The invention relates to the technical field of salt manufacturing brine purification, in particular to a
calcium type brine
coupling synthesis
ammonia low-A
tail gas purification process which comprises the following steps: pumping raw brine from a mine and
mother liquor returned by a salt manufacturing workshop into a
primary reaction clarification tank, adding
sodium sulfate and a
calcium hydroxide solution for reaction, and precipitating Mg < 2 + > and part of Ca < 2 + > in the brine; and pumping the
clear liquid into a secondary reaction clarification tank, introducing CO2
tail gas generated by a synthetic
ammonia low-temperature
methanol washing process to perform
carbonization reaction, controlling the reaction endpoint, supplementing
sodium carbonate to completely precipitate Ca < 2 + > into
calcium carbonate, and clarifying to obtain refined brine.
Ammonia synthesis low-temperature
methanol washing CO2
tail gas is adopted to replace
flue gas of a power
plant boiler, and CO2 is provided for salt manufacturing brine purification; and the synthesized low-
methane tail gas is relatively high in CO2 content and relatively pure in component, so that the effects of reducing the brine purification cost and recycling CO2 are achieved, and the influence of dust, escaping
ammonia, heavy
metal ions and the like contained in the
flue gas of the power
plant boiler on the quality of a salt-making finished product can be avoided.