570results about How to "Small volume shrinkage" patented technology

A method of forming a silicon oxide layer is described. The method may include the steps of mixing a carbon-free silicon-and-nitrogen containing precursor with a radical precursor, and depositing a silicon-and-nitrogen containing layer on a substrate. The silicon-and-nitrogen containing layer is then converted to the silicon oxide layer.

Methods, materials, and systems are described for forming conformal dielectric layers containing silicon and nitrogen (e.g., a silicon-nitrogen-hydrogen (Si—N—H) film) from a carbon-free silicon-and-nitrogen precursor and radical-nitrogen precursor. The carbon-free silicon-and-nitrogen precursor is predominantly excited by contact with the radical-nitrogen precursor. Because the silicon-and-nitrogen film is formed without carbon, the conversion of the film into hardened silicon oxide is done with less pore formation and less volume shrinkage. The deposited silicon-and-nitrogen-containing film may be wholly or partially converted to silicon oxide which allows the optical properties of the conformal dielectric layer to be selectable. The deposition of a thin silicon-and-nitrogen-containing film may be performed at low temperature to form a liner layer in a substrate trench. The low temperature liner layer has been found to improve the wetting properties and allows flowable films to more completely fill the trench.

The invention discloses a heat-dissipating double-sided adhesive tape with an ultrahigh heat conductivity coefficient. Ethylene glycol or triethylamine is added into a polyamic acid solution, the resulting mixture is put in an oven in a vacuum environment and maintained at 100 DEG C for 0.9-1.1 hours, the temperature is raised to 300 DEG C and maintained for 0.9-1.1 hours, followed by natural cooling, to produce a polyimide film; the polyimide film is heated up to 250 DEG C from room temperature and then heated up to 500 DEG C, and further heated up to 1200 DEG C at a rate of 9-11 DEG C/min, to produce a prefired carbonized film; the prefired carbonized film obtained in the step 4 is rolled by a calendar; the rolled product is heated up to 2400 DEG C at a rate of 19-21 DEG C/min and maintained for 0.9-1.1 hours and then heated up to 2900 DEG C at a rate of 19-21 DEG C/min and maintained for 1.8-2.2 hours, followed by cooling, to produce a fired graphite film; and subsequently the graphite film is rolled to obtain a graphite coating. The heat transfer performance of the double-sided adhesive tape in both the vertical and the horizontal directions are improved, so as to prevent local overheat of the adhesive tape and ensure uniformity of heat transfer performance of the adhesive tape.

The invention discloses a preparation method and application of resin having double curing groups. The resin having double curing groups comprises epoxy monoacrylate and polyurethane acrylate chain segments and has the following structure. The molecule of the resin having double curing groups has an acrylate double bond (a curing free radical) and an epoxy group (a curing or thermally curing anion), so the brittleness of a cured film is reduced and the flexibility of the cured film is improved and the resin can be used in ultraviolet curing paint, adhesive and ink. The resin can improve large shrinkage factor of a single acrylate free radical curing system and large brittleness and poor flexibility of the UV curing film and the like and can also solve the problem that a several-resin mixed compounding system has unstable performance, uneven local curing, poor compatibility among resin and the like.

The invention discloses a curing agent for filling iron tailings and a preparation method thereof and belongs to the technical field of mine safety. The curing agent comprise the following components in parts by mass: 0-70 parts of fly ash, 10-80 parts of superfine mineral slag powder, 0-70 parts of superfine steel slag powder, 0-20 parts of an alkaline activator, 0-20 parts of an sulfate activator, 0.1-1 part of a foam stabilizer and 2-5 parts of a microcapsule in which aluminum powder is used as a core material. The preparation method of the curing agent comprises the steps of firstly weighting fly ash, superfine mineral slag powder, superfine steel slag powder, alkaline activator, sulfate activator and foam stabilizer according to the blending ratio of the components of the curing agent, adding all the components in a stirrer, quickly stirring for 5-15 minutes, adding microcapsule in which aluminum powder is used as a core material and slowly stirring for 2-5 minutes to obtain the curing agent for filling iron tailings. The curing agent for filling iron tailings provided by the invention has strong curing capability and is simple and controllable in use and operation.

Disclosed is a method for manufacturing a semiconductor device, which provides an isolation region in which a dense silicon oxide film is formed in a trench that requires high aspect ratio. The method includes forming an isolation trench using, as an etching mask, a nitride mask film formed on a substrate, forming a liner nitride film in the isolation trench, depositing a flowable silazane compound by a CVD method such that the height of the flowable silazane compound is higher than the upper surface of the nitride mask film from the upper portion of the trench, performing heat treatment under an oxidizing atmosphere to convert the flowable silazane compound film into a silicon oxide film and simultaneously densifying therefor, and planarizing the silicon oxide film to the height of the upper surface of the nitride mask film.

The invention discloses flame retardant heat-insulation foam concrete which consists of the materials by mass as follows: 30-60 parts of cement; 30-70 parts of coal ash; 10-40 parts of mineral powder; 0.05-1. 0 part of water reducing agent; 0.02-0.2 part of cellulose ether; 0.05-1.0 part of water repellent; 1-10 parts of anhydrous anhydrite; 0.06-0.2 part of polypropylene fiber; 0.1-0.4 part of foaming agent; and 0.30-0.60 part of water. The advantages are as follows: the foam concrete has high strength, low shrinkage and good water repellent property; the heat insulation performance is good and can meet different heat-insulation requirements of buildings; the preparation technology is simple; and industrial wastes such as coal ash, mineral powder and the like are utilized fully, and the flame retardant heat-insulation foam concrete has excellent environment-protection effects of utilizing waste, saving energy and the like, as well as better economic benefit.

The invention relates to a polyurethane complex film adhesive and a preparation method thereof. The polyurethane complex film adhesive comprises a solidifying agent A component and a main agent B component, wherein the solidifying agent A component is an isocyanate-terminated prepolymer obtained by reacting polyisocyanate with polyalcohol a; the main agent B component is a polyhydroxylated compound prepared by reacting special polyalcohol, epoxy resin and polyalcohol b with polyisocyanate; the mole ratio of the functional groups of the A and B components is NCO:OH=(1.0-2.0):1. The process for preparing the polyurethane complex film adhesive is simple; the prepared product has the advantages of high initial viscosity, good wetting property on a base material, good hydrolysis resistant stability, wetness and heat resistance, long opening time, good compatibility, high adhesive force on metals, chemical resistance, good compound flexible package appearance and high stripping strength, can be used for series complex films with generality, high solid content, solvent-less lamination, and the like and overcomes the defects of low solid content, poor wetness, poor hydrolysis resistance, no wetness and heat resistance, short opening period, poor composite adhesive force on the metals, and the like of a common polyurethane complex film adhesive.

The invention provides a molten nano-carbonate heat transfer and accumulation medium, and a preparation method and an application thereof, and belongs to the technical field of heat storage and transmission. The molten nano-carbonate heat transfer and accumulation medium contains a molten carbonate system formed by potassium carbonate, sodium carbonate, lithium carbonate and sodium chloride, nanoparticles are added into the molten carbonate system, and the nanoparticles are metal oxide and/or nonmetal oxide; and the nanoparticles are dispersed into the molten carbonate system, and the molten nano-carbonate heat transfer and accumulation medium is formed through compounding. The melting point of molten nano-carbonate is low, so the molten nano-carbonate heat transfer and accumulation medium has an upper limit use temperature of 800DEG C, has a good heat stability and a high heat conductivity, and is very suitable for the heat accumulation and transfer systems of industrial energy accumulation and solar photo-thermal power generation.

The invention relates to a nanometer molten binary nitrate heat-transfer heat-storage medium and a preparation method thereof and belongs to the field of solar photo-thermal electricity generation. The nanometer molten binary nitrate heat-transfer heat-storage medium is characterized in that nano-particles are dispersed in a KNO3-NaNO3 and KNO3-NaNO2 solid-liquid phase-change molten binary nitrate system at a high temperature so that the nanometer molten binary nitrate heat-transfer heat-storage medium is compounded, and the nano-particles comprise SiO2, ZnO, Al2O3, TiO2, CaO and/or MgO nanoparticles. The nanometer molten binary nitrate heat-transfer heat-storage medium solves the problem that the existing nanometer molten binary nitrate system has a low heat conductivity coefficient, poor heat stability and a narrow use temperature scope and can be widely used in the technical field of solar photo-thermal electricity generation.

The invention discloses a high fluidization micro expansive high-strength grouting material which comprises the following raw materials by mass percentage: 23-34% of cement, 3-5% of microbead, 5-7.5% of phosphorus slag composite powder, 2.5-3.5% of silica fume, 2.5-3.5% of quartz powder, 46-55% of fine aggregate, 0.7-1% of water reducer, 0.01-0.03% of defoaming agent, 2.5-3.5% of expanding agent and 0.5-1% of early strength agent. The grouting material has the advantages of high strength in the early stage and later stage, good flowing property and adjustable expansiveness by taking the cement as a major binding material and employing the silica fume, the microbead and the phosphorus slag composite powder with different hydration activities together with a chemical additive matched with a binding material system and an aggregate system with reasonable gradation, and is particularly applicable to high precision equipment mounting, secondary grouting of an equipment foundation, bolt anchoring, crack repairing, duct grouting and the like.

The invention discloses high intumescent fire stopping mastic and a method for preparing the same. The mastic is prepared by taking acrylate emulsion (or elastic styrene-acrylate emulsion), polybutene (or polyisobutylene), glycol, emulsifying agent and tritolyl phosphate as base materials with addition of certain auxiliary materials. The preparation method is as follows: the base materials are added into a reaction kettle according to certain mass portion, stirred, slowly heated and insulated for a period of time, and transferred into a colloid stirrer; auxiliary materials such as ammonium polyphosphates, flame-retarding aluminum hydroxide, flame-retarding zinc borates, calcium carbonates, expandable graphite, iron oxide red and glass fibers are gradually added into the mixture under the condition of stirring; and the process of stirring is continued until a colloid is uniform. The fire stopping mastic prepared by adoption of the method can be quickly carbonized and expanded to 5 to 8 times of the prior volume in case of fire, and can not fall off; the strength and the heat insulation after solidification are good, and the fire resistance is very good; and the adhesion is strong and the elasticity is good. The high intumescent fire stopping mastic and the method are particularly suitable for fire compartmentation of various penetrating penetration assemblies such as cables, cable bridges, pipes and so on.

The invention belongs to the field of novel 3D printing materials and in particular belongs to the field of photosensitive resin. The photosensitive resin is prepared from the following components in percentage by weight: 5-80% of acrylic ester, 5-80% of epoxy resin, 0.5-8% of a radical initiator, 0.5-5% of a cationic initiator, 5-50% of a diluent and 0.5-5% of gas phase silicon dioxide. Flexural modulus and tensile modulus of the photosensitive resin reach over 2000Mpa; the photosensitive resin is high in capability of resisting bending deformation stress in an elastic limit, high in strength, low in possibility of deforming and high in mechanical strength; the service life is greatly prolonged; the volume shrinkage rate is about 1.0%; the ultralow volume shrinkage rate is achieved; the industrial use requirement can be met.

The invention belongs to the technical field of casting, and particularly relates to a high-strength composite salt core material for low-melting-point alloy casting. The high-strength composite salt core material comprises, by mass, 70%-100% of water-soluble inorganic salt and 0%-30% of a reinforcement, wherein the water-soluble inorganic salt comprises one of low-melting-point salts including potassium nitrate and sodium nitrate, and at least one of high-melting-point salts including potassium chloride, sodium chloride, potassium bromide and sodium bromide, and positive ions of the low-melting-point slats are the same as positive ions of the high-melting-point salts. The invention further discloses a preparation method of a high-strength composite salt core, and an obtained salt core product. The prepared composite salt core has extremely high bending strength, excellent hygroscopicity and small volume shrinkage, and the comprehensive performance is excellent. In addition, the preparation technique of the high-strength composite salt core is simple, raw materials are cheap, and industrial production is easy.

The invention discloses a high-temperature-resistant photosensitive resin composition used for photocuring rapid formation. The high-temperature-resistant photosensitive resin composition comprises the following components in parts by weight: 20-70 parts of epoxy resin, 8-40 parts of acrylic resin, 10-40 parts of acrylate monomers, 0.5-5 parts of inorganic nano-particle filler, 1-20 parts of a flexibilizer, 0.5-10 parts of a free radical photoinitiator and 0.5-10 parts of a cationic photoinitiator, based on 100 parts in total. The high-temperature-resistant photosensitive resin composition is high in reaction speed, is small in volume shrinkage after being cured, is low in water absorption and is high in dimension stability of products; the products have high temperature resistance, can keep normal high-temperature-resistant requirements, have considerable toughness, and are not damaged as a result of embrittlement in a using process.

The invention belongs to the technical field of a macromolecular material and discloses a polylactic acid/polycarbonate alloy material for 3D printing and a preparation method thereof. The alloy material is prepared from the following components in parts by weight: 60-95 parts of polylactic acid, 5-40 parts of polycarbonate, 0.5-2 parts of end-group modifier, 0.5-5 parts of ester exchanger, 0-10 parts of chain extender, 1-20 parts of plasticizer and 0.1-2 parts of antioxidant. By adopting a two-step blending and modifying method, the mutual dissolution of polylactic acid and polycarbonate is promoted, the thermal stability and machinability of the alloy material are improved and the volume shrinkage of the material is reduced. The alloy material has the advantages of being low in cost and high in performance, can be applied to a 3D printing process and enriches the varieties of 3D macromolecular materials.

The present invention discloses a surface treatment agent comprising: (A) an acrylic resin having a hydrolysable silyl group, a hydroxyl group and a polysiloxane chain; (B) an organopolysiloxane having a hydrolysable silyl group; and (C) an organopolysiloxane not having a hydrolysable silyl group.

The invention belongs to a flame retardant and heat-insulation building material, relates to flame retardant and heat-insulation foamed concrete and a preparation method thereof. In the prior art, the foamed concrete has disadvantages of low strength, large shrinkage, easy cracking due to water absorption. The flame retardant and heat-insulation foamed concrete provided by the present invention comprises the following materials, wherein the materials comprise, by mass, 30-60 parts of cement, 30-70 parts of fly ash, 10-40 parts of mineral powder, 0.05-1.0 parts of a siloxane water reducing agent, 0.02-0.2 parts of a cellulose ether, 0.05-1.0 parts of a silane water-repelling agent, 1-10 parts of anhydrite, 0.06-0.2 parts of polypropylene fibers, 0.1-0.4 parts of a foaming agent and 0.30-0.60 parts of water. The flame retardant and heat-insulation foamed concrete and the preparation method provided by the present invention have the following advantages that: the foamed concrete has characteristics of high strength, low shrinkage and good water repellency; the foamed concrete has excellent heat insulation property, such that different heat insulation requirements of the building can be met; the preparation process is simple; the industrial waste materials such as fly ash, mineral powder and the like are adopted so as to protect the environment.

The invention discloses a high-hardness photosensitive resin composition used for light curing rapid prototyping. The photosensitive resin composition is prepared from, by weight, 25-60% of epoxy resin, 15-45% of acrylate oligomer, 15-35% of acrylate monomer, 1-10% of inorganic filler, 5-20% of flexibilizer, 1-8% of free-radical photoinitiator and 1-8% of cationic photoinitiator, wherein the weight percentages of all the components sum up to 100%. The photosensitive resin composition is high in hardness and high in strength, meanwhile, the high-temperature resistant requirements can be met, and the gap in the market requiring for high hardness can be filled up.

The invention discloses a room-temperature addition silicon rubber putty-type dental impression material applied to primary impression. The room-temperature addition silicon rubber putty-type dental impression material is composed of a substrate component and a catalytic component in a blending manner, wherein the substrate component is composed of vinyl silicone oil, hydrogen silicone oil, a bulking agent, an enhancer and other assistants according to a certain ratio; the vinyl silicone oil contains more than two vinyl functional groups; the hydrogen silicone oil contains more than three Si-H functional groups; the catalytic component is composed of vinyl silicone oil, a catalyst, a bulking agent, an enhancer and other assistants according to a certain ratio; and the catalyst is a complex of chloroplatinic acid and vinyl silicone oil. The room-temperature addition silicon rubber putty-type dental impression material is rational in formula, and easy to operate, the elastic recovery of the cured material can be up to 99.8%, the curing time is 3-5 minutes, the shore hardness is about 65, and the dental impression material is finely copied into 0.02mm and clearly visible, and can be applied to fabrication of accurate dental crowns, and delivery of dental bridges, false teeth, articulation registration and oral cavity tissue.