The invention relates to the technical field of
polyester resin, and discloses a preparation process of
tin-free environment-friendly
polyester resin, which is characterized in that dihydric
alcohol,
dibasic acid, a catalyst, an
antioxidant, an acidolysis agent, a curing accelerator and the like are reacted to obtain the
tin-free environment-friendly
polyester resin. According to the invention,
bismuth iso-octoate and 4-dimethylaminopyridine form a compound catalyst to replace a traditional organic
tin catalyst, so that the tin-free environment-friendly
polyester resin is obtained, and the blank of the tin-free environment-friendly
polyester resin is filled. The toxic and side effects are effectively reduced, the environmental
pollution is reduced, and the requirements of environment-friendly
polyester resin are met. Meanwhile,
tris (2-hydroxyethyl)
benzene-1, 3, 5-triformate is added to participate in esterification
polycondensation reaction, contains a plurality of hydroxyl crosslinking
polymerization sites and a heat-resistant
benzene ring structure, and is crosslinked into polyester resin molecules, so that the glass-
transition temperature, the
heat stability and the biodegradability of the resin can be improved.