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32 results about "Liquid gallium" patented technology

High-heat-conductivity leakproof liquid metal phase change heat-conducting gasket and preparation method thereof

PendingCN121427289AUV curingPhysical chemistry
The invention discloses a high-heat-conductivity leakproof liquid metal phase change heat-conducting gasket and a preparation method thereof, and relates to the technical field of heat-conducting gaskets. The preparation method comprises the following steps: alloying high-heat-conductivity low-melting-point liquid metal gallium with high-heat-conductivity metal silver and copper, mixing with a polymer containing a specific functional group, adding a modified heat-conducting filler, and carrying out UV curing to form the heat-conducting gasket. Liquid metal is easily alloyed to form eutectic alloy, the melting point can be increased, a chemical cross-linked network formed by the modified heat conduction filler and UV curing can make up heat conduction loss, a heat conduction path is established, the interface thermal resistance is reduced, and the heat conduction efficiency is remarkably improved. The surface oxide layer interacts with the polar group of the polymer, and the steric hindrance effect of the cross-linked network is combined to synergistically realize the leak-proof effect. The high-heat-conductivity leakproof liquid metal phase change heat-conducting gasket prepared by the invention has the effects of high heat conductivity and leakproof.
Owner:KUSN ZHONGDI MATERIALS TECH

Liquid metal-based catalyst with flowable amorphous cobalt active sites as well as preparation method and application of liquid metal-based catalyst

The invention discloses a liquid metal-based catalyst with flowable amorphous cobalt active sites as well as a preparation method and application of the liquid metal-based catalyst. The spherical gallium-based liquid metal loaded amorphous cobalt nanosheet material is synthesized by using a sodium borohydride ice bath method. Due to the optimization of the synthesis process, the amorphous cobalt nanosheets are uniformly distributed on the surfaces of the liquid gallium balls, are small in size, are high in utilization rate and are not easy to agglomerate; the intrinsic flow characteristic of the liquid metal gallium realizes the efficient reverse hydrogen overflow effect, optimizes the formation process of a catalytic reaction intermediate, and accelerates the formation of the intermediate. The composite material has the advantages of low overpotential, high Faraday efficiency, high ammonia production rate, good stability and the like during nitrate electrocatalytic reduction reaction, meets the requirements of production and use, and is low in preparation cost.
Owner:TIANJIN UNIV

An experimental device and method for simulating bubble behavior in a liquid metal cooled reactor

The application provides a bubble behavior test device and method for simulating a liquid metal cooled reactor, and belongs to the technical field of nuclear engineering. The device aims to solve the problems of high operating temperature, large power consumption and poor safety of a traditional experimental loop using lead-bismuth alloy as a liquid phase medium, and the shortcoming that a traditional contact type measurement method easily causes disturbance to the flow characteristics of fluid. The bubble behavior test device for simulating the liquid metal cooled reactor comprises a flow channel body, a rod bundle matrix and liquid gallium-indium-tin alloy metal arranged in the flow channel body, and a plurality of gas check valves arranged on each rod of the rod bundle matrix; an inert gas output assembly is provided with a plurality of gas output ports and is connected with the gas injection ports on each rod of the rod bundle matrix; an ultrasonic probe array is arranged on the side of the rod bundle matrix and in the central rod; and a fluid circulation assembly is connected with the flow channel body at the inlet end and the outlet end and is used for driving the fluid in the flow channel body to move from top to bottom and separating the gas from the flow channel body. The device is mainly used for simulating the bubble behavior of the liquid metal cooled reactor.
Owner:HARBIN ENG UNIV

Radiation refrigeration coating with recyclable function and preparation method thereof

The application discloses a radiation refrigeration coating with a recyclable function and a preparation method thereof, and belongs to the technical field of refrigeration coatings.The coating is composed of base oil 500SN, hollow silica microspheres (SiO2@APTES) modified by a silane coupling agent, a liquid metal-based crosslinking agent (GLM) composed of a self-prepared urea-based monomer (UM), cetyl methacrylate (CMA) modified liquid gallium (Ga), talcum powder, calcium carbonate, ethylene glycol butyl ether, polyacrylate, methyl ethyl ketone oxime and methyl methacrylate.The GLM crosslinking agent in the coating has a reversible thermal stimulation response, can reversibly perform phase conversion under thermal stimulation, and simultaneously endows the coating with recyclable performance.Meanwhile, the introduction of the SiO2@APTES realizes high reflection of sunlight and high emission of a medium and far infrared band, and guarantees excellent radiation refrigeration performance of the coating.
Owner:SOUTHWEST PETROLEUM UNIV

Precursor composition for thin film deposition, method for manufacturing thin film, thin film manufacturing using same, and electronic device including thin film

The present disclosure provides: a precursor composition for depositing a thin film including a liquid indium precursor, a liquid gallium precursor, and a liquid zinc precursor; a method for manufacturing a thin film by using the precursor composition; a thin film manufactured by using the precursor composition; and an electronic device including the thin film.
Owner:SAMSUNG DISPLAY CO LTD +1

Liquid gallium ion source and method of emitting gallium ions

PendingCN122337954AThermal deformationIon beam
The application discloses a liquid gallium ion source and a gallium ion emission method. The liquid gallium ion source comprises an insulating base, a gallium storage container arranged below the insulating base, the gallium storage container having a containing cavity in which a gallium source is stored, an emission needle fixedly connected with the gallium storage container and extending downward along an axial direction of the gallium storage container from a bottom of the gallium storage container, a heating wire at least partially located in the containing cavity of the gallium storage container and in contact with the gallium source, an electrode assembly comprising first and second column electrodes fixedly and spacedly arranged in the insulating base and used for being fixedly electrically connected with two ends of the heating wire respectively, and a fixing assembly fixedly arranged in the insulating base and fixedly connected with the emission needle, the fixing assembly being not in contact with the heating wire. The application can improve the thermal efficiency of the liquid gallium ion source, reduce ion beam deviation caused by thermal deformation of the emission needle and as far as possible prolong the service life of the liquid gallium ion source.
Owner:DAZHU TECH (BEIJING) CO LTD

Magnetic control directional crystallization process for self-adaptive magnetic field regulation and control in high-purity gallium production

The invention discloses a self-adaptive magnetic field regulation and control magnetic control directional crystallization process in high-purity gallium production, which comprises the following steps: step 1, raw material pretreatment: putting a gallium raw material containing impurities into a smelting furnace, and heating to a temperature above a melting point, so that the gallium raw material is completely molten into liquid gallium; waste heat is recovered through a heat exchange device in the melting process and is used for preheating subsequent raw materials or other production links; 2, setting a self-adaptive magnetic field: transferring the liquid gallium into a crystallization container with a magnetic field generating device; step 3, accurate temperature control: arranging a plurality of coil heating units and water pipe cooling units outside the crystallization container, and arranging temperature sensors at different heights inside the crystallization container; step 4, crystal separation and post-treatment; the self-adaptive magnetic field regulation and control magnetic control directional crystallization process in high-purity gallium production can ensure the purity and quality of crystals through magnetic field regulation and control during use, can also effectively utilize the waste heat of equipment, reduces the production cost, and is suitable for popularization and application.
Owner:CHINALCO (ZHENGZHOU) ALUMINUM CO LTD

A method of form grinding for thin-walled gears

The present application relates to a kind of forming grinding method for thin-walled gear, belong to the lubrication cooling technical field in grinding processing, method as follows: liquid gallium is transported to the detachable sealed gallium delivery box of electrostatic spraying module, part of liquid gallium in detachable sealed gallium delivery box enters pressurized pipeline pressurization;Part of liquid gallium enters electric field application cavity, realizes particle charging atomization under the action of electrostatic field and is sent to uniform electric field duct.Switch off control switch at the same time, after the electric field in uniform electric field duct is stable, liquid gallium in pressurized pipeline flows into uniform electric field duct.In the uniform field effect, liquid gallium in uniform electric field duct is uniformly charged atomization, and charged liquid gallium after atomization is sprayed to workpiece surface.Grinding workpiece surface, temperature control module adjusts workpiece surface temperature in real time, maintains the state of dynamic conversion between liquid gallium and solid liquid.The present application effectively solves the problem that cooling liquid is difficult to penetrate to the depth of tooth surface in thin-walled gear forming grinding, and improves the quality and efficiency of forming grinding.
Owner:HUNAN INSTITUTE OF SCIENCE AND TECHNOLOGY

A profile grinding device for grinding a thin-walled gear

The present application relates to a kind of forming grinding device for grinding thin-walled gear, belong to the lubrication cooling technical field in grinding processing, including electrostatic spraying module, temperature regulation module and grinding wheel;Grinding wheel has inner runner, electrostatic spraying module sprays liquid gallium to the workpiece surface ground by grinding wheel;Electrostatic spraying module includes pressurizing module, charge application module and conveying module;After liquid gallium is transported to detachable closed gallium delivery box, part is pressurized after entering uniform electric field conduit by pressurizing pipeline, part enters the electric field particle charging by detachable closed gallium storage cavity, and is sent to uniform electric field conduit, under the action of electric field, all liquid gallium in uniform electric field conduit is uniformly charged, and is sprayed to workpiece surface by conveying module;The temperature regulation module adjusts workpiece surface temperature, maintains liquid gallium solid-liquid conversion.The present application effectively solves the problem that coolant is difficult to penetrate to the depth of tooth surface in thin-walled gear forming grinding, and improves the quality and efficiency of forming grinding.
Owner:HUNAN INSTITUTE OF SCIENCE AND TECHNOLOGY

Method and device for detecting impurity zinc in high-purity gallium

The application discloses a method and device for detecting impurity element zinc in high-purity gallium. The detection method comprises the following steps: taking a mixed centrifugal extraction tube, adding a high-purity gallium sample, adding a solution containing a high-purity extractant, sealing the mixed centrifugal extraction tube, fixing the mixed centrifugal extraction tube horizontally on a mixed oscillation extractor, performing oscillation extraction, taking out the mixed centrifugal extraction tube, vertically storing the mixed centrifugal extraction tube, making liquid gallium gather at the conical bottom of the mixed centrifugal extraction tube, separating the extraction liquid, and using internal standard calibration ICP-MS to detect the impurity zinc content. The volume concentration of the high-purity extractant in the solution containing the high-purity extractant is 1-10%, and the high-purity extractant is selected from one of hydrochloric acid, nitric acid and sulfuric acid. The detection method provided by the application has the advantages of simple process, short flow, easy operation, fast extraction and separation speed, clean matrix removal, complete impurity retention and good reproducibility.
Owner:ZHUZHOU KENENG NEW MATERIAL CO LTD

A composite phase change film material based on dual-function filler enhancement and a preparation method thereof

ActiveCN121652434BImprove thermophysical propertiesImprove thermal conductivityInksCoatingsActive safetyPolymer science
This invention relates to a composite phase change film material and its preparation method based on a dual-functional filler reinforcement, belonging to the field of phase change composite material technology. The method includes the following steps: The composite phase change film comprises a poly(p-phenylbenzobisoxazole) nanofiber substrate, phase change microcapsules, liquid gallium metal modified with thermally conductive boron nitride nanosheets, and thermochromic ink. The prepared liquid gallium metal modified with boron nitride nanosheets has a core-shell structure with an average particle size of 576.9 nm. The prepared composite phase change film possesses excellent thermal conductivity, high heat storage performance, outstanding mechanical properties, and flexibility. Furthermore, this composite phase change film exhibits passive thermal management and active safety warning effects, achieving a dual thermal protection function combining visual cues for heat storage and temperature control. In a small car model, it not only triggered a blue-to-yellow color transition at 50°C, providing an intuitive temperature warning, but also achieved a temperature suppression effect of 5.9°C.
Owner:SOUTHWEST PETROLEUM UNIV

Continuous crystallization equipment for high-purity gallium production

ActiveCN224270216UEasy to detectCrystal harvesting realizedSolution crystallizationProcess efficiency improvementPhysical chemistryLiquid gallium
This utility model relates to the field of high-purity gallium production technology, specifically a continuous crystallization apparatus for high-purity gallium production. It includes a boat-shaped crucible with a crystallization tank and a crystal storage tank at its top. A crystallization retrieval mechanism is installed on the boat-shaped crucible, comprising a movable frame and a rotating belt. The movable frame includes a pair of parallel support plates, and several rows of retrieval rods are fixed to the outer surface of the rotating belt. This continuous crystallization apparatus for high-purity gallium production, through its flip-up crystallization retrieval mechanism, allows the retrieval rods fixed to the outer surface of the rotating belt to promptly transfer the crystallized gallium crystals from the crystallization tank to the crystal storage tank, enabling continuous retrieval of the crystallized gallium crystals. This avoids the formation of large crystal clumps due to prolonged residence in liquid gallium, facilitating subsequent gallium quality testing.
Owner:CHUXIONG CHUANZHI ELECTRONIC MATERIALS CO LTD

High load gear forming grinding method based on ultrasonic-assisted liquid gallium phase transformation strengthening

This invention proposes a high-load gear forming grinding method based on the local phase transition strengthening effect of liquid gallium assisted by ultrasonic rapid cooling. When room-temperature liquid gallium is transported from a constant-temperature storage tank to an ultrasonic atomizing device, the liquid gallium metal is vibrated by ultrasonic waves into atomized particles, which are then propelled forward. Due to the rapid increase in kinetic energy and decrease in internal energy, the ejected liquid gallium atomized particles quickly condense, forming a solid-liquid transition state. The direction of movement of the ejected liquid gallium droplets is controlled by charging electrodes and deflection electrodes, focusing the precise ejection of liquid gallium droplets into the core grinding area. During the solid-liquid transition process of the liquid gallium particles, a large amount of heat energy is rapidly absorbed on the gear processing surface. After thermal melting, gallium atoms react with titanium atoms to form a metastable gallium titanate compound, achieving local phase transition strengthening of the high-dynamic-load gear. This method utilizes the local phase transition strengthening effect of the liquid gallium solid-liquid transition process to significantly enhance the metal strength and toughness of the high-dynamic-load gear, which is in line with the concept of green development.
Owner:HUNAN INSTITUTE OF SCIENCE AND TECHNOLOGY

A method for preparing gallium-based liquid metal thermal interface material by plating Ga2O3 on diamond particles

The application discloses a method for preparing gallium-based liquid metal thermal interface material by coating Ga2O3 on diamond particles. The method comprises the following steps: firstly, preparing gallium-based liquid metal by heating metal gallium, indium and tin with a specified ratio; secondly, coating Ga2O3 on the surface of specified diamond particles by low-pressure chemical vapor deposition after ultrasonic cleaning, wherein liquid gallium and high-purity oxygen are used as precursors, and high-purity argon is used as a protective gas; thirdly, mixing the prepared gallium-based liquid metal and the diamond particles coated with Ga2O3 and stirring in an oxygen-free environment; and fourthly, preparing high-thermal-conductivity gallium-based liquid metal thermal interface material after the interface wetting of the mixed composite material is regulated by Ga2O3 through ultrasonic-assisted wetting. The method can finely regulate the layer thickness of Ga2O3 between two phases, efficiently utilize Ga2O3 to improve the interface wetting, and reduce the negative effect of low thermal conductivity of Ga2O3 to the minimum, so that the gallium-based liquid metal thermal interface material with high thermal conductivity is finally prepared.
Owner:GRIMAT ENG INST CO LTD

A method for preparing a rare earth oxide / gallium oxide magnetoresistance composite film based on multi-source thermal resistance evaporation

PendingCN122358125AComposite filmFilm base
This invention discloses a method for preparing rare-earth oxide / gallium oxide magnetoresistive composite thin films based on multi-source thermal resistance evaporation. The method includes: providing at least two evaporation raw materials, each independently selected from core-shell structured rare-earth oxide / gallium oxide composite particles or separately packaged rare-earth oxide precursor powder mixed with a homogeneous suspension of liquid gallium metal; after pretreatment of the substrate, placing the at least two evaporation raw materials in multiple evaporation boats, and forming a wet film using sequential evaporation or co-evaporation; finally, performing a flash calcination treatment under oxygen-rich conditions to obtain the composite thin film. Sequential evaporation can obtain multilayer thin films with different compositions; co-evaporation can obtain a single-layer mixed-component thin film. This invention allows for flexible control of the composition, thickness, and interface structure of the thin film through multi-source thermal resistance evaporation, enabling the preparation of single-layer mixed-component or multilayer thin films, expanding the design dimensions of magnetoresistive functional materials. Furthermore, the process is stable, the equipment cost is low, and it is suitable for large-scale production.
Owner:KUNMING UNIV OF SCI & TECH

Test device for simulating bubble behavior of liquid metal cooling reactor

The utility model provides a test device for simulating bubble behaviors of a liquid metal cooling reactor, and belongs to the technical field of nuclear engineering. The utility model aims to solve the problems of high operating temperature, high power consumption and poor safety of a traditional experimental loop using lead-bismuth alloy as a liquid phase medium, and the defect that a traditional contact measurement method is easy to cause interference on the flow characteristics of fluid. A liquid metal cooling reactor bubble behavior simulation test device comprises a flow channel body, a rod bundle matrix and liquid gallium indium tin alloy metal are arranged in the flow channel body, and each rod of the rod bundle matrix is provided with a plurality of gas check valves; the inert gas output assembly is correspondingly connected with the gas injection port in each rod of the rod bundle matrix; the ultrasonic probe array is arranged on the periphery of the rod bundle matrix and inside the central rod; and the fluid circulation assembly is used for driving the fluid in the flow channel body to act from top to bottom and separating the gas out of the flow channel body. The device is mainly used for simulating liquid metal cooling reactor bubble behaviors.
Owner:HARBIN ENG UNIV

Carbon fiber composite membrane as well as preparation method and application thereof

The invention belongs to the technical field of carbon fiber materials, and particularly relates to a carbon fiber composite membrane as well as a preparation method and application thereof. The carbon fiber composite film comprises a conductive film and polymer layers arranged on the surfaces of the two sides of the conductive film. The conductive film comprises a modified carbon fiber layer and a metal-based material arranged inside and on the surface of the modified carbon fiber layer, and the metal-based material comprises gallium and gallium oxide; the modified carbon fiber layer is obtained by modifying the carbon fiber base material with a coupling agent and polyethyleneimine. The specific modifier is adopted to modify the carbon fibers, so that the modified carbon fiber layer can provide interface binding force and binding sites, has a synergistic effect with a conductive network provided by a metal-based material containing liquid metal gallium and gallium oxide, and is combined with the polymer layer; therefore, the carbon fiber composite film has good mechanical property, self-healing property and electromagnetic shielding capability.
Owner:GUANGDONG POLYTECHNIC NORMAL UNIV +1

Preparation method of gallium-rich alloy material based on liquid metal surface segregation

The invention discloses a preparation method of a gallium-rich alloy material based on liquid metal surface segregation, gallium-rich alloy particles are obtained through a physical mixing-high-temperature alloying-electrochemical separation technology, and the method comprises the steps that active metal powder and liquid metal gallium are mixed and react at high temperature to form a solid alloy phase; and then the internal alloy is controllably driven to be segregated outwards rapidly through an electrochemical means, and separation of a solid alloy phase and a liquid gallium phase is achieved. The alloy obtained through separation is an alloy phase rich in gallium and is in a granular shape, and gallium and active metal elements are evenly distributed on particles. The method is simple in process, high in process controllability and applicable to preparation and separation of various gallium-rich active alloys.
Owner:TIANJIN UNIV

High load gear forming grinding device based on ultrasonic-assisted liquid gallium phase transformation strengthening

The application provides a high-load gear forming grinding device based on ultrasonic-assisted liquid gallium phase transformation strengthening, which comprises a control module, an ultrasonic atomization module, a circulating liquid supply module, a temperature control module, a processing module and a recycling module. The control module is integrated with temperature, current and pressure controllers and dynamically adjusts ultrasonic frequency, liquid gallium flow and nitrogen pressure. The ultrasonic atomization module is composed of a high-porous high-pressure nozzle and an ultrasonic oscillation device and utilizes high-speed airflow to push liquid gallium droplets into a grinding area. The circulating liquid supply module composed of sectional spiral high-frequency electromagnetic coils ensures the stable circulation of liquid gallium supply and recycling. The temperature control module monitors the temperature distribution of the workpiece surface under high dynamic load of the grinding wheel through an infrared temperature sensor and controls the cooling rate and cooling area in a closed loop according to the actual grinding process changes in the processing process. The recycling module is used for recycling liquid gallium and realizing the reuse of liquid gallium.
Owner:HUNAN INSTITUTE OF SCIENCE AND TECHNOLOGY

Intelligent body armor containing self-repairing micro-channels and three-dimensional damage assessment method

The invention relates to the technical field of body armor, and discloses an intelligent body armor containing self-repairing micro-channels, which comprises an outer protective layer, a middle bulletproof functional layer and a sensing layer, the main line micro-channel is arranged between the middle bulletproof functional layer and the sensing layer, and a liquid gallium indium tin alloy is arranged in the main line micro-channel to form a circuit; the branch micro-channel comprises a first branch micro-channel and a second branch micro-channel, the first branch micro-channel is communicated with the multiple channels in the main micro-channel, the second branch micro-channel is communicated with part of the channels in the main micro-channel, and the second branch micro-channel is communicated with the first branch micro-channel; when the main line micro-channel of the body armor is damaged to form a to-be-repaired channel gap, the branch line micro-channel enables the main line micro-channel to be kept in a power-on state, liquid gallium-indium-tin alloy near the to-be-repaired channel flows to the gap, and the gap of the to-be-repaired channel is made to be communicated with the main line micro-channel recovery circuit after being filled.
Owner:JIAXING UNIV

Hydrogen-producing acid-resistant liquid metal particle and preparation method and application thereof

The invention belongs to the technical field of medicines, and relates to hydrogen-producing acid-resistant liquid metal particles and a preparation method and application thereof. The hydrogen-producing acid-resistant liquid metal particle comprises a liquid gallium-indium alloy nanoparticle, a hyaluronic acid layer wrapping the liquid gallium-indium alloy nanoparticle and a sodium alginate layer wrapping the hyaluronic acid layer, and the hydrogen-producing acid-resistant liquid metal particle can completely pass through gastric juice and trigger hydrogen to be continuously released in a colon alkalescence environment, so that intestinal mucosa injury is repaired, and the intestinal mucosa healing effect is improved. The disordered intestinal flora can be improved.
Owner:XIEHE HOSPITAL ATTACHED TO TONGJI MEDICAL COLLEGE HUAZHONG SCI & TECH UNIV

Biosensor based on heterojunction field effect transistor and preparation method thereof

The invention relates to the technical field of semiconductors, in particular to a heterojunction field effect transistor-based biosensor and a preparation method thereof, the biosensor comprises a substrate, a graphene / molybdenum disulfide heterojunction, a liquid metal electrode and a microfluidic module; a central liquid flow channel, a grid electrode pore channel and two groups of electrode channels are formed in the micro-fluidic module; each group of electrode channels comprises two electrode hole channels of which the bottoms are communicated, and the inlet end of one electrode hole channel is used for inserting a wire of external connecting equipment; and the inlet end of the other electrode hole channel is used for infusing liquid gallium-indium alloy to form a liquid metal electrode so as to connect the heterojunction with a wire. According to the invention, by introducing a modular heterojunction film construction method, the assembled preparation of each functional component of the biosensor is realized, the overall manufacturing complexity and time cost are remarkably reduced, the experimental repeatability and the feasibility of large-scale preparation are improved, and the high sensitivity and high specificity of extremely low concentration biomolecule detection are realized.
Owner:SHENZHEN INST OF ADVANCED TECH CHINESE ACAD OF SCI

Method for constructing functional interface on metal surface at low temperature through ultrasonic-assisted liquid gallium

The invention discloses a method for constructing a functional interface on a metal surface at a low temperature through ultrasonic-assisted liquid gallium, and belongs to the field of material surface modification. The method comprises the following steps: pretreating metal substrates such as copper, silver, nickel and the like, immersing the metal substrates in liquid gallium, applying low-power-density ultrasonic waves at a low temperature of less than or equal to 50 DEG C, treating for several minutes, overcoming a solid atomic diffusion barrier by utilizing an ultrasonic cavitation effect, and rapidly driving an interface alloying reaction to form an intermetallic compound functional layer; and then residual gallium is removed through centrifugation and acid pickling. According to the invention, low-temperature, rapid and controllable construction of metal surface functions is realized.
Owner:YANTAI NANSHAN UNIV +2

Precursor composition for thin film deposition, method for manufacturing thin film and thin film manufactured using the same, and electronic device comprising thin film

The present disclosure provides a precursor composition for deposition of a thin film including liquid indium precursor, liquid gallium precursor and liquid zinc precursor, a manufacturing method of the thin film by using the precursor composition, the thin film manufactured by using the precursor composition and an electronic device including the thin film.
Owner:SAMSUNG DISPLAY CO LTD +1

Method for preparing gallium-indium alloy

PCT designated stageWO2026066217A1Process efficiency improvementIndiumAlloy
The present invention provides a method for preparing a gallium-indium alloy. The preparation method comprises: roasting a mixture of a gallium-containing waste and an indium-containing waste, smelting same under a negative pressure, cooling same to obtain a liquid gallium-indium, and uniformly mixing same to obtain a gallium-indium alloy. The roasting process is used for removing some of the chlorides and sulfides from the raw materials so as to reduce corrosion to subsequent equipment. The negative-pressure smelting is divided into three stages: the first negative-pressure smelting is used for removing low-melting-point substances that have been reduced; the second negative-pressure smelting is used for removing zinc and lead elements; and the third negative-pressure smelting enables gallium and indium to vaporize within corresponding temperature ranges and volatilize with the flue, and the vapors are subsequently cooled to form a liquid form upon cooling. After uniform mixing, the gallium-indium alloy can be obtained. In summary, the preparation method provided by the present invention has a short production process and a good impurity removal effect, and also produces by-products having economic value.
Owner:CHENGDU ADVANCED METAL MATERIALS IND TECH RES INST CO LTD

An easily peelable wafer-level gallium nitride epitaxial growth system

ActiveCN122082109AAvoid the inherent contradiction between destructive strippinginhibit spontaneous contractionsPolycrystalline material growthFrom chemically reactive gasesLiquid stateSingle crystal
This invention relates to the field of single crystal growth technology and discloses an easily peelable wafer-level gallium nitride epitaxial growth system, comprising: pre-placing a liquid gallium metal layer on a substrate and epitaxially growing a gallium nitride layer thereon; applying periodic pressure fluctuations to the reaction chamber during growth to actively suppress the wettability of the liquid gallium layer; and cooling and solidifying the layer after growth to serve as a metal sacrificial layer. This invention, by constructing an active liquid interface dynamically maintained by a pressure field, transforms the physical process of heteroepitaxial growth from passive stress accumulation to active stress self-release, thereby resolving the contradiction between stress accumulation in thick film growth and subsequent non-destructive peeling. This system ensures process robustness under long-term growth.
Owner:XIANYANG VOCATIONAL TECHN COLLEGE

Application of single crystal gallium electrode in electrolytic refining and preparation method of single crystal gallium electrode

The invention discloses application of a single crystal gallium electrode in electrolytic refining and a preparation method, and belongs to the technical field of production of scattered metal gallium. The method comprises the following steps: melting and cooling metal gallium, grafting a seed crystal with a specific crystal form into obtained liquid gallium, carrying out cooling crystallization, pickling, and cutting to obtain a single crystal gallium electrode with a target crystal form and specification. A single crystal gallium electrode in a specific crystal form is subjected to acid pickling and then serves as a cathode, crude gallium serves as an anode, the cathode and the anode are placed in an electrolyte, electrolysis is conducted within the set temperature range, and refined gallium is obtained. By adopting the scheme provided by the invention, the problems that corrosion or hydrogen evolution and other side reactions are preferentially generated by utilizing the polycrystalline gallium electrode, and optimal electrochemical selective impurity pollution cannot be realized due to limitation of grain boundary defects and crystal face mixing are solved at the same time; and the problems of low current efficiency, impurity pollution, high energy consumption and unstable process caused by a common cathode material are solved.
Owner:NORTHEASTERN UNIV CHINA

Self-repairing high-thermal-conductivity modified dimethyl silicone oil and preparation method thereof

PendingCN121517911APolymer sciencePhenyl group
The invention discloses self-repairing type high thermal conductivity modified dimethyl silicone oil, which is prepared from the following ingredients in parts by mass: 70 to 85 parts of basic dimethyl silicone oil, 5 to 15 parts of phenyl alkoxy silane, 5 to 10 parts of silicon-terminated hydroxyl (-SiOH) terminated polydimethylsiloxane, 22 to 5 parts of alkoxy silane R1R2Si (OR) and 0.5 to 2 parts of liquid gallium-based alloy nanometer filling materials. The preparation method comprises the following steps: reacting a modified monomer; constructing a dynamic cross-linking system; dispersing the filler; and post-processing. Compared with the prior art, the preparation method has the advantages that the phenyltrimethoxysilane reacts with the basic dimethyl silicone oil, so that the heat-resistant stability of the material can be improved. And 2, a dynamic covalent bond network formed by silicon-terminated hydroxyl terminated polydimethylsiloxane and specific alkoxy silane can prolong the service life of the material. And 3, the liquid gallium-based alloy nanofiller with the particle size of 50-200nm can be uniformly dispersed in the matrix, so that the thermal conductivity of the material is effectively improved.
Owner:XINJIANG HESHENG SILICON NEW MATERIAL CO LTD

Low-thermal-resistance heat-conducting silica gel as well as preparation method and application thereof

The invention discloses low-thermal-resistance heat-conducting silica gel as well as a preparation method and application thereof. The low-thermal-resistance heat-conducting silica gel comprises the following raw material components in parts by mass: 100 parts of vinyl silicone oil; 1-10 parts of hydrogen-containing silicone oil; 3000 to 3800 parts of a heat conducting filler; 0.1 to 1.0 part of an inhibitor; 0.05 to 0.2 part of a catalyst; the heat-conducting filler is a mixture of aluminum oxide, boron nitride and liquid metal, and the liquid metal is liquid metal gallium or / and liquid gallium-indium alloy. The liquid metal with high thermal conductivity, aluminum oxide, boron nitride and the like are adopted to construct a main heat conduction path, so that high thermal conductivity is ensured; the filling density can be improved, the material can be directionally arranged in the horizontal direction, and the contact thermal resistance between the material and an interface is effectively reduced.
Owner:矽时代材料科技股份有限公司