The invention relates to a multifunctional tourmaline health-care material and a preparation method thereof, and relates to a health-care composite material and a preparation method thereof, which solve the problem of single function in the conventional health-care material. The multifunctional tourmaline health-care material is prepared from iron tourmaline powder, neodymium iron boron powder, titanium dioxide powder, cerium oxide powder, a bonder, a coupling agent and a lubricating agent. The method comprises the following steps of: mixing the iron tourmaline powder, the neodymium iron boron powder, the titanium dioxide powder, the cerium oxide powder, the bonder, the coupling agent and the lubricating agent uniformly, pressing the mixture to form parison, and curing and magnetizing to prepare the multifunctional tourmaline health-care material. The multifunctional tourmaline health-care material also can be prepared from the iron tourmaline powder, the neodymium iron boron powder, the titanium dioxide powder, the cerium oxide powder and viscose fiber slurry, and the method comprises the following steps of: adding the iron tourmaline powder, the neodymium iron boron powder, the titanium dioxide powder and the cerium oxide powder into the viscose fiber slurry, mixing uniformly, and after performing wire drawing, spinning and weaving, magnetizing to prepare the multifunctional tourmaline health-care material. The multifunctional tourmaline health-care material releases negative ions, far infrared rays, magnetic fields and microcurrent, and can be used for preparing health-care products.