C70 high-performance graphene oxide concrete is 18% less than that of C70 high-performance concrete prepared through C70high-performance concreted design and having same performances. The reduction of the cement consumption facilitates environment protection.
Owner:FOSHAN UNIVERSITY

Manufacturing method of artificial lightweight aggregate or super lightweight aggregate multifunctional concrete

The invention relates to a manufacturing method of artificial lightweight aggregate or super lightweight aggregate multifunctional concrete and belongs to the technical field of novel concrete materials, environmental engineering and construction. Firstly, a special additive C for preparing the artificial lightweight aggregate or super lightweight aggregate multifunctional concrete is manufactured, a shrinkage restraining additive D is manufactured, after cement, mineral powder, coal ash, microbeads, silica powder, water, glass beads, river sand and other materials are weighed in proportion, the materials are mixed according to the process requirement, and the artificial lightweight aggregate or super lightweight aggregate multifunctional concrete is obtained. According to the method, the multifunctional concrete is manufactured from domestic existing concrete raw materials, industrial residues and other materials, and the product has the functions of self-compaction, self-maintenance, low hydration heat, low shrinkage, high durability and high plasticity retention, and can be applied to constructional engineering, civil engineering, traffic engineering and the like. The manufacturing method has the advantages that construction is convenient, quality is easy to guarantee, management is easy and convenient, and cost is low, energy and resources are saved, and the requirements of environmental protection are met.
Owner:冯乃谦 +2

A kind of silane coupling agent modified polycarboxylate water reducer and preparation method thereof

The invention discloses a polycarboxylate water reducer modified by a silane coupling agent and a preparation method thereof. It belongs to the field of cement additives. Add a certain amount of acrylic acid to the polyether macromonomer solution, stir evenly, then add a silane coupling agent containing a double bond, the stirred solution is clear, continue to stir; continue to keep stirring, add oxidant, initiator solution and small Monomer solution; after stirring and aging for 1-2 hours, add liquid caustic soda to neutralize, stabilize the pH value at 6, and then add a silane coupling agent without double bonds to obtain a silane coupling agent-modified polycarboxylate superplasticizer finished product. The synthesis of the present invention introduces a functional group containing a siloxane structure into the main chain of the polycarboxylic acid molecule to provide an anchoring ability for the branched chain of the comb-shaped polycarboxylate superplasticizer to chemically bond and strongly interact with the gelling material particles , the increase of the anchoring capacity can significantly enhance the adaptability and slump retention of the water reducer, and expand the use of the water reducer in the field of mineral powder dispersion to a certain extent.
Owner:HAINAN TAIHOO TECH CO LTD

A kind of preparation method of naphthalene series water reducing agent

ActiveCN105236798BSolve the defect of poor plastic retention performanceHigh densitySuperplasticizerHydrolysis
The invention relates to a preparation method of a naphthalene-series water reducing agent. The method comprises the following steps: (1) methylnaphthalene and phenol are separately sulfonated, such that a sulfonated methylnaphthalene material and a p-hydroxybenzenesulfonic acid material are obtained; (2) the sulfonated methylnaphthalene material is subjected to a hydrolysis reaction; un-reacted methylnaphthalene or homologs thereof are removed through zeotropy; the rest of the sulfonated methylnaphthalene material enters a reaction in the step (3); (3) the sulfonated methylnaphthalene material obtained in the step (2) and the p-hydroxybenzenesulfonic acid material obtained in the step (1) are subjected to a condensation reaction with formaldehyde acidified with concentrated sulfuric acid, such that a condensed material is obtained; and (4) alkali liquid is added into the condensed material obtained in the step (3), such that a neutralization reaction is carried out, until the pH value is 7.5-9; and the naphthalene-series water reducing agent is obtained when the reaction is finished. The naphthalene-series water reducing agent provided by the invention has the excellent performances of good adaptability to cement, good concrete workability, high plasticity-maintaining performance, low concrete gradual loss, high water reducing rate, and the like. The preparation method has the advantages of simple process and easy-to-control reaction conditions. With the method, naphthalene-series water reducing agent production cost can be reduced.
Owner:ZHEJIANG JISHENG CHEM BUILDING MATERIALS

A method for producing multi-functional concrete by utilizing domestic waste power generation waste slag

The invention relates to a method for producing multifunctional concrete from household garbage power generation waste residues, and belongs to the technical field of novel concrete materials and environmental engineering. The method comprises the following steps: mixing the household garbage power generation waste residues with natural sand to obtain mixed sand; mixing the household garbage power-generation waste residues with the grain sizes greater than 5 mm with crushed stones to obtain mixed crushed stones; mixing natural zeolite powder with brucite fibers to prepare a thickening early-strengthening anti-cracking self-curing agent; mixing a polycarboxylate superplasticizer with ultrafine mineral powder to obtain a liquid water-reducing plasticity-maintaining agent; weighing cement, coal ash, silicon powder, mineral powder, the thickening early-strengthening anti-cracking self-curing agent and the mixed crushed stones in a mass ratio, and pouring into a stirrer successively for uniformly stirring to obtain the multifunctional concrete. The concrete prepared by the method has characteristics of self-compaction, self-curing, low hydration heat, low shrinkage, high durability and high plasticity retention property and can be applied to architectural engineering, civil engineering, traffic engineering, city construction engineering and the like. The method has very high economic and social benefits.
Owner:冯乃谦 +3

Polybasic and multifunctional liquid cement grinding aid and production technology thereof

The invention discloses a polybasic and multifunctional liquid cement grinding aid and production technology of the polybasic and multifunctional liquid cement grinding aid. The polybasic and multifunctional liquid cement grinding aid and the production technology of the polybasic and multifunctional liquid cement grinding aid are characterized by comprising the following raw materials of tri ethanol amine, polymerization polybasic alcohol and water. The raw materials comprise, by weight percentage, 60 percent of the tri ethanol amine, 20 percent of the polymerization polybasic alcohol and 20 percent of the water. The production technology comprises the following steps. Firstly, weighing is performed based on proportion, and the raw materials are prepared. Secondly, the water is heated to 80 DEG C by a boiler and put in a reaction kettle, the polymerization polybasic alcohol is added, and meanwhile, the reaction kettle is started for stirring for 20 minutes. The tri ethanol amine is then added and stirred for 3 hours and cooling is performed. Thirdly, after the solution is cooled, the solution is transferred into an end product jar, and production is finished. The liquid cement grinding aid is high in comprehensive use performance, plasticity protection performance of cement mixed plastic soil is improved, and the liquid cement grinding aid has good compatibility with a concrete high-efficiency slushing agent. Comprehensive performance of cement is improved, in addition, the production technology is simple, short in production time, and high in production yield.
Owner:GUIZHOU CHUZHI BUILDING MATERIAL SCI & TECH

Preparation method of super-sustained release ester-ether crosslinking polycarboxylic acid water reducer

A preparation method of a super-sustained release ester-ether crosslinking polycarboxylic acid water reducer is provided. The method which combines synthesis of an ester water reducer and synthesis of an ether water reducer allows the polycarboxylic acid water reducer synthesized from large monomers containing different chain lengths and simultaneously containing long side chains and short side chains to be researched and developed, and the method which can guarantee good dispersity and good fluidity keeping ability brings conveniences for the concrete construction process. In the esterification reaction process, hydroxyethyl methacrylate is introduced to increase active hydroxy side chains, and the activity of methacrylic acid is effectively controlled, so the esterification rate of a reaction system is high, product performances are high, and the synthetic method of optimized ester polycarboxylic acid water reducer intermediates is researched and developed through utilizing above principles. A certain synergistic effect is reached by introducing high activity ester monomers in the copolymerization process and combining the long side chains and the short side chains of produced polycarboxylic acid, so performances of the ester-ether crosslinking polycarboxylic acid water reducer of the invention are better than the performances of common ester and ether polycarboxylic acids, and the water reducing rate and the fluidity keeping ability are improved.
Owner:湖南加美乐素新材料股份有限公司
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