24349 results about "Compositermes" patented technology

The invention belongs to the technical field of high polymer material design and intelligent manufacturing, and discloses a machine learning driven epoxy resin based composite material thermal-mechanical property aided design method, which comprises the following steps: S1, data acquisition and feature construction; s2, performing feature screening; s3, constructing and training an interpretable prediction model; s4, carrying out reverse design and optimization; and S5, performing closed-loop verification and updating. According to the method, the quantitative relation of structure-process-performance is constructed through an interpretable machine learning model, and the contribution mechanism of each factor is revealed by means of SHAP analysis. And finally, reversely designing an optimal epoxy resin monomer structure and a matched curing process according to the performance target. The limitation of a traditional trial and error method is broken through, collaborative optimization of the material structure and the forming process can be achieved, and the development efficiency of the epoxy resin-based carbon fiber composite material is remarkably improved.

The invention discloses a carbon fiber composite material surface modification spraying system and a control method thereof. The system comprises a multi-axis robot, a plasma spray gun, a contact angle measuring probe, a 3D line laser scanner, a hyperspectral imager, an environment sensor and a controller. According to the method, the plasma power and the robot speed are adjusted in real time through contact angle measurement and plasma treatment feedback control, so that the CFRP surface can accurately reach a target value, and the coating adhesive force is improved; 3D line laser scanning and hyperspectral imaging are combined, and the posture, the distance, the wet film thickness and the component uniformity of the spray gun are monitored in real time; based on a prediction model fusing a physical model and a neural network, a self-adaptive fuzzy PID control algorithm is adopted, and the coating flow and the track posture of a spray gun are accurately regulated and controlled in real time. The problems of weak coating binding force, uneven thickness, orange peel, sagging and serious coating waste in traditional spraying are effectively solved, and self-adaptive, high-quality and green spraying of workpieces with complex curved surfaces is achieved.

The invention relates to the technical field of control of manufacturing units, in particular to a composite material rod piece winding tension dynamic compensation control method and system. The method comprises the following steps of: calculating an instantaneous linear velocity pulsation quantity caused by the change of a non-circular section contour of a core mold at each moment; according to the dynamic elastic modulus and the equivalent viscosity coefficient, calculating a phase correction factor for representing the viscoelastic response lag of the prepreg tape at each moment; based on the instantaneous linear velocity pulsation quantity and the phase correction factor at each moment, a dynamic compensation torque instruction is obtained, and the dynamic compensation torque instruction is in negative correlation with the phase correction factor; and the dynamic compensation torque instruction is output to the tension unwinding motor, so that the adjustment of winding tension is realized, the accuracy of tension dynamic compensation control is effectively improved, and the product quality is effectively improved.

The invention belongs to the technical field of radar wave-absorbing materials, and discloses a double-sided wave-absorbing broadband stealth composite material and a preparation method thereof. The broadband stealth composite material with the double-sided wave absorbing function comprises a non-metal-based composite material body and at least five metamaterial layers arranged in the thickness direction of the non-metal-based composite material body at intervals. The number of the metamaterial layers is an odd number, a middle metamaterial layer is arranged in the middle of the metamaterial layers in the thickness direction, and the rest metamaterial layers are symmetrically distributed on the two sides of the middle metamaterial layer; the metamaterial layer comprises conductive pattern units which are periodically arranged; the relative dielectric constant of the nonmetal-based composite material body is not greater than 10; the double-sided wave-absorbing broadband stealth composite material does not contain a metal reflecting layer. When electromagnetic waves with the frequency of 1-18 GHz vertically enter the material, the transmissivity of the material is small (smaller than-13 dB, namely smaller than 5%), and meanwhile the material has low reflectivity in a broadband. And the preparation method is simple to operate and easy to realize large-scale production.

The invention provides a fly ash composite material goaf filling body interface quality intelligent evaluation method, and belongs to the technical field of mining engineering and artificial intelligence detection crossing. The method comprises the steps that firstly, filling body interface quality characteristic data are collected and comprise interface sound wave signals, stress strain, coal ash composite material physical parameters and environment working condition data; secondly, constructing a multi-physical field data completion model, performing unsupervised learning on the acquired sound wave, stress, temperature and moisture content data, and generating completion data of global spatial distribution; secondly, constructing a multi-field fusion interface quality index prediction model, and inputting multi-source data into the model to obtain an interface quality index; and finally, combining the quality index to realize interface defect mode classification and grade evaluation, and generating a targeted maintenance strategy. The invention provides an intelligent evaluation method which fuses multi-source data and gives consideration to real-time performance and comprehensiveness, so as to solve the industrial pain points of interface quality evaluation lag, low precision, large destructiveness and the like.

A golf club head has a cast cup including a forward portion of a crown and a forward portion of a sole of the golf club head. A polymeric rear ring is coupled to heel and toe portions of the cast cup to form a club head body defining a crown opening and a sole opening. A crown insert is coupled to the crown opening, and a sole insert coupled to the sole opening. The club head has an inertia generator including an outwardly extending protrusion formed in the sole and a rear weight positioned at an aft end of the protrusion, the sole insert defining at least a portion of the protrusion of the inertia generator. The sole insert includes a composite material having a thickness between 0.45 mm and 1 mm, and a plurality of ribs positioned along an internal surface, and at least one rib is inside the inertia generator.

The invention relates to a preparation method and application of a porous material for preparing methanol through carbon dioxide adsorption and conversion. When the material is prepared, firstly, 4, 4 '4' '-(1, 3, 5-triazine-2, 4, 6-trimethylene) triphenylamine and 1, 2-acenaphthequinone are treated in a mixed solvent containing dioxane / acetonitrile / 6M acetic acid, and AT-COF is obtained; further synthesizing by adopting an impregnation method to obtain IrRu-COF; and finally, uniformly mixing the active gamma-aluminum oxide and the IrRu-COF material to form a carrier dispersion liquid, and then carrying out PEI loading, vacuum impregnation, washing and drying to obtain the PEI functionalized gamma-Al2O3 / COF composite catalyst. The technical closed loop from low-concentration CO2 capture to solar driven conversion is realized, the process flow is simple, and the energy consumption is low.

The invention belongs to the technical field of aerogel, and particularly relates to high-conductivity aerogel powder as well as a preparation method and application thereof. The preparation method comprises the following steps: firstly preparing a graphene / polypyrrole nanosheet composite material with a three-dimensional structure, and then preparing the polyimide / graphene / polypyrrole ternary hybrid conductive aerogel by taking a polyamide acid solution as a precursor through a solution dipping and freeze drying process. Polyimide is used as a framework of high-conductivity aerogel powder, excellent mechanical strength and structural integrity are provided, the common brittleness problem of a pure graphene carbon material or polypyrrole conductive polymer aerogel is solved, and the three-dimensional graphene / polypyrrole nanosheet composite material has excellent elasticity and toughness and can be used for preparing a composite material with high conductivity. The polyimide aerogel prepared by the method can be dispersed in a polyimide matrix as a nano reinforcement, can effectively transfer stress and prevent crack propagation, and endows the aerogel with higher mechanical properties.

The invention provides an ultrasonic detection method and system for inverting residual stress by using sound wave phase velocity, and belongs to the field of air coupling ultrasonic guided wave detection. The method is based on an air coupling ultrasonic guided wave sound field propagation finite element model, and guides optimization design of air coupling ultrasonic transducer parameters. The air coupling ultrasonic guided wave detection technology is adopted for conducting non-contact excitation and receiving of guided wave signals on the composite material component with the preset stress through the stretcher. And calculating the phase velocity of the air-coupled ultrasonic guided wave in the composite material component based on a geometric positioning and time difference cooperative gradual difference method. And calibrating the phase velocity in the target composite material and preset stress to obtain a corresponding relational expression, performing phase velocity detection on a composite material component with unknown stress based on a calibration result of the target composite material, and performing inversion to obtain composite material construction residual stress. By adopting the method and the system, the residual stress detection of the composite material component is realized.

The invention discloses a power device for posture adjustment and butt joint of large-size composite components, and particularly relates to the technical field of aircraft production, the power device comprises an adjustment driving assembly and an adsorption fixing assembly, the adsorption fixing assembly is installed at the output end of the adjustment driving assembly, the adsorption fixing assembly comprises a grabbing frame and a suction cup base, and the suction cup base is installed on the grabbing frame; a flexible adsorption ring is installed at the bottom of the suction cup base, a vacuum adsorption space is formed between the flexible adsorption ring and the suction cup base, and a back supporting positioning column is further installed in the suction cup base in a sliding mode and installed at the output end of the pushing driver. According to the invention, downward reverse support is formed on the surface of the component by means of the reverse support positioning column, so that the component cannot extrude the flexible adsorption ring due to motion inertia under the support of the reverse support positioning column in the process of adjusting the posture of the component, and the component is not easy to generate micro vibration; and therefore, the stability and the safety of adjusting the part are improved.

The invention relates to a preparation method of a nickel ion doped modified ferric sodium pyrophosphate positive electrode material, and belongs to the technical field of sodium ion battery positive electrode materials. The nickel ion doped modified ferric sodium pyrophosphate positive electrode material is prepared by adopting an integrated process system of liquid phase uniform mixing, spray granulation and precise segmented calcination. According to the process system, atomic-scale uniform doping of nickel ions and a specific microstructure of a precursor are realized through spray drying, and a plurality of inherent key technical problems of low electronic conductivity, low ion diffusion rate, impurity phase generation and the like of an NFPP material are solved together through a synergistic effect with a subsequent calcining process; furthermore, the discharge capacity of the ferric sodium phosphate pyrophosphate composite material at high rate is improved, so that the battery has relatively high cycling stability.

The invention relates to the technical field of wind power blade material testing, and discloses a testing device and method for a salt spray corrosion test of a wind power blade composite material layer. According to the method, wind power blade composite material coating preparation parameters are obtained, and coating basic information is provided for subsequent performance evaluation; based on preset salt spray test environment control parameters, dynamic salt spray environment simulation conditions are generated so as to better fit the actual outdoor environment; then, a multi-sensor coupling monitoring network is constructed, real-time data acquisition is conducted on the corrosion process of the composite material coating, and comprehensive tracking of the corrosion process is achieved; processing real-time data by utilizing a corrosion characteristic analysis algorithm, generating a multi-dimensional corrosion characteristic index, and quantitatively representing the corrosion condition of the coating; and finally, evaluating the anti-corrosion stability of the new material coating in combination with the coating characteristic parameters and the multi-dimensional corrosion characteristic indexes. According to the method, the corrosion resistance of the coating in the actual environment can be more accurately reflected, and support is provided for research, development and application of the composite coating of the wind power blade.

The invention discloses a preparation method of a high-temperature-resistant high-strength polyimide composite material, and relates to the technical field of polyimide composites.The preparation method comprises the following preparation steps that S1, a customized silane coupling agent is prepared; s2, preparing a bionic dynamic interface modified reinforcing filler, wherein the modified reinforcing filler is synergistically modified through a bionic coating and a customized silane coupling agent; and S3, preparing a polyimide precursor solution containing the dynamic network. According to the preparation method of the high-temperature-resistant high-strength polyimide composite material, through the integrated design of'customized silane coupling agent + bionic dynamic interface modification + dynamic network-containing polyimide precursor + gradient hot-pressing curing ', the glass-transition temperature of the prepared composite material is greater than or equal to 335 DEG C, the tensile strength is greater than or equal to 208 MPa, and meanwhile, the thermal repair efficiency at 180-250 DEG C is greater than or equal to 87%; the technical bottleneck that high temperature resistance, mechanical strength and repairing performance of the material are difficult to consider at the same time in the prior art is solved.

The invention provides a reinforcing beam reinforced by adopting an out-of-service wind power blade and a method for determining the bending rigidity. According to the reinforcing beam, a plurality of grooves are formed in at least one surface of a reinforced concrete beam; the reinforcing layer comprises reinforcing ribs and a cement-based composite matrix, a plurality of protrusions are arranged on the surface of the cement-based composite matrix, the protrusions are arranged at intervals in the length direction of the cement-based composite matrix, and the protrusions are correspondingly embedded into the grooves, so that the reinforcing layer is connected with the reinforced concrete beam to obtain a reinforced concrete reinforced beam; wherein the reinforcing ribs are obtained by disassembling and cutting a main beam of the retired wind power blade. According to the reinforcing beam, the combining capacity of the reinforced concrete beam and the reinforcing layer is high, mutual slippage is avoided, the retired wind power blade composite material resources are utilized, the environment is protected, and the cost is saved while high-performance reinforcing treatment can be conducted on the damaged reinforced concrete beam structure or the reinforced concrete beam structure with insufficient bearing capacity.

The invention discloses a method for preparing a carbon monoxide oxidation catalyst by using red mud and tungsten-molybdenum smelting slag, which comprises the following steps of: uniformly stirring and mixing the red mud and the tungsten-molybdenum smelting slag at a high speed, mixing with inorganic strong acid, and performing ultrasonic-assisted stirring to obtain acid leaching slag; the acid leaching residues are subjected to low-temperature plasma activating treatment and then microwave activating treatment, and microwave activated plasma residues are obtained; weighing tricalcium phosphate and microwave activated plasma slag, and uniformly stirring to obtain phosphorus-calcium doped activated slag; weighing an ammonium sulfide solution and the phosphorus-calcium doped activated slag, uniformly stirring, transferring the obtained sulfur-phosphorus-calcium doped activated slag into a hydrothermal reaction kettle, carrying out hydrothermal reaction, carrying out compression molding on the obtained hydrothermal composite material, and carrying out pyrolysis carbonization treatment in an inert gas atmosphere to obtain the phosphorus-calcium doped activated slag. The obtained pyrolysis composite material is soaked with a silane coupling agent solution and then roasted again, and the carbon monoxide oxidation catalyst is obtained. The catalyst prepared by the invention can realize efficient oxidation photocatalysis of carbon monoxide under the conditions of normal temperature and normal pressure.

The invention relates to a bionic Al / SiC composite material with a three-dimensional network multilevel structure and a preparation method of the bionic Al / SiC composite material, and belongs to the technical field of new material preparation. According to the method, through the collaborative process of freeze casting and organic foam impregnation, the problem that in the prior art, the multilevel aperture and the complex network structure are difficult to cooperatively regulate and control is solved. The preparation method comprises the following specific steps: preparing tert-butyl alcohol-based ceramic slurry, impregnating the slurry with polyurethane foam, performing freeze casting molding, removing a solvent through freeze drying, performing high-temperature sintering to form SiC ceramic with a three-dimensional reticular hierarchical pore structure, and finally preparing the Al / SiC composite material through a vacuum pressure infiltration process. Wherein a sintering aid is added into the slurry, so that the sintering temperature is obviously reduced; the specification (40-60 ppi) of polyurethane foam, the solid phase content (20-30 vol.%) of slurry, the freezing speed (0-90 DEG C) and the content (5-20 wt.%) of a sintering aid are regulated and controlled. And the cross-scale collaborative design of micron-scale directional holes and millimeter-scale mesh holes is realized. The Al / SiC composite material prepared by the invention has the advantages that the compressive strength, fracture toughness and other properties are obviously higher than those of the traditional single-aperture porous ceramic, and the Al / SiC composite material is suitable for the fields of manufacturing and energy absorption of precise instruments, electronic packaging and optical devices.

The invention provides a preparation method of a self-repairing resin-based composite material based on dynamic bonds. The self-repairing epoxy resin comprises one covalent dynamic bond of a Diels-Alder bond, a disulfide bond or a borate bond, and the preparation method of the self-repairing epoxy resin comprises the following steps: heating epoxy resin to a molten state, adding a curing agent component while stirring, and carrying out a prepolymerization reaction to obtain a prepolymer; the curing agent comprises a rigid diamine curing agent, a dynamic diamine monomer and a flexible chain segment regulator, and the dynamic diamine monomer contains a dynamic covalent bond; and carrying out curing molding on the prepolymer to obtain the self-repairing epoxy resin. And impregnating reinforced fibers or fabrics thereof with the prepared prepolymer, and heating and curing to obtain the self-repairing resin-based composite material. The invention provides a chemical molecule design, dynamic reversible chemical bonds are introduced into a resin matrix, and by constructing the dynamic bonds, the composite material has high performance of a traditional composite material and also has life-like self-healing ability.

The invention discloses a high-capacity composite material hydrogen storage cylinder layering design method considering the strength of a transition section, and relates to the technical field of hydrogen storage cylinders. Establishing a finite element model of the hydrogen storage cylinder, inserting a cohesion unit with zero thickness between adjacent layers, and performing damage evolution on the cohesion unit to obtain a hydrogen storage cylinder simulation result considering the interlayer failure in the composite material layer; according to the fiber stress of the composite material layer and the damage state of the cohesion unit, determining a weak position under the current layering design, determining to-be-optimized parameters of the weak position, and formulating a layering optimization strategy; according to the method, sensitivity analysis of layering parameters is carried out on a transition section, so that a layering optimization strategy of the transition section is formulated; and according to the layering optimization strategy, parameters to be optimized in the layering design are gradually adjusted until no fiber damage exists in the whole composite material layer. According to the invention, the layering design of the high-capacity composite hydrogen storage cylinder considering the strength of the transition section is realized.

The invention discloses a flexible heat-conducting composite material with chain-shaped boron nitride and a preparation method, and belongs to the technical field of flexible electronic device heat management materials, the flexible heat-conducting composite material comprises an elastomer matrix and a magnetic functionalized boron nitride filler filled in the elastomer matrix; the elastomer matrix is polydimethylsiloxane; the magnetic functionalized boron nitride filler is prepared by modifying Fe3O4 nanoparticles on the surface of a boron nitride sheet; the boron nitride sheets form a vertically arranged chain structure in the elastomer matrix. The chained vertical arrangement of the boron nitride sheets is realized by prolonging the magnetic field treatment time, the Fe3O4 modification quantity is controlled to optimize the balance between the magnetic responsiveness and the heat-conducting property, a chained heat-conducting network connected end to end is formed, and the thermal seepage threshold value is reduced. According to the flexible composite material and the preparation method thereof, boron nitride sheets are induced to be vertically arranged through a magnetic field to form a chain-shaped heat-conducting network, so that high heat conductivity under low filler loading capacity is realized, and excellent stretchability is kept at the same time.

The invention discloses a mold partition temperature control system based on an air film adjustable thermal resistance boundary, and belongs to the technical field of mold temperature control and thermal management. The system comprises a mold body, at least two temperature control subareas and gas film adjustable thermal resistance boundary units arranged between the adjacent temperature control subareas. The air film adjustable thermal resistance boundary unit comprises a boundary air cavity, an air injection micropore, an exhaust adjusting structure and an air supply unit. Gas enters the partition boundary area through the gas injection micropores and forms a gas film layer, and the thickness, continuity, stability and coverage range of the gas film layer are changed by adjusting the gas supply pressure, the gas supply flow and the exhaust resistance, so that the thermal coupling strength between the adjacent temperature control partitions is adjusted. The system is suitable for injection molding, pressure casting, hot pressing and composite material forming molds.

The invention belongs to the technical field of metal composite materials and hydrogen storage and transportation materials, and particularly relates to a high-strength hydrogen-embrittlement-resistant layered metal composite material for hydrogen storage and a preparation method and application of the high-strength hydrogen-embrittlement-resistant layered metal composite material. According to the preparation method, the nickel-saving austenitic stainless steel (NEASS) and the 30CrMo steel are alternately overlapped in a multi-layer mode, and the processes of vacuum electron beam welding, high-temperature hot rolling, accumulative ply rolling, multi-stage heat treatment and the like are combined, so that the composite board with the layer number reaching hundreds of layers, firm interface bonding, excellent mechanical performance and good hydrogen embrittlement resistance is prepared; the technical problem that strength, toughness and hydrogen brittleness resistance of an existing metal material in a high-pressure hydrogen environment are difficult to consider at the same time is solved. The obtained composite material has high strength, high plasticity and excellent hydrogen embrittlement resistance, and is suitable for structural materials of high-pressure hydrogen storage tanks, hydrogen conveying pipelines and other key hydrogen energy equipment.

The invention discloses a high-initial-efficiency fast-charge graphite composite material and a preparation method thereof, the composite material is of a core-shell structure, the core is graphite, and the shell is lithium sulfonate / lithium molybdate and an amorphous carbon coating layer thereof; the mass ratio of the shell is 5-15 wt% according to the mass ratio of the composite material being 100%. The preparation method comprises the following steps: adding a molybdenum compound into a solvent to prepare a solution, adding graphite oxide, an inorganic lithium salt and a carbon nanotube conductive solution, reacting for 2-12 hours at the temperature of 50-120 DEG C, filtering, carbonizing filter residues to obtain a lithium molybdate conductive agent coated graphite material, and depositing a lithium sulfonate derivative on the surface of the lithium molybdate conductive agent coated graphite material by an atomization method to obtain the lithium molybdate conductive agent coated graphite material. The electron and ion conductivity of the material can be improved, and the rate and the first efficiency of the material can be improved.

The invention relates to an ionic redox couple thermoelectric cement-based composite material, the composite material comprises a cement matrix and redox couples, and the redox couples exist in pores of the cement matrix; wherein the redox pairs are K4 [Fe (CN) 6] and K3 [Fe (CN) 6], and the porosity of the cement matrix is 25%-50%. According to the invention, the migration of ions in a cement matrix is regulated and controlled by introducing the redox couple, so that a relatively high Seebeck coefficient, conductivity and power factor are achieved while good mechanical properties are maintained, and the thermoelectric conversion efficiency is remarkably improved. Besides, the composite material can drive electrode reaction through temperature difference to generate a closed current loop, stable current output is achieved, and the problem of current output of a traditional ionic thermoelectric material is solved.

The invention discloses a composite material T-shaped beam forming method in the technical field of aviation, a forming die, a laying die and a bottom face forming die which are arranged in a split mode and can be combined are adopted, forming is conducted through a secondary hot-pressing curing process, and the method comprises the following steps that S1, preforming and R corner prefabricating are conducted, the independently-prefabricated prepreg core material is positioned in a T-shaped beam R-angle area formed after the prepreg core material and the T-shaped beam R-angle area are oppositely combined; and S2, first-time mold closing and pre-curing are carried out, specifically, the laying mold and the forming mold are oppositely closed, lateral auxiliary positioning is carried out through the bottom face forming mold, locking and fixing are carried out through a positioning pin and a clamping piece, and first-time hot-pressing curing is carried out on a combined body obtained after mold closing. According to the method, the independently prefabricated core material which is subjected to heat-sealing, pressing and pre-curing is filled in the R-angle area, and a secondary hot-pressing process of pre-curing and final curing is matched, so that sufficient pressure transmission and tight laying of the R-angle area are ensured, the defects of layering, bridging and the like are effectively avoided, and the percent of pass of nondestructive testing of products is remarkably improved.

The invention discloses a biodegradable polylactic acid composite material and a preparation method thereof, and relates to the technical field of polylactic acid materials. The method comprises the steps that firstly, chitosan activated through hydrochloric acid is subjected to graft modification through a KH550 silane coupling agent, meanwhile, nano-zinc oxide is subjected to surface modification through stearic acid, the chitosan and the nano-zinc oxide are mixed, spray drying is conducted, and antibacterial composite powder is prepared; the preparation method comprises the following steps: performing hydrochloric acid activation and KH570 silane coupling agent modification on nano silicon dioxide, performing hydroxypropylation modification on alkali lignin, and performing reflux crosslinking reaction on the modified alkali lignin, KH570 modified nano silicon dioxide, polycaprolactone, methyl methacrylate and azodiisobutyronitrile to prepare a heat-resistant reinforcer; uniformly mixing polylactic acid, poly (butylene succinate), the antibacterial composite powder, the heat-resistant reinforcer, tributyl citrate, polyethylene glycol and talcum powder, and extruding and granulating by using a twin-screw extruder to obtain the heat-resistant antibacterial material. The composite material prepared by the invention has excellent antibacterial property, heat resistance and biodegradability.

According to the hard process cover plate forming method capable of achieving directional control over the R angle thickness of the composite part, the carbon fiber fabric prepreg is laid on the hard cover plate forming tool to prepare a hard cover plate, and the inner R angle of the hard cover plate is compensated to adapt to R angle forming of parts with different thicknesses. By adjusting the value of the R angle in the hard cover plate, the part prepreg is prevented from being excessively extruded in the R angle in the forming process, so that glue flowing is serious, the forming quality of the R angle of the part is guaranteed, and the percent of pass of the composite material part with the R angle is effectively improved.

The invention relates to the technical field of functional polymer composite materials, and provides diatomite modified composite super absorbent and rapid absorbent resin and a preparation method thereof. The preparation raw materials of the diatomite modified composite high-water-absorption and rapid-water-absorption resin provided by the invention comprise acrylic acid, acrylamide, sodium hydroxide, N, N '-methylene bisacrylamide, ammonium persulfate and modified diatomite. The diatomite is modified by the silane coupling agent, the agglomeration problem of the diatomite is solved, the compatibility with organic monomers is improved, and the modified diatomite, acrylic acid and acrylamide are utilized to construct an organic-inorganic synergistic three-dimensional porous network structure, so that the resin has ultrahigh water absorption rate, rapid water absorption performance and good water retention stability. Meanwhile, the preparation method disclosed by the invention does not need nitrogen protection, has the advantages of simple process, controllable raw material cost and easiness in industrial mass production, and is suitable for multiple fields such as water-saving agriculture, soil moisturizing, landscaping and the like.

The invention discloses a carbon nitride-based composite material as well as a preparation method and application thereof. The carbon nitride-based composite material comprises a non-metal doped carbon nitride carrier and a noble metal, wherein the noble metal exists in the carrier in an element doping form and / or is loaded on the carrier in an oxide form; the precious metal is one or more of Pt, Pd, Au and Ru, and the nonmetal is one or more of P, S and I. According to the carbon nitride composite material disclosed by the invention, noble metal is utilized to modify carbon nitride, the number of surface active sites is increased, the electron and chemical structures of an active center are adjusted, and meanwhile, generation and migration of photo-generated charges are promoted. Meanwhile, the surface of the carbon nitride composite material is modified by non-metallic elements, so that adsorption and activation of reactant H2O molecules are effectively promoted. The catalyst disclosed by the invention is simple in preparation process, good in repeatability and easy for large-scale production.

The invention relates to the technical field of non-oxide ceramic-based composite materials, in particular to Fe-N-based high-entropy nitride ceramic as well as a preparation method and application thereof. The method comprises the following steps: by taking iron powder as a sintering aid, mixing (Hf < 0.2 > Zr < 0.2 > Ti < 0.2 > Nb < 0.2 > Ta < 0.2 >) N high-entropy powder with the iron powder, and carrying out ball milling treatment to obtain ball-milled powder; and under the oxygen-free condition, the ball-milled powder is subjected to sintering treatment, transformation from the loose ball-milled powder to compact and uniform solid solution ceramic is achieved in the sintering treatment process, and the Fe-N-based high-entropy nitride ceramic is obtained. According to the method, a nitride thermal reduction method sintering process is adopted, energy is provided for densification of the Fe-N-based high-entropy nitride ceramic by utilizing reaction heat release of the (Hf0. 2Zr0. 2Ti0. 2Nb0. 2Ta0. 2) N high-entropy powder and the iron powder, the sintering temperature is reduced, energy is saved, and the defect that densification needs to be carried out under a high-temperature condition in the prior art is overcome.

Disclosed golf club heads include a weight channel positioned in the sole and defining a path along the sole. A weight member positioned in the weight channel can be adjusted to any of a range of selectable positions to adjust mass properties of the golf club head. A fastener secures the weight member in any of the selectable positions, while the fastener itself, regardless of where the weight member is positioned along the path, is secured to the body at a fixed location that is independent of the position of the weight member along the path. Part of the weight channel and weight member can be covered by an overhanging portion of the sole, which can form a sit pad. The overhanging portion can be part of a composite sole insert.