The invention relates to a lithium metal negative electrode with a double-layer interface film, preparation of the lithium metal negative electrode, and application. The double-layer interface film isattached to the surface of lithium metal; the inner layer of the double-layer interface film is a lithium fluoride inorganic layer; the outer layer of the double-layer interface film is an ether polymer layer. When the interface film is applied to a lithium metal battery, the inner-layer compact film of the interface film can inhibit dendrite growth on the surface of lithium metal, the outer-layer flexible film of the interface film can effectively relieve the breakage of the lithium fluoride layer caused by the volume expansion of a negative electrode, and therefore, interface stability is improved, continuous reaction and consumption of the lithium negative electrode and an electrolyte are inhibited, and the cycle life of the battery is prolonged. In addition, due to the introduction oforganic lithium salt into the interface film, interface lithium ion transmission is greatly accelerated, and lithium deposition uniformity is improved.