791 results about "Microporous membranes" patented technology

Improved performance ion exchange membranes for use in REM, AEM and DMFC fuel cells, buffered fuel cells, hydrolysis, other applications comprise a molecular matrix of homopolymers, di-monomer, heteropolymers, copolymers, or block-polymers of fluorocarbon and hydrocarbon compounds combined with (i) skeletal support grid to improve durability, handling, reduce membrane swelling, and sequester dopants and nanoparticles from leakage; (ii) microporous membrane formed using a sacrificial filler process enhancing conductivity and limiting fuel crossover; (iii) hetero-ionomeric matrix of two-or-more membrane-bound acids e.g. sulphonic and phosphonic acid expanding usable range; (iv) permanent fillers enhancing conductivity and porosity including nanoparticles, metal-oxides, zeolites, silicates, GOs, CNTs, MOFs, POSS, and others; (v) ionic liquid doping to enhance membrane conductivity; (vi) membrane nanocoating preventing H2O2 diffusion; and / or (vii) catalytic nanocoating with metals, metal-oxides, and MOFs preventing atmospheric toxin catalyst poisoning. Combined with a heterogenous GDI, the IEM is integrated into iBFC power blade and energy bank applications.

The invention belongs to the technical field of wastewater treatment, and particularly relates to an efficient ozone micro-nano bubble preparation system and a process method thereof. The device further comprises an ozone preparing unit, a gas conveying pipeline, a jet flow unit, a spiral mixing unit, a Venturi tube, a microporous membrane unit and a reaction unit. The ozone producing unit is connected with the jet flow unit through a gas conveying pipeline, the ozone producing unit comprises an ozone generator, and the gas inlet pressure is regulated and controlled through a gas valve in the gas conveying pipeline; and the jet flow unit is used for generating and conveying a mixed solution with ozone microbubbles. The jet flow unit enables the mixed liquid to form ozone microbubbles based on a Venturi effect and a hydraulic shearing effect; by arranging the jet flow unit, the spiral mixing unit, the Venturi tube and the microporous membrane unit, ozone micro-nano bubbles with high concentration and uniform size distribution can be generated under relatively low energy consumption, so that the treatment efficiency of the ozone micro-nano bubbles in the technical fields of wastewater treatment and environmental protection is improved.

The invention relates to the technical field of microbial culture, and provides a culture device for agricultural microbial agent production and a use method, the culture device comprises a culture box, and the top of the culture box is hermetically and detachably provided with a box cover. According to the device, the air pump is controlled by the controller to be started, so that the air pressure in the closed space is increased, the air passes through the non-woven fabric and the polymer microporous membrane, more tiny bubbles can be generated under the action of the polymer microporous membrane, a nutrient solution flows and is mixed, and the stirring effect on the nutrient solution is achieved; a nutrient solution in the incubator flows into the culture dish through the liquid discharge pipe, so that the stirring of the nutrient solution and the injection of the nutrient solution into the culture dish to be mixed with a microbial inoculum can be completed without using more structural components, the operation is simple, and the condition of pollution caused by improper cleaning is avoided; therefore, the subsequent microbial agent culture effect is improved.

The invention provides a preparation method of a composite double-layer microporous membrane, and belongs to the technical field of separation membrane preparation, different lower-layer and upper-layer membrane casting solutions are prepared respectively, the separation membrane is prepared at one time by adopting a double-scraper casting and coating method, the upper layer is thermally induced phase separation, and the lower layer is thermally induced phase separation or non-solvent induced phase separation; the double-layer liquid membrane is subjected to pre-phase splitting and pore opening in a constant-temperature and constant-humidity environment, and enters a gel bath at a certain temperature after pre-phase splitting, and a microporous membrane with a certain membrane structure is formed under the action of RTIPS and NIPS. According to the invention, a co-coating method is adopted, and VIPS, RTIPS and NIPS are used for adjusting the pore structure of the membrane, so that the microporous membrane meeting different filtering requirements is prepared; the prepared membrane product is high in flux and high in yield; the preparation process is simple and conditions are mild: the microporous membrane prepared by the method is simple in process, mild in conditions and suitable for industrial production; and the membrane structures of the upper and lower membranes can be freely adjusted.

The invention discloses a polytetrafluoroethylene microporous membrane as well as a preparation method and application thereof, and belongs to the technical field of polytetrafluoroethylene microporous membranes. According to the invention, the polytetrafluoroethylene microporous membrane added with different amounts and different types of lubricants is prepared by a thermomechanical two-way stretching method, and the pore structure is researched. According to the invention, the entanglement density, the average pore size, the porosity, the hydrophobic property and the mechanical property can be regulated and controlled by changing the quantity and the type of the lubricant. And a new idea is provided for preparing the high-performance PTFE biaxially oriented film, and the method has a good application prospect.

The present application relates to the technical field of separator material preparation, and specifically relates to a microporous membrane, and a preparation method therefor and an application thereof. The microporous membrane comprises a polymer and an ionic liquid. Based on the total mass of the microporous membrane, the microporous membrane comprises 0.01 wt% to 5 wt% of the ionic liquid, optionally 0.1 wt% to 5 wt% of the ionic liquid. In the present application, an appropriate amount of the ionic liquid is introduced into the microporous membrane, and the ionic liquid can be continuously or discontinuously adsorbed on the surfaces of fibers in the microporous membrane. The ionic liquid is adsorbed on the surfaces of the fibers in the microporous membrane by means of a lipophilic end of the ionic liquid, thereby eliminating internal static electricity, also better reducing the reduction of ionic conductivity, increasing the migration speed of ions in an electrolyte, and reducing lithium dendrites. When the microporous membrane of the present application is used as a battery separator, an appropriate amount of the ionic liquid is added into the microporous membrane, so that the problem of electrostatic accumulation of the microporous membrane can be alleviated, and the microporous membrane has relatively low thermal shrinkage, avoiding problems such as affecting battery capacity, electrochemical safety.

The invention provides an organ chip unit for simulating the pathogenesis of rheumatoid arthritis, and belongs to the technical field of cell culture. The chip comprises a top-layer chip, a bottom-layer chip and a middle microporous membrane, the top-layer chip and the bottom-layer chip are separated by the middle microporous membrane, and the middle microporous membrane is used for enabling cells in a cell culture space of the top-layer chip and cells in a cell culture space of the bottom-layer chip not to be in direct contact, but interaction of signal molecules and substance exchange can be carried out; synovial cells and cartilage cells are injected into the bottom-layer chip or the top-layer chip to be cultured. According to the invention, multi-cell three-dimensional co-culture can be realized. Through the additional stress stimulation co-culture part, the influence of pressure or tension on the cell environment can be judged, and the actual condition that rheumatoid arthritis joints receive pressure or tension for a long time can be simulated. The synovial cells and the cartilage cells are used, so that the structure of the inflammation joint in a living body can be truly reflected, and the interaction among various cell tissues can be reflected.

The preparation method comprises the following steps: mixing corncobs, a carbon source, rice husks, a nitrogen source and a conditioner, and adjusting the initial moisture content of the mixture to 55-65% so that the C / N ratio reaches (25-30): 1 to obtain a pile body; covering the surface of the pile body with a nano microporous membrane, starting an aeration system in a high-temperature stage, adjusting the air pressure difference inside and outside the membrane to 50-100Pa in a cooling stage, and continuously fermenting; after 7-10 days of fermentation, when the pH value of the base material is stable and the total nutrient meets the requirement, the fermentation is completed, the base material is bagged and sterilized, and the tricholoma matsutake cultivation base material is obtained. According to the method, the fermentation period is shortened to 1 / 3-1 / 2 of that of a traditional method, and the production efficiency is improved. In addition, the infectious microbe contamination rate of the base material is reduced, the purity and quality of the base material are improved, and a healthier environment is provided for growth of tricholoma matsutake. And the yield of tricholoma matsutake is increased by 40%. Not only is the yield of tricholoma matsutake increased, but also the nutritional value of tricholoma matsutake is improved, and higher economic benefits are brought to farmers.

The present invention provides a ship exhaust gas desulfurization device and a desulfurization method, which include a sulfur-containing ship exhaust gas pretreatment system, a seawater pretreatment system, a membrane contactor, and a seawater post-treatment system; the outlet end of the sulfur-containing ship exhaust gas pretreatment system is connected to the shell-side inlet end of the membrane contactor for sending the dust- and oil-removed exhaust gas into the shell side of the membrane contactor; the outlet end of the seawater pretreatment system is connected to the tube-side inlet end of the membrane contactor for sending the pretreated seawater into the tube side of the membrane contactor; the membrane contactor is a membrane contactor filled with polytetrafluoroethylene hollow fiber hydrophobic microporous membranes; the inlet end of the seawater post-treatment system is connected to the tube-side outlet end of the membrane contactor for post-treating the seawater after absorbing sulfur dioxide and oxidizing sulfite into sulfate. The ship exhaust gas desulfurization device described in the present invention has a high integration degree, a compact volume, and a high desulfurization efficiency, can achieve efficient desulfurization of ship exhaust gas, and has good application prospects.

The invention discloses an anti-ultraviolet high-flame-retardant polyester fiber and a preparation method thereof. The polyester fiber is prepared from the following raw materials in parts by weight: 100 parts of polyester chips, 20-60 parts of core-shell flame-retardant anti-ultraviolet particles and 2-4.5 parts of an anti-dripping agent. According to the invention, a porous alumina-titanium dioxide compound is used as a carrier, a magnesium hydroxide flame retardant, iron-doped carbon dots with photo-thermal performance and auxiliaries (an antioxidant and an ultraviolet light absorber) are combined with the carrier to construct a structural system loaded with multiple active components: functionalized flame-retardant particles, and then a polyurethane microporous membrane is coated, so that the flame-retardant polyurethane composite material is obtained. The core-shell type flame-retardant anti-ultraviolet particles are added into polyester fibers, so that the anti-ultraviolet performance and the flame-retardant performance of the polyester fibers can be remarkably improved. The polyester fiber provided by the invention can adaptively increase the release rate of the ultraviolet absorbent and the antioxidant when the ultraviolet property is enhanced in the environment, so that more optimized protection can be provided for a polyester fiber matrix at the moment.

The invention belongs to the technical field of diaphragm material preparation, and particularly relates to a microporous membrane as well as a preparation method and application thereof. The microporous membrane comprises a polymer and an ionic liquid, and the microporous membrane comprises 0.01 wt%-5wt% of the ionic liquid, optionally 0.1 wt%-5wt% of the ionic liquid, based on the total mass of the microporous membrane. A proper amount of ionic liquid is introduced into the microporous membrane, the ionic liquid can be continuously or discontinuously adsorbed on the surfaces of the fibers in the microporous membrane, and the ionic liquid is adsorbed on the surfaces of the fibers in the microporous membrane through the oleophylic end of the ionic liquid, so that internal static electricity can be eliminated, and reduction of ionic conductivity can be better avoided; and the ion migration speed of the electrolyte is increased, and lithium dendrites are reduced. When the microporous membrane is used as a battery diaphragm, a proper amount of ionic liquid is added into the microporous membrane, so that the problem of electrostatic accumulation of the microporous membrane is solved, meanwhile, the microporous membrane has relatively low thermal shrinkage, and the problems that the battery capacity is influenced, the electrochemical safety is caused and the like are avoided.

The invention belongs to the technical field of waterproof and moisture permeable membrane materials, and particularly relates to a bio-based microporous membrane based on a template and a preparation method and application thereof, and the preparation method comprises the following steps: dispersing one of polybenzimidazole, aminated PI and carboxylated PBO and modified CNF into a DMF / water system; performing electrostatic spinning on the high-viscosity spinning solution; carrying out low-temperature vacuum drying treatment on the modified nanofiber self-supporting framework; coating and filling the bio-based polyurethane resin into the bio-based microporous membrane template, and carrying out negative pressure adsorption until the filling is uniform; and carrying out gradient drying on the bio-based wet membrane to obtain the bio-based microporous membrane. Compared with the prior art, the problems that in the prior art, the mechanical property or stability of bio-based polyurethane is insufficient, and a nanofiber reinforcing technology is difficult to combine with the bio-based polyurethane are solved. A nanofiber self-supporting framework with a stable structure is prepared through an electrostatic spinning technology, and then the nanofiber self-supporting framework is compounded with bio-based polyurethane to form a microporous membrane layer with waterproof and moisture permeable functions.

The invention discloses a waterproof and moisture-permeable composite film and a preparation method thereof, a waterproof and moisture-permeable fabric and clothes. The waterproof moisture-permeable composite film comprises a microporous film, a ceramic layer and a waterproof layer, wherein the ceramic layer is arranged on the surface of one side or two sides of the microporous film in a laminated manner; the waterproof layer is arranged on the surface of the ceramic layer in a laminated manner; the ceramic layer comprises ceramic particles, the waterproof layer comprises a cross-linked substance of a waterproof finishing agent, or the waterproof moisture-permeable composite film comprises a microporous film and a composite layer laminated on the surface of one side or two sides of the microporous film, and the composite layer comprises ceramic particles and a cross-linked substance of a waterproof finishing agent. The waterproof and moisture-permeable composite film can be used for preparing a waterproof and moisture-permeable fabric. The waterproof and moisture-permeable composite film disclosed by the invention has excellent waterproof performance and washing resistance while keeping good air and moisture permeability.

The invention provides a preparation method and application of a dual-cleaning polytetrafluoroethylene microporous membrane, and the preparation method comprises the following steps: 1) heating polyethyleneimine and 1, 3-propane sultone in one step to form a polyion liquid, and dissolving the polyion liquid and dopamine in a Tris aqueous alkali to obtain a buffer reaction liquid; 2) soaking a polytetrafluoroethylene microporous membrane in a buffer reaction solution, heating and reacting, and then taking out to obtain a first microporous membrane; 3) soaking the first microporous membrane in a ferric chloride hexahydrate aqueous solution for heating reaction, and then taking out the first microporous membrane to obtain a second microporous membrane; 4) soaking the second microporous membrane in a copper acetate methanol solution for heating reaction, and then taking out to obtain a third microporous membrane; 5) soaking the third microporous membrane in a methanol solution of 2, 5-dihydroxy terephthalic acid, heating and reacting, and then taking out to obtain a fourth microporous membrane; and 6) washing and drying the fourth microporous membrane to obtain the dual self-cleaning polytetrafluoroethylene microporous membrane. The dual self-cleaning polytetrafluoroethylene microporous membrane is high in separation efficiency, high in flux recovery rate and low in pollution rate in treatment of high-viscosity emulsified oil-containing wastewater.

The present invention provides a waterproof breathable membrane, a preparation method therefor, and a composite fabric comprising same. The preparation method for a waterproof breathable membrane comprises: performing first mixing of a polyolefin raw material and a solvent to obtain a premixed gel; performing second mixing of an elastomer and a solvent, and then performing third mixing with the premixed gel to obtain a mixed gel; performing melt extrusion on the mixed gel to obtain an initial gel membrane, followed by performing initial stretching on a biaxial stretching machine, and then extracting by using an extracting agent to obtain an initial microporous membrane; and performing expanded stretching on the initial microporous membrane, and performing heat setting and rapid high-temperature treatment in sequence. The waterproof breathable membrane is prepared by the described preparation method. The composite fabric is composed of an inner layer fabric, an outer layer fabric, and the waterproof breathable membrane provided by the present invention which is compounded between the inner layer fabric and the outer layer fabric. The preparation method provided by the present invention facilitates industrial promotion and use, and the obtained product possesses excellent waterproof and breathable properties, as well as higher tensile strength and elongation at break.

The invention provides a polypropylene microporous membrane as well as a preparation method and application thereof. The polypropylene microporous membrane comprises polypropylene resin, an inorganic nano material and a coupling agent, the relative molecular mass of the polypropylene resin is in a range of 1000000 Da to 2000000 Da. The polypropylene resin is used as a matrix, the inorganic nano-material and the coupling agent are added at the same time to modify the polypropylene resin, and the polypropylene resin, the inorganic nano-material and the coupling agent have a synergistic effect, so that the mechanical strength, surface tension and other physical properties of the polypropylene film can be further improved; therefore, the base film is prevented from wrinkling and deforming in the preparation process of the composite current collector, and the production yield and the physical performance of the composite current collector are improved.

The invention discloses a polyvinylidene fluoride network-like microporous membrane, a preparation method and application. The polyvinylidene fluoride network-like microporous membrane has an average pore size of 0.40-0.55 [mu] m, an average pore size distribution (PSD) of 65-80%, a tensile strength of 6.5-11 MPa and an elongation at break of 150-350%. The membrane surface of the polyvinylidene fluoride network microporous membrane is provided with a skin layer, the inside of the membrane is provided with a network pore structure, and the polyvinylidene fluoride network microporous membrane has the advantages of high mechanical strength, high water flux, high protein adsorption capacity, high filtering precision, high stability and the like.

The purpose of the present disclosure is to provide: a separator for power storage devices, the separator having high adhesion to an electrode and a low thermal shrinkage ratio, while being capable of improving the cycle characteristics and output characteristics of a power storage device; and a power storage device which comprises this separator for power storage devices. A separator for power storage devices according to the present disclosure comprises: a base material which is formed of a polyolefin microporous membrane that contains a polyolefin as a main component; and a cover layer which is arranged on at least one surface of the base material.

The present disclosure provides a composite cooling film including a micro-voided film layer that has a solar weighted reflectivity at normal incidence of electromagnetic radiation over a majority of wavelengths in a range of 400 nanometers (nm) to 2500 nm of 0.8 or greater. The composite cooling film also includes a UV reflecting composite layer disposed adjacent to a major surface of the micro-voided film layer. The UV reflecting composite layer includes a polymeric matrix and inorganic particles distributed in the polymeric matrix. The UV reflecting composite layer exhibits an average reflectance of electromagnetic radiation of at least 55% over a wavelength bandwidth of at least 30 nm within a wavelength range from 300 nm and up to but not including 400 nm.

The invention relates to a preparation technology of a polyurethane nanoscale microporous membrane for protective clothing, and belongs to the technical field of clothing fabric preparation, and the preparation technology specifically comprises the following steps: extracting silk fibroin and carrying out hydrophobic modification to obtain modified silk fibroin; then, the modified cellulose and polyurethane are mixed and dissolved in a solvent, a pore-forming agent and breathable particles obtained by mixing the modified cellulose and aerogel powder are added, and a mother solution is prepared; and finally, preparing a membrane by using the mother liquor, thereby obtaining the polyurethane nano-scale microporous membrane for the protective clothing. According to the process, modified silk fibroin and a polyurethane material are mixed, and breathable particles obtained by mixing modified cellulose and aerogel powder are added, so that the mechanical property of the membrane is remarkably improved, and the breathability is optimized. Meanwhile, through acetylation treatment on silk fibroin and modification on carboxymethyl cellulose by using dopamine hydrochloride, the overall performance of the material and the stability in the preparation process are further improved.

The invention discloses a straw leavening agent suitable for a microfiltration membrane fermentation system and application of the straw leavening agent, and relates to the technical field of biology. The straw leavening agent comprises a microorganism combination. The microbial composition is prepared from bacillus subtilis (Bacillus subtilis) 1JN2, streptomyces globisporus (Streptomyces globisporus) XS2301 and myroides odortorius (Myroides odortorius) YW-1, and the microbial composition is prepared from bacillus subtilis (Bacillus subtilis) 1JN2, streptomyces globisporus (Streptomyces globisporus) XS2301 and myroides odortorius (Myroides odortorius) YW-1. The straw fermenting agent can improve the humification index in the straw composting process, remarkably shorten the composting period of crop straw and effectively reduce volatilization of irritant gas such as ammonia gas and hydrogen sulfide in the straw composting process. The straw leavening agent provided by the invention not only can efficiently treat crop straws, but also has the dual advantages of environmental protection and agricultural yield increase, and provides important technical support for agricultural sustainable development.

The invention relates to the technical field of fabrics and manufacturing thereof, and discloses a novel anti-fouling cold-proof garment fabric and a process thereof. The preparation process comprises the following steps: S1, mixing polyethylene glycol and polyvinylpyrrolidone in proportion to obtain a spinning solution; s2, performing electrostatic spinning on the spinning solution to obtain phase change fibers; s3, respectively spinning the phase change fibers and the blend fibers, and then blending and interweaving the phase change fibers and the blend fibers with the thermal insulation filler to obtain fiber cloth; s4, nano titanium dioxide is prepared, the prepared nano titanium dioxide is subjected to deposition treatment through a vacuum evaporation method, and a nano titanium dioxide microporous membrane is obtained; s5, spinning and interweaving glass fibers to form glass fiber cloth; s6, the fiber cloth, the nano titanium dioxide microporous membrane and the glass fiber cloth are subjected to hot-pressing compounding, and the three-layer composite garment fabric is obtained. The garment fabric has the advantages of cold resistance, stain resistance and scratch resistance, and can be better suitable for being used in a severe environment.

The invention discloses a polyimide intrinsic microporous membrane, a diamine monomer adopted by the polyimide intrinsic microporous membrane and a preparation method of the polyimide intrinsic microporous membrane and the diamine monomer. The polyimide intrinsic microporous membrane is prepared from a dianhydride monomer and the diamine monomer with a dibenzo spirofluorene xanthene structure, the diamine monomer with the dibenzo spirofluorene xanthene structure is prepared by the following steps: firstly, condensing substituted or unsubstituted 2-nitro-9-fluorenone with 1-naphthol, then carrying out nitration, and finally, carrying out reduction, thereby obtaining the diamine monomer with the dibenzo spirofluorene xanthene structure. The dibenzo spirofluorene xanthene structure contained in the polyimide intrinsic microporous membrane can effectively reduce the dielectric constant of a polymer, the polyimide intrinsic microporous membrane can be applied to the technical field of electronics and microelectronics, the asymmetric diamine structure enables a main chain of a macromolecular chain to be twisted, the twisted macromolecular chain can effectively enlarge interchain pores, and therefore the polyimide intrinsic microporous membrane has the advantages that the dielectric constant of the polymer can be effectively reduced; therefore, the free volume of the polymer is increased, the polymer has higher permeability, selectivity can be balanced, and the polymer can be applied to the technical field of membrane separation.

The invention relates to a heterogeneous polyelectrolyte self-assembled membrane as well as a preparation method and application thereof. In the flowing process of the electrolyte of the flow battery, the polyanion compound in the electrolyte on one side and the polycation compound in the electrolyte on the other side are self-assembled on the glass fiber substrate in the middle under the action of strong electrostatic adsorption to form the diaphragm of the flow battery, namely the heterogeneous polyelectrolyte self-assembled membrane. The microporous membrane has good mechanical properties and ionic conductivity, and the formed microporous membrane structure can effectively inhibit interpenetration and mixing of redox active molecules in the flow battery. The aqueous flow battery system assembled by the heterogeneous polyelectrolyte self-assembled membrane and typical oxidation-reduction active organic molecules still keeps the initial capacity of 97% or above after 2000 charge-discharge cycles. Compared with the prior art, the heterogeneous polyelectrolyte self-assembled membrane provided by the invention can effectively inhibit capacity attenuation caused by permeation and cross mixing of electrolyte redox active molecules in an aqueous flow battery through the membrane.

Disclosed are a virus-removal composite membrane and a preparation method thereof. A virus-removal composite membrane comprises a main body, wherein the main body comprises: a porous substrate layer including a liquid inlet surface and a separation layer including a liquid outlet surface, the porous substrate layer is a microporous membrane layer formed by a first polymer, the separation layer is formed by a second polymer, and the first polymer and the second polymer are different polymer materials; in a region of the porous substrate layer close to one side of the separation layer, the second polymer permeates from a surface of the porous substrate layer into a pore structure of the porous substrate layer to form a bonding region, and pores formed by the second polymer in the bonding region are connected to pores of the separation layer.

The invention provides a multistage composite microporous membrane electrode, a preparation method thereof and a water treatment and purification method. The multistage composite microporous membrane electrode comprises an inorganic ceramic microfiltration membrane, an anode electrocatalytic active layer and a cathode electrocatalytic active layer, the anode electrocatalytic active layer and the cathode electrocatalytic active layer are respectively positioned on two sides of the surface of the inorganic ceramic microfiltration membrane; the thickness of the inorganic ceramic microfiltration membrane is 2-6 mm, the thickness of the anode electrocatalytic active layer is 100-800 nm, and the thickness of the cathode electrocatalytic active layer is 1 [mu] m-1 mm; silicite nanocrystals are loaded on the inner walls of pore channels of the inorganic ceramic microfiltration membrane. The particle size of the silica zeolite nanocrystal is 50 to 200 nm. When the multi-stage composite microporous membrane electrode provided by the invention is used for water treatment and purification, oxygen molecules can be efficiently enriched in micropores, the conversion efficiency of hydroxyl radicals is improved, and efficient removal of refractory organic matters is realized.

The invention relates to the technical field of high-molecular compounds, in particular to a PTFE microporous membrane and a preparation method and application thereof. The composite conductive material is prepared from the following components in parts by weight: 55 to 65 parts of PTFE dispersion resin, 5 to 8 parts of graphene quantum dot / carbon nanotube and metal organic framework composite conductive phase, 6 to 9 parts of POSS-graphene hybrid modified nano silicon dioxide, 7 to 10 parts of fluorosilane grafted polyether-ether-ketone-polyimide block copolymer, 3 to 5 parts of nano hydroxyapatite-chitosan composite particles and 10 to 15 parts of composite pore-foaming agent. 1 to 3 parts of organic montmorillonite; wherein the grafting rate of the block copolymer is 25-30%, the fluorine content is 12-15 wt%, and the silicon-oxygen bond density is 0.8-1.2 mmol / g. The preparation method has the advantages of good mechanical properties and stability, multifunction synergy, pollution resistance, good biocompatibility, process optimization, improvement of consistency, meeting of multi-field requirements, and wide application prospect.

The utility model relates to the technical field of paper product packaging boxes, and discloses a moisture-proof paper product packaging box which comprises a box body, a cover plate is arranged on the upper surface of the box body, a microporous membrane is arranged on the inner wall of the box body, and a drainage groove is formed in the edge of the bottom in the box body. Water outlet holes are formed in the left side and the right side below the front face of the box body, the left side and the right side below the back face of the box body and two corners below the left side and the right side of the box body, grooves are formed in the middles of the upper portions of the left side and the right side of the box body, and a plurality of protruding rods are arranged on the front face and the back face of the box body. The microporous membrane is arranged on the inner wall of the carton body, is made of polyethylene materials and has air permeability, water vapor can penetrate through the inner wall of the carton body, but water drops cannot penetrate into the inner wall of the carton body, the drainage groove is embedded in the edge of the bottom in the carton body, and water on the surface of the microporous membrane falls into the drainage groove and is discharged outwards through the drainage holes. Therefore, the moisture-proof effect of the packaging box is effectively improved.

The invention discloses an anti-ultraviolet portable high-elastic sunscreen clothing fabric and a preparation method thereof. The fabric is sequentially compounded with a skin-friendly layer, a high-elastic breathable layer, an anti-ultraviolet functional layer and a protective outer layer from inside to outside. The skin-friendly layer is formed by blending natural bamboo fibers and chitosan-containing regenerated cellulose antibacterial fibers according to the ratio of 7: 3, and it is ensured that the skin is comfortable and antibacterial; the high-elastic breathable layer is of a warp-knitted elastic mesh structure formed by blending 15-20 wt% of spandex and chinlon, and has both elasticity and breathability. According to the anti-ultraviolet function layer, 80-100 g / m < 2 > polyester fiber base cloth is coated with a coating containing nanometer titanium dioxide and zinc oxide (the total mass accounts for 8-12% of the polyurethane coating, and the mass ratio is 2: 1), and efficient and lasting sun protection is achieved. The protective outer layer is formed by compounding a polytetrafluoroethylene microporous membrane and a polyester fabric, so that the protective performance is improved. During preparation, each layer is precisely processed by adopting a specific process, such as ultrasonic dispersion of nanoparticles and hot-pressing compounding of a hot melt adhesive, and is finally laminated, compounded and molded. According to the scheme, the problems that a traditional sunscreen garment fabric is poor in breathability, not lasting in sunscreen, poor in skin-friendly performance and the like are solved.

The invention belongs to the field of polytetrafluoroethylene microporous membranes, and particularly relates to a polytetrafluoroethylene microporous membrane with a high interception rate and a preparation method thereof. The polytetrafluoroethylene microporous membrane is prepared from the following raw materials in parts by weight: 40 to 50 parts of polytetrafluoroethylene resin powder, 1 to 10 parts of paraffin oil, 1 to 5 parts of alkyl acrylate, 1 to 5 parts of ethylene oxide acrylic resin and 5 to 10 parts of polyalkenyl succinimide. Alkyl acrylate and ethylene oxide acrylic resin can improve wear resistance and corrosion resistance; the high temperature resistance, chemical corrosion resistance and low-temperature flexibility can be improved, the size and distribution of pores are controlled by adjusting the stretching ratio, and the interception rate is improved on the premise that permeability is guaranteed.