The invention discloses a double-glass photovoltaic module. The double-glass photovoltaic module comprises an outdoor tempered glass layer, an organic silica gel film, tempered glass, a low-radiation metal film and an indoor tempered glass layer, wherein a glass substrate, a transparent conducting layer, a photoelectric absorption layer and a back electrode layer are arranged from bottom to top in sequence; a sound insulation cavity is arranged between the tempered glass on the insider side and the low-radiation metal film; and the low-radiation metal film is adhered to the inner side of the indoor tempered glass layer. According to the double-glass photovoltaic module, a novel organic silica gel film is introduced, and through the copolymerization modification for polysiloxane molecular chains, the novel organic silicon material has excellent thermoplastic performance, can be processed into films, has good adhesion with glass, and is suitable for assembling the double-glass photovoltaic modules. Multiple performances, such as glass transition temperature and light transmittance, of the novel organic silica gel film are higher that those of a PVB or PVA material packaging material, and the performances are relatively stable after moist heat and thermo-oxidative aging of the novel organic silica gel film.