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Method of operating metal-bromine cells

a technology of metal bromine and cell, applied in the direction of electrolysis components, electrical equipment, electrochemical generators, etc., can solve the problems of troublesome operation, troublesome operation, and easy volatile liquid of molecular bromine, and achieve the effect of convenient operation

Inactive Publication Date: 2014-12-16
BROMINE COMPOUNDS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

The present invention describes a safe way to generate molecular bromine in an electrolyte solution containing bromide ions, which can be used in a metal bromine cell (specifically, a zinc bromine cell). This method involves chemically oxidizing bromide ions in an acidic environment to produce molecular bromine. This in-situ generation of molecular bromine can improve the operation of various types of bromine cells, including those with separate anolyte and catholyte streams.

Problems solved by technology

The presence of these zinc fragments in the electrolyte may interfere with the efficient operation of the cell.
However, molecular bromine is an easily volatile liquid with a strong, disagreeable odor an irritating effect.

Method used

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Examples

Experimental program
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Effect test

preparation 1

[0028]An electrolyte solution was prepared by charging into an Erlenmeyer flask the following ingredients:[0029]1) Zinc bromide brine (672 g of 76% w / w aqueous ZnBr2 solution, commercially available from ICL-IP).[0030]2) Zinc chloride brine (74 g of 50% w / w aqueous ZnCl2 solution, commercially available from ICL-IP).[0031]3) MEP (commercially available from ICL-IP as 65% w / w aqueous solution); the concentration of the MEP in the electrolyte solution was 0.5M.[0032]4) MEM (commercially available from ICL-IP as 65% w / w aqueous solution); the concentration of the MEM in the electrolyte solution was 0.5M.[0033]4) An aqueous solution of hydrogen bromide (about 7-8 g of 48% w / w solution, commercially available from ICL-IP.[0034]5) Deionized water, up to 1000 g.

[0035]The procedure set forth above was repeated to produce electrolyte solutions which were used in the following examples. The pH values of the resultant electrolyte solutions were about 2.4 (±0.5).

example 1

Bromide source and acid: HBr

Oxidizer: H2O2

[0036]To 1000 g of an electrolyte solution containing ZnBr2, ZnCl2, HBr and MEP / MEM mixture in an Erlenmeyer flask, were added consecutively under stirring at 22° C. hydrobromic acid (20 g of an aqueous 48% HBr solution) and hydrogen peroxide (3.28 g of 52% H2O2 solution). The electrolyte solution was stirred in the closed flask at said temperature for 24 hours. The electrolyte solution was sampled in order to measure the bromine concentration at 2, 4, 18 and 24 hours after the beginning of the reaction. The concentration of bromine, which was measured in the electrolyte solution 24 hour after the beginning of the reaction, was about 0.8% (w / w). The measurements were carried out using either UV-vis absorption spectroscopy (against a calibration graph) or iodometric titration.

example 2

Bromide source and acid: HBr

Oxidizer: zinc peroxide (as ZnO2 / ZnO mixture)

[0037]To 1000 g of an electrolyte solution containing ZnBr2, ZnCl2, HBr and MEP / MEM in an Erlenmeyer flask, were added consecutively under stirring at 22° C. hydrobromic acid (7 g of an aqueous 48% HBr solution) and a 1:1 mixture of ZnO2 / ZnO (1.3 g). The electrolyte solution was stirred in the closed flask at said temperature for four hours. The electrolyte solution was sampled 1, 2, and 4 hours after the beginning of the reaction in order to measure the concentration of molecular bromine. The bromine content of the electrolyte solution after four hours was ˜0.1% (measured using the techniques set forth in Example 1).

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Abstract

A method for generating molecular bromine in bromide-containing electrolyte solution suitable for use in a metal bromine cell, involves chemically oxidizing bromide (Br−) in the electrolyte solution in an acidic environment, to produce the molecular bromine.

Description

BACKGROUND OF THE INVENTION[0001]The invention relates to a method for generating elemental bromine in electrolyte solutions used for operating metal-bromine cells, such as zinc-bromine batteries.[0002]Zinc-bromine rechargeable cell contains two chemically non-reactive electrodes and a suitable separator located between the electrodes (e.g., an ion exchange membrane). The electrolyte used in the cell is an aqueous solution of zinc bromide, which is generally fed to the two compartments of the cell from two separate external reservoirs, utilizing a suitable circulation system. The term “anode” is used herein to indicate the electrode where metal zinc is formed (during charge) and oxidized (during discharge). The term “cathode” is used herein to indicate the electrode where elemental bromine evolves (during charge) and reduced (during discharge). The charge and discharge states of zinc-bromine battery will now be described in more detail.[0003]During charge, an electric current is sup...

Claims

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Application Information

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Patent Type & Authority Patents(United States)
IPC IPC(8): H01M8/18C25B1/24H01M12/08H01M10/36H01M8/20
CPCC25B1/24H01M2300/0002H01M8/20H01M10/365H01M2300/0005Y02E60/528H01M12/085H01M8/188Y02E60/10Y02E60/50
Inventor FREIBERG, MIRA BERGSTEINDAVID, IRIS BENMAGNES, BEN-ZION
Owner BROMINE COMPOUNDS
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