The invention discloses a sulfur-bridged quinazoline-based tetradentate platinum complex phosphorescent material and a preparation method thereof. The phosphorescent material has a general structure represented by formulae (I) and (II) as shown in the specification. In the formulae, R can be one selected from the group consisting of phenyl, 4-fluoro-substituted phenyl, 2,4-difluoro-substituted phenyl, 3,4,5-trifluoro-substituted phenyl, 4-trifluoromethyl-substituted phenyl, 2-trifluoromethyl-substituted phenyl, 2,6-dimethyl-substituted phenyl, 4-methoxy-substituted phenyl, 4-nitro-substitutedphenyl, 4-N,N-dimethylamino-substituted phenyl, 2-benzothienyl, 2-benzofuryl, 9-(4-substituted phenyl)carbazole, 9-(4-substituted-phenyl)phenothiazine, 2-substituted 9,9-dimethylfluorenyl, tert-butoxy, 2,6-dimethyl-substituted phenoxy, hexahydropyridyl, N-carbazolyl, N-diphenylamino, N-bis(4-a tertiary butyl phenyl)amino, N-phenothiazinyl, 9,9-methylacridanyl radicals.