The invention relates to a non-oriented high-silicon electrical steel ribbon and its making method, and belongs to the fields of the metallurgical technology and the material science. The chemical components of the ribbon comprise 4.5-7.0wt% of Si, 2.0-5.0wt% of Cr, 0.06-1.0wt% of Al, 0.3-0.8wt% of Mn, 0.005wt% or less of N, 0.004wt% or less of S, 0.02wt% or less of P, 0.003wt% or less of O, 0.005wt% or less of C, and the balance Fe, and the thickness of the ribbon is 0.35-0.5mm. The making method comprises the following steps: smelting non-oriented high-silicon steel in a vacuum smelting furnace; carrying out double-roller ribbon roll-casting at a casting temperature of 1420-1460DEG C to the ribbon thickness of 1.0-1.5mm; carrying out hot rolling of the ribbon at 800-1100DEG C to the hot rolled ribbon thickness of 0.8-1.0mm; pickling, and preheating the ribbon, and carrying out warm rolling at 400-700DEG C; and annealing. The addition of the Cr element in the high-silicon electrical steel ribbon obviously improves the processing performance of the high-silicon steel ribbon, the iron loss value is same to the iron losses of present high-silicon steel products, and the magnetic induction intensity is above 0.03T higher than that of the present products. The making method has the advantages of simple technology, low energy consumption, high yield, and excellent product magnetic property.