791results about "Exhaust gas handling" patented technology

A method for producing hydrogen gas is provided and comprises reducing a metal oxide in a reduction reaction between a carbon-based fuel and a metal oxide to provide a reduced metal or metal oxide having a lower oxidation state, and oxidizing the reduced metal or metal oxide to produce hydrogen and a metal oxide having a higher oxidation state. The metal or metal oxide is provided in the form of a porous composite of a ceramic material containing the metal or metal oxide. The porous composite may comprise either a monolith, pellets, or particles.

A process and system for producing reducing gases are disclosed, wherein volatile components derived from coal are transformed into reducing gases suitable for utilization as synthesis gas, as a reducing agent for the direct reduction of iron ores and/or as a clean fuel.

A process for energy- and emission-optimized iron production and an installation for carrying out the process. A first partial amount of a generator gas produced in a melter gasifier is used as a first reducing gas in a first reduction zone. A second partial amount is fed to at least one further reduction zone as a second reducing gas. In addition, after CO₂ scrubbing, a partial amount of top gas removed from the first reduction zone is admixed with the generator gas after the latter leaves the melter gasifier, for cooling the generator gas.

Metallic iron is produced from a composition formed from a mixture of iron ore particles and particles of a reductant made of a biomass material, a coal or coke in a particulate form together with a flux and is processed in a loose, un-agglomerated non-pelletized, non-briquetted form in a reducing furnace to produce metallic iron directly from the ore. An excess of biomass or coal or coke reductant can be used to provide CO and H that can be recovered as a synthetic gas and converted to electrical or other energy. Metallic iron nuggets or slabs can be produced from manganiferous ores or concentrates. Manganese can be caused to enter the nugget or slab or the slag by adjusting the furnace temperature. Titaniferous ores or concentrates can be used to produce metallic iron slabs or nuggets and a titanium-rich slag.

Combined microwave heating and plasma/electric arc heating is utilized in several processes and apparatus which involve co-production of pig iron and high quality syngas, biomass to liquid fuel production, coal to liquid fuel production, co-gasification of biomass and coal, municipal solid waste treatment, waste-to-energy (agriculture waste, ASR and PEF), EAF dust and BOF sludge treatment to recover zinc and iron, hazardous bottom ash vitrification, and bromine, chlorine and sulfur removal/recycling.

A method and an integrated steel plant wherein, instead of using coke oven gases, converter gases and blast furnace top gases available as fuel for power generation or other heating purposes, these gases are more efficiently utilized as chemical agents for direct reduction of iron ores producing DRI.

DRI is charged to blast furnaces increasing production of crude steel without increasing the capacities of the coke oven plant and blast furnaces and without changes in the quality of the crude steel, or, if production rate is maintained, the fossil fuels specific consumption is significantly reduced.

Utilisation of primary fossil energy according to the invention also reduces the specific CO₂ emissions per ton of crude steel. The specific CO₂ emission in conventional integrated mills is about 1.6 tons of CO₂ per ton of crude steel.

A process for reducing iron ore particles in a moving bed reduction reactor comprising an upper reduction zone and a lower discharge zone, wherein the coke oven gas, preferably forming all the make-up for the reducing gas circulating through and reacting in said reduction zone, is first fed to said discharge (cooling) zone and thereafter said coke oven gas, conditioned by the DRI in the lower zone, is withdrawn from the reactor and fed preferably into the recycled reducing gas for injection into the reduction zone of the reactor. Heavy hydrocarbons and other components of coke oven gas which may otherwise cause fouling, corrosion, or deposits in the direct reduction plant are removed from coke oven gas by catalytic and/or adsorptive action of the DRI present in said lower zone, before being externally transferred to the reduction zone of the reduction reactor.

A bedding carbonaceous material is charged onto a hearth of a rotary hearth furnace, carbonaceous-material containing pellets containing powdery iron ore and powdery coal are placed on the bedding carbonaceous material, and the hearth is caused to pass inside the rotary hearth furnace to heat and reduce the carbonaceous-material containing pellets to solid reduced iron and to heat and dry the bedding carbonaceous material by distillation into char. Subsequently, the solid reduced iron and the char are charged into an iron-melting furnace without being substantially cooled, and an oxygen gas is blown into the iron-melting furnace to melt the solid reduced iron, thereby obtaining molten iron. At least a part of an exhaust gas from the iron-melting furnace is used as a fuel gas for the rotary hearth furnace after being cooled and having dust removed.

A method of treating an offgas includes purifying the offgas to remove particulate matter, water, undesirable gaseous components and inert gases to produce a dried carbon oxide gas feedstock, and converting at least a portion of carbon oxides in the dried carbon oxide gas feedstock into solid carbon. In other embodiments, a method includes passing a dried carbon oxide gas feedstock through a multi-stage catalytic converter. A first stage is configured to catalyze methane-reforming reactions to convert methane into carbon dioxide, carbon monoxide and hydrogen with residual methane. A second stage is configured to catalyze the Bosch reaction and convert carbon oxides and hydrogen to solid carbon and water.

Calories of a first mixed gas are predicted by calculations based on the mixed flow rate of a blast furnace gas and the mixed flow rate of a converter gas measured by flow meters, and preset blast furnace gas calories and converter gas calories; the flow rate ratio of the mixed flow rate of a coke oven gas to a gas turbine consumed fuel gas flow rate is calculated based on the predicted calories, set calories, and preset coke oven gas calories; the mixed flow rate required value of the coke oven gas is calculated based on the flow rate ratio and a gas turbine fuel gas requirement signal corresponding to the gas turbine consumed fuel gas flow rate; and the opening of a coke oven gas flow control valve provided in a fuel gas production system is controlled, based on the mixed flow rate required value, to control the mixed flow rate of the coke oven gas.

PCT No. PCT/KR97/00275 Sec. 371 Date Aug. 20, 1998 Sec. 102(e) Date Aug. 20, 1998 PCT Filed Dec. 19, 1997 PCT Pub. No. WO98/28449 PCT Pub. Date Jul. 2, 1998A 3-stage fluidized bed type iron ore reducing apparatus having X shaped circulating tubes is disclosed for forming a gas pore fluidizing layer of a fine iron ore, and for drying/pre-heating it to reduce it, so that the gas utilization rate and the reducing rate can be improved, as well as decreasing the gas consumption rate. The present invention relates to a 3-stage fluidized bed type iron ore reducing apparatus having X shaped circulating tubes comprising: a shaft type single type first fluidized bed furnace where a raw fine iron ore is dried and pre-heated in a bubbling fluidization state; a first cyclone for collecting fine iron ore particles from a exhaust gas of said first fluidized bed type furnace; a shaft type single type second fluidizing bed furnace where the dried and pre-heated fine iron ore is pre-reduced in a bubbling fluidization state; a second cyclone for separating the fine iron ore particles from a exhaust gas from said second fluidizing bed type furnace so as to re-circulate them; a twin type third fluidized bed furnace consisting of a first reaction furnace and a second reaction furnace, for separating the pre-reduced iron ore from said second fluidized bed type furnace into coarse particles and medium/fine particles so that the coarse particles and medium/fine particles ore finally reduced in separate reactors in bubbling fluidization states; and a third cyclone for separating fine iron ore particles from the exhaust gas of said second reaction furnace of said third fluidized bed type furnace so as to re-circulate them to said first reaction furnace.

A method and apparatus for reducing iron oxides using microwave heating in a furnace chamber which is sealed against the entrance of air reduces the energy required and produces a low temperature reduction and allows the recovery of combustible synthetic gas as a byproduct of the process. Avoidance of the reduction of sulfur, phorphorus and silica is also insured, as is the need to reduce the silica content of the feed material prior to reducing the ore. A continuous rotary hearth furnace, a rotary kiln, a linear conveyor and vertical shaft furnace chamber configurations are described. A secondary heating zone can also be included to process the reduced iron into iron nuggets or liquid metallic iron.

An apparatus and method for adjusting the parameters of a reducing gas stream prior to introduction into a direct reduction furnace, such parameters including temperature of the gas stream, and amount of hydrocarbon, carbon monoxide, and hydrogen contained in the reducing gas. The apparatus is placed in-line with the reducing gas recycle loop of a direct reduction furnace, which has an enrichment section which introduces hydrocarbon components to the main stream, and an oxygen/fuel injection system, located downstream from the enrichment section, which injects a shrouded stream of oxygen and hydrocarbon gas into the reducing gas stream. Temperature, carbon monoxide content, and hydrogen content of the reducing gas are adjusted by controlling the flow of oxygen and the ratio of hydrocarbon to oxygen injected in the oxygen/fuel injection system. Hydrocarbon content of the reducing gas is adjusted primarily by controlling the flow rate of the enrichment section.

A smelting reduction method comprising (a) charging a carbonaceous material and an ore into a reacting furnace to directly contact the carbonaceous material and the ore; (b) reducing the ore until at least a part of the ore is metallized, the resultant reduced ore containing at least a part of metallized metal being produced; (c) charging the carbonaceous material and the ore containing at least a part of the metallized metal from step (b) into a smelting furnace having a metal bath; and (d) blowing a gas containing 20% or more of oxygen into the metal bath in the smelting furnace to produce molten iron.

An apparatus and a method for manufacturing molten pig iron by using a fine iron ore are disclosed. Coal is used to produce a reducing gas, and a fine iron ore is used to produce a molten iron and a reduced iron in a simple and efficient manner. The apparatus for manufacturing a molten iron by directly using coal as the fuel according to the present invention is characterized as follows. A high temperature reducing gas is sent from a melter-gasifier for a fluidized bed lime stone calcining furnace to calcine lime stone. Then the reducing gas is supplied to a second fluidized bed reducing furnace so as to manufacture a reduced iron directly. An off-gas from the second fluidized bed reducing furnace is supplied to a first fluidized bed reducing furnace disposed above the second fluidized bed reducing furnace to pre-heat and pre-reduce the fine iron ore. The calcined lime stone and the finally reduced iron are supplied to a melter-gasifier to manufacture a molten pig iron.

A process that produces pozzolanes, synthetic blast furnace slags, belite, or alite clinkers, as well as pig iron alloys, from oxidic liquid slag. The oxidic liquid slag is reduced above an iron bath in a reactor containing submerged tuyeres. Carbon is blown through the submerged tuyeres and into the iron bath to maintain the iron bath at a carbon content of between 2.5 wt % and 4.6 wt %.

The invention discloses a liquid molten slag dry-type centrifugal granulation and afterheat recycle system having molten slag buffer-storage and flow control functions. The system comprises a molten slag buffer-storage and flow control unit, a granulation unit, a mobile bed unit and an afterheat utilization unit; the molten slag buffer-storage and flow control unit is arranged at the upper part ofthe granulation unit and is used for buffer-storage of the liquid molten slag and controlling the flow rate and speed of the liquid molten slag falling to the granulation unit; the granulation unit is used for granulating the falling liquid molten slag; the mobile bed unit is arranged at the lower part of the granulation unit and is used for cooling and temporarily storing the granulated molten slag; hot air inside the granulation unit and the mobile bed unit communicates with the afterheat utilization unit; and the afterheat utilization unit comprises a hot air flue, a primary dust collector, an afterheat boiler, a secondary dust collector, an exhaust fan and a chimney which are arranged in sequence. The system disclosed by the invention does not use water resources, is free of environmental pollution, can effectively recycle high-quality afterheat resources contained in the high-temperature liquid molten slag, and can meet the urgent requirements of energy conservation and emissionreduction of the present steel and iron industry.