The invention discloses a white light electrogenerated light-emitting apparatus, which comprises the structure including a substrate, a conductive layer, a hole injecting layer, a hole transmitting layer, an electron stop layer, a light emitting layer, a hole stop layer, an electron transmitting layer, an electron injecting layer and a cathode layer in sequence; the light emitting layer is a composite layer structure, and the composite layer structure comprises the following layers of a red phosphor light emitting layer, a first interval layer, a blue light emitting layer, a second interval layer and a green phosphor light emitting layer in sequence; and the red phosphor light emitting layer is prepared on the surface of the electron stop layer, and the hole stop layer is prepared on the surface of the green phosphor light emitting layer. According to the invention, light emitting layers of blue light emitting materials, red and green light phosphor materials are applied in the white light electrogenerated light-emitting apparatus, red and green light phosphor light emitting layers are respectively arranged on both sides of the blue light emitting layer, therefore the triplet state energy of blue light can be fully captured, and the light emitting efficiency is further increased.