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121 results about "Glass matrix" patented technology

Thermal shock resistant transparent high borosilicate glass

The invention belongs to the technical field of glass materials, and discloses thermal shock resistant transparent high borosilicate glass which comprises the following components in percentage by weight: 60-70% of silicon dioxide, 18-22% of diboron trioxide, 4-7% of aluminum oxide, 3-5% of magnesium oxide, 2-4% of alkali metal oxide, 0.5-1.5% of nano silicon nitride and 0.5-1% of nano aluminum titanate. The thermal shock temperature difference of the glass within the temperature change range of 20-200 DEG C is larger than or equal to 180 DEG C, the light transmittance within the visible light range of 400-760 nm is larger than or equal to 85%, the alkali metal oxide is composed of sodium oxide and potassium oxide, the weight ratio of the sodium oxide to the potassium oxide is 1: 1-3: 1, the average particle size of the nanometer silicon nitride is smaller than or equal to 100 nm, and the nanometer silicon nitride is evenly dispersed in the glass matrix; according to the thermal-shock-resistant transparent high borosilicate glass and the preparation method thereof, the thermal shock resistance and light transmittance of the glass are improved by optimizing the chemical components of the glass and adding the special nanoparticles in cooperation with a specific preparation process, and the thermal shock resistance of the glass is improved. The problems that existing high borosilicate glass is insufficient in thermal shock resistance and low in light transmittance in a high-temperature environment are solved.
Owner:JIANGSU HUAOU GLASS CO LTD

High-transparency rare earth doped fluoride glass and preparation method thereof

The invention provides high-transparency rare earth doped fluoride glass and a preparation method thereof, and belongs to the technical field of glass. The calcium fluoride ensures high transparency and chemical stability, the magnesium fluoride improves the ultraviolet transmittance and the mechanical strength, and the barium fluoride optimizes the melting fluidity and the rare earth doping uniformity; aluminum fluoride is added to inhibit crystallization and enhance uniformity, the rare earth element realizes optical function regulation and control, and ammonium fluoride provides a fluorine source and reduces impurities; in a preparation link, quick lime is dedusted and then reacts with pure water in proportion, impurities in a calcium nitrate solution are removed by hydrogen peroxide, uniform growth of calcium carbonate crystal nucleuses is controlled by ammonia water and carbon dioxide, and calcium fluoride is synthesized by hydrofluoric acid in proportion and dried at low temperature after plate-frame pressure filtration and purification; after the raw materials are refined through ball milling, the melting temperature is controlled in stages, impurities, reaction integrity and a microstructure are accurately controlled in the whole process, and finally the high-transparency functional glass is prepared.
Owner:QINHUANGDAO MICROCRYSTALLINE TECH CO LTD

A perovskite quantum dot glass with enhanced luminescence ability and its preparation method and application

The present invention discloses a perovskite quantum dot glass with enhanced luminescence capability, a preparation method thereof, and an application thereof, and belongs to the field of perovskite quantum dot glass display technology. The present invention regulates the network structure of borosilicate glass by adding ZrO2, so that the perovskite quantum precursor glass gradually changes from self-crystallization to transparency and finally to devitrification, the network structure of the glass matrix is ​​ordered, the surface defects at the interface between the perovskite quantum dots and the glass matrix are passivated, and the radiation recombination probability is increased, thereby obtaining a perovskite quantum dot glass with significantly improved photoluminescence performance. The perovskite quantum dot glass has a green light emission wavelength of 527nm, a full width at half maximum (FWHM) of 25.8nm, an internal quantum dot efficiency of 93.1%, and a brightness of 375cd / m ‑2 The maximum green light brightness under the excitation of the blue light (450nm) plate can reach 2647cd / m ‑2 When this perovskite quantum dot glass is used as an LED backlight module in LCD display, it can achieve a color gamut area of ​​118% of the NTSC standard, which is 1.73 times the color gamut of commercial displays, achieving a wide color gamut display effect.
Owner:FUJIAN NORMAL UNIV

Composite material, preparation method thereof and automobile glass

The invention belongs to the technical field of new materials, and discloses a composite material, a preparation method thereof and automobile glass, the composite material is a curved surface, and comprises a composite matrix, a glass plate and an organic back plate from bottom to top in sequence; wherein the composite matrix comprises a plurality of transparent ceramics and a glass matrix, and the plurality of transparent ceramics are spliced and laid in the glass matrix to form a structure that the glass is filled with the transparent ceramics. According to the invention, glass is taken as a matrix, a plurality of transparent ceramics are taken as filling bodies to form a composite matrix structure of partitioned transparent ceramic filled glass, and the composite matrix structure is compounded with a glass plate and an organic back plate, so that the composite material of the curved transparent ceramic filled glass with high safety, light weight, large size (1000mm * 1800mm) is obtained, the light transmittance is 64.2-81.2%, and the bending strength reaches 168.4-213.7 MPa.
Owner:CHINA FAW CO LTD

Enamel glaze based on transient template in-situ reaction as well as preparation method and application of enamel glaze

ActiveCN121800421AFritPhysical chemistry
The invention belongs to the technical field of enamel glaze, and particularly relates to enamel glaze based on transient template in-situ reaction and a preparation method and application thereof. The enamel glaze is prepared by mixing basic enamel glaze slip and a core-shell structure functional precursor, wherein the basic enamel glaze slip is water suspension prepared by mixing and grinding basic enamel frits and auxiliaries; the core-shell structure functional precursor is inorganic composite powder, and the original structure of the core-shell structure functional precursor is as follows: silicon nitride micron particles are used as a core, and a layer of Y-Zr-Ti composite oxide is coated on the surface as a shell. According to the invention, a real chemical bonding strong interface is realized, and a firm chemical bond is constructed in situ between a reinforced phase and a glass matrix by using a high-activity oxide shell layer as a solder in a final sintering stage. The problem that an interface is weak in traditional physical blending is fundamentally solved, and stress can be effectively transmitted from a matrix to a high-strength reinforced phase.
Owner:ZIBO ZHONGSHENG MASCH CO LTD

A method for preparing a high rare earth doped low loss boron containing glass optical fiber

This invention discloses a method for preparing high rare-earth-doped low-loss boron-containing glass optical fibers. The steps are as follows: weigh glass raw materials containing rare-earth oxides and boron oxide, mix them uniformly, and place them in a high-temperature furnace. First, heat the mixture under a high-purity nitrogen atmosphere, then switch to a high-purity oxygen atmosphere or a high-purity air atmosphere for continued heating. The resulting glass melt is cooled and annealed to obtain a large glass block. The glass is then processed into a preform and placed in an optical fiber drawing furnace for fiber drawing under a high-purity oxygen atmosphere, thus achieving the preparation of high rare-earth-doped low-loss glass optical fibers. This invention eliminates the additional glass matrix absorption in the near-infrared region caused by boron in boron-containing glass optical fibers and also transforms the transition metal impurity ions from a low valence state with broad absorption in the near-infrared region to a high valence state with narrow low absorption in the near-infrared region. Both of these aspects significantly reduce the matrix absorption of boron-containing glass optical fibers, providing possibilities for the application of high rare-earth-doped low-loss glass optical fibers.
Owner:HFB PHOTONICS CO LTD

Cover glass with outer frame, semiconductor light emitting device, and semiconductor light receiving device

This invention relates to a glass cover with an outer frame, wherein a flat glass plate is directly joined to the outer frame, wherein the glass matrix within the outer frame comprises at least one of bismuth oxide and boron oxide, and the glass ceramic has a coefficient of thermal expansion of 15 × 10⁻⁶. -7 In the glass ceramics described above, the total volume fraction of the negative thermal expansion filler and the total volume fraction of the filler components are both 40% to 65%, and the softening point of the glass components in the glass matrix is ​​lower than the glass transition point of the flat glass.
Owner:AGC INC

Nonlinear optical glass, method for producing the same, and use thereof

The application relates to a nonlinear optical glass, comprising a glass matrix and noble metal nanocrystals doped in the glass matrix, wherein the mass fraction of the glass matrix in the nonlinear optical glass is greater than or equal to 40%, and the composition of the glass matrix is xBi2O3-(66-x)P2O5-yZnO-(34-y)Al2O3 in terms of a mole fraction, 1 < x < 21, and 26 < y < 32. The application further provides a preparation method and application of the nonlinear optical glass. The nonlinear optical glass can realize high-concentration doping of noble metal nanocrystals and improve the third-order nonlinear performance of the nonlinear optical glass.
Owner:ZHEJIANG LAB

Perovskite quantum dot passivation method and perovskite quantum dot

PendingCN121135156AHalogenQuantum dot
The invention discloses a passivation method of a perovskite quantum dot and the perovskite quantum dot. The method comprises the steps that a mixed raw material is ground and then subjected to hot melting treatment, a molten material is obtained, and the mixed raw material comprises a glass matrix raw material, a lead source, a substance containing halogen elements and a cesium source; performing first heat treatment on the molten material to obtain 113-phase perovskite quantum dots of which the outer layers are coated with glass bodies; the 113-phase perovskite quantum dots with the outer layers coated with the glass bodies are subjected to second-time heat treatment, 416-phase perovskite quantum dots are formed on at least part of the surfaces of the 113-phase perovskite quantum dots, passivated perovskite quantum dots are obtained, and the temperature of the first-time heat treatment is higher than that of the second-time heat treatment. By adopting the method provided by the invention, the blue light stability of the perovskite quantum dots can be improved.
Owner:WUXI UTMOST LIGHT TECH CO LTD

Thermally managed optical fiber

The present application is generally directed to compositions and methods for forming glass matrices which may exhibit anti-Stokes fluorescence. The glass matrices of the present disclosure are formed such that a thermal characteristic can be tuned, such as the extent to which cooling by anti-Stokes fluorescence occurs. Optical fibers, such as those used in lasers, may be formed out of the presently described glass matrices. In embodiments, glass matrices of the present disclosure may form a cladding layer around an optical fiber. Further, glass matrices of the present disclosure may be used in combination with a device or to provide cooling to said device.
Owner:ENGHOLM MAGNUS +1

Method for manufacturing optical fiber preforms

The present invention provides a manufacturing method for optical fiber preforms that satisfies one or more of the following criteria: a method that produces as little manufacturing waste as possible, a method that produces a preform with the most uniform doping possible, a method that is as simple as possible to implement, and a method that is as cost-effective as possible. [Solution] A method for manufacturing an optical fiber matrix includes: a step of synthesizing glass particles using a plasma zone generated by a plasma generator; b step of repeatedly moving the glass matrix forward and backward in the axial direction relative to the plasma generator while the glass matrix is ​​rotating, wherein the forward and backward movement is performed at a relative supply speed between two reversal points; and c step of depositing glass particles on the glass matrix while the glass matrix is ​​moving and rotating relative to the plasma generator.
Owner:HERAEUS QUARZGLAS GMBH & CO KG

High-strength impact-resistant glass product and preparation method thereof

ActiveCN122079493AImproves Strength and ToughnessImprove thermal compatibilityThermal compatibilityPhysical chemistry
The invention discloses a high-strength impact-resistant glass product and a preparation method of the high-strength impact-resistant glass product in the field of glass, and the high-strength impact-resistant glass product comprises the following raw materials in parts by weight: 50-60 parts of SiO2; 10 to 15 parts of Al2O3; 5 to 8 parts of Li2O; 1 to 3 parts of Na2O; 0.5 to 1.5 parts of K2O; 2 to 5 parts of P2O5; 2 to 4 parts of ZrO2; 1 to 3 parts of TiO2; 1 to 2 parts of B2O3; 0.5 to 2 parts of rare earth oxide; 4 to 12 parts of modified SiC particles; and 1 to 3 parts of modified MoAlB particles. The modified SiC particles and the modified MoAlB particles are adopted as a double-phase reinforcing system, the thermal matching performance with a glass matrix is enhanced, and the strength and toughness of the final glass product are greatly improved under the assistance of the structural densification effect of the rare earth oxide.
Owner:SHAANXI YELLOW SEA SPECIAL GLASS CO LTD

Wavelength conversion assembly and lighting equipment

The utility model discloses a wavelength conversion assembly and lighting equipment. The wavelength conversion assembly comprises a supporting piece, a reflection unit and a fluorescent glass film. Wherein the reflection unit comprises a first reflection layer and a second reflection layer which are used for reflecting light; the first reflecting layer is connected between the second reflecting layer and the supporting piece, and the thermal conductivity of the first reflecting layer is larger than that of the second reflecting layer. The fluorescent glass film covers the side, away from the supporting piece, of the second reflecting layer and is suitable for being arranged on the light path where the exciting light is located. The fluorescent glass film provided by the utility model is a fluorescent film in which a glass matrix contains fluorescent particles. Therefore, the fluorescent film arranged on the wavelength conversion assembly adopts a glass matrix inorganic packaging mode, and compared with a mode of organic packaging by organic silica gel or resin and the like, the fluorescent glass film has better heat-conducting property, so that the phenomenon that the fluorescent glass film possibly becomes yellow under long-time irradiation of high-power laser is avoided, and the service life of the fluorescent glass film is prolonged. And the excitation efficiency of the excited light is ensured.
Owner:YLX INC

Coated substrate, paste and method for producing a paste

The invention relates to a coated substrate made of glass or glass ceramic, the coating having pigment particles embedded in a glass matrix, the average layer thickness of the coating being 2 to 5 [mu] m, the transmittance of the coating being at most 2%, the average particle size d50 of the pigment particles being less than 1.0 [mu] m, and the thickness of the coating being at least 10 [mu] m. Wherein the polydispersity index (PI) of the particle size distribution of the pigment particles is at most 2.0.
Owner:SCHOTT AG

CdTe power glass matrix and curtain wall

The application belongs to the technical field of power generation curtain wall, and discloses a cadmium telluride power generation glass matrix and curtain wall, a mounting groove is formed in the window frame, and a cable connector is arranged in the mounting groove; a first photovoltaic junction box is arranged at the top of the first photovoltaic glass, and the first photovoltaic junction box and the cable connector are electrically connected through a photovoltaic cable; the fan frame is connected to the top of the first photovoltaic glass and is rotationally connected with the window frame; the window frame has an extension part, the extension part is located at the side of the first photovoltaic glass and extends towards the bottom of the first photovoltaic glass, and a wiring channel is formed between the extension part and the first photovoltaic glass; and the photovoltaic cable has an extension amount. The application can realize the electrical connection function without additionally increasing the bridge and the connector, and the structure is more simple and the connection is more reliable. The application further discloses a cadmium telluride power generation glass curtain wall with the cadmium telluride power generation glass matrix.
Owner:CNBM CHENGDU OPTOELECTRONICS MATERIAL

Alkali metal sulfide nanocrystalline dispersed glass and preparation method thereof

The present invention discloses an alkali metal sulfide nanocrystal dispersed glass and a preparation method thereof. The alkali metal sulfide nanocrystal dispersed glass comprises a glass matrix and alkali metal sulfide nanocrystals within the glass matrix. The glass components, measured in molar percentage, include: SiO2: 40-70; Al2O3: 0-15; B2O3: 0-15; M2O: 0-30; NO: 0-4; and M2S: 15-45, the sum of which is 100, where M represents an alkali metal element and N represents an alkaline earth metal element. The present invention achieves controllable preparation of alkali metal sulfide nanocrystals in glass through composition design and heat treatment process regulation. The preparation process is simple, the nanocrystal size is controllable, and the cost is low.
Owner:WUHAN UNIV OF TECH

Narrow-band emission fluorescent powder-glass composite material for laser fluorescent display as well as preparation method and application thereof

The invention discloses a narrow-band emission fluorescent powder-glass composite material for laser fluorescent display as well as a preparation method and application of the narrow-band emission fluorescent powder-glass composite material. The problems of heat accumulation and efficiency attenuation of traditional fluorescent powder under high-power laser irradiation are solved through a rapid compounding process of an ultralow-melting-point glass matrix (SnF2-NaF-P2O5 system) and narrow-band fluorescent powder (such as KSF: Mn and beta-SiAlON: Eu) in cooperation with a dynamic heat dissipation design of a device. Stable light output is achieved under the 50W laser power, the luminous flux reaches 684lm and 4770lm respectively, and the color gamut covers 125% Rec.709 after the blue laser is coupled with blue laser. Meanwhile, the device is suitable for various commercial fluorescent powder and supports the design of a patterned fluorescent rotating wheel. The application bottleneck of traditional fluorescent powder is broken through, and the fluorescent powder is particularly suitable for high-end display scenes such as IMAX cinema, AR / VR immersive display and high-brightness engineering projection.
Owner:SOUTH CHINA UNIV OF TECH

A low-optical-distortion, spotless, large-curvature tempered glass and its forming method

This invention relates to the field of new materials technology, specifically to a low-optical-distortion, spotless, large-curvature tempered glass and its forming method. The glass substrate includes a glass matrix with a preset curvature and a large projected area. The surface physical tempering stress value of the glass substrate is 90MPa~150MPa, and the stress difference between different areas of its surface is controlled within 5MPa. Under anisotropic observation conditions, the glass substrate has no visible stress marks on its surface, and its transmitted optical distortion intensity is no greater than 0.05 diopter, with reflection waviness controlled within a preset extremely low threshold. By precisely controlling the surface physical tempering stress value between 90MPa and 150MPa, and creatively controlling the stress difference between different areas of its surface within 5MPa, the stress gradient approaches zero. This extreme stress uniformity fundamentally eliminates the optical birefringence phenomenon caused by local stress abrupt changes, resulting in completely no visible stress marks on the glass under anisotropic observation conditions.
Owner:FOSHAN GAOMING YAQI TEMPERED GLASS CO LTD

Fluorescent glass and preparation method and application thereof

The application discloses Ce:YAG fluorescent glass as well as a preparation method and application thereof, belongs to the technical field of rare earth luminescent materials, and solves the problems of serious interface corrosion, and decreased luminous efficiency and thermal stability caused by insufficient matching degree between a fluorescent glass matrix material and fluorescent powder in the prior art. The fluorescent glass comprises a glass matrix and Y3Al5O 12 :Ce fluorescent powder; wherein the glass matrix comprises, in terms of molar percentage, 45-55mol% of SiO2, 15-25mol% of Al2O3, 1-10mol% of NaF, 1-10mol% of Na2O, 2-12mol% of MgO, 3-13mol% of CaO and 1-10mol% of K2O. The application has the advantages of relatively low reaction temperature, small energy consumption, no need of complex equipment, loose and cheap material selection, and wide application in the fields of illumination, display and optical devices, etc.
Owner:BAOTOU RESEARCH INSTITUTE OF RARE EARTHS

Process of growing a biofilm

PCT designated stageWO2026062086A4Immobilised enzymesBacteriaBiotechnologyBiofilm
The present invention relates to a process of growing a biofilm on a glass matrix comprising a step of contacting glass fragments with at least one microorganism in an open flow reactor.
Owner:UNIV GUSTAVE EIFFEL

Application of radiation refrigeration glass prepared from fly ash on photovoltaic panel based on neural network and optimization algorithm and optimization method

The invention relates to radiation refrigeration glass based on industrial by-product fly ash and a preparation and optimization method thereof. The glass material with high sunlight reflectivity and high far infrared radiance is prepared by purifying and processing industrial by-product fly ash, using SiO2 and Al2O3 which are rich in fly ash as glass substrates and doping functional oxides such as CaO, MgO, TiO2 and ZrO2. A neural network fitting technology is innovatively adopted to establish a nonlinear mapping relationship between the glass component proportion and optical / thermal / mechanical properties, the component proportion is globally optimized in combination with a genetic algorithm or a particle swarm optimization algorithm, and the balance of high performance and low cost is realized through data driving. An optimization result is verified by utilizing tools such as MATLAB / ANSYS and the like, and indexes such as light transmittance, infrared radiance and mechanical strength are tested by experiments. The glass can be applied to the back face of a photovoltaic panel, the working temperature is reduced through efficient heat dissipation, the photoelectric efficiency is improved, and meanwhile high-added-value resource utilization of the fly ash is achieved. The material is suitable for the fields of photovoltaic power generation and building energy-saving window / wall materials, and has the advantages of environmental protection and economy.
Owner:NORTH CHINA ELECTRIC POWER UNIV

CsSnCl3 nanocrystalline doped chalcogenide glass and acousto-optic application thereof

PendingCN121361957AChalcogenide glassOptical coefficient
The invention discloses CsSnCl3 nanocrystal doped chalcogenide glass and acousto-optic application of the CsSnCl3 nanocrystal doped chalcogenide glass, the molar composition formula of the chalcogenide glass is 97 (0.8 GeS2-0.2 Sb2S3)-3 CsSnCl3, and CsSnCl3 nanocrystals separated out in situ through heat treatment are dispersed in the chalcogenide glass. The chalcogenide glass has the advantages as follows: the chalcogenide glass has excellent thermal mechanical properties and high robustness, the comprehensive characteristics are outstanding, the Vickers hardness, the elastic modulus, the thermo-optical coefficient, the laser damage threshold and other parameters of the chalcogenide glass are remarkably improved compared with those of current mainstream acousto-optic chalcogenide glass, and a guarantee is provided for stable operation of a device in a high-temperature and high-power environment; the CsSnCl3 nanocrystals are packaged by using the stable glass matrix, so that the problems that the Sn-based perovskite material is easy to oxidize in the environment and poor in stability are fundamentally solved; the material has good infrared acousto-optic comprehensive characteristics and an ultra-wide infrared transmission range, can be used as an acousto-optic medium to be applied to acousto-optic devices, and has a wide application prospect in the acousto-optic field.
Owner:NINGBO UNIV

Dual-band single-frequency linear polarization laser based on halogen anion and neodymium co-doped polarization maintaining optical fiber

The invention discloses a dual-band single-frequency linear polarization laser based on halogen anion and neodymium co-doped polarization maintaining optical fiber. Halogen anions, sulfur ions and neodymium are introduced into a glass matrix for co-doping, the local coordination environment and bonding covalence of Nd < 3 + > ions are regulated and controlled, and the emission cross section and bandwidth of the 0.9 mu m wave band are remarkably enhanced, so that the gain of the glass in the 0.9 mu m wave band and the gain of the glass in the 1.0 mu m wave band are balanced. A first DBR resonant cavity is formed by the optical fiber and a 0.9-micron broadband fiber grating / narrow-band polarization-maintaining fiber grating, and a second DBR resonant cavity is formed by the optical fiber and a 1.0-micron broadband fiber grating / narrow-band polarization-maintaining fiber grating, so that a cascade short linear cavity is formed, and simultaneous efficient lasing and single-longitudinal-mode stable operation of 0.9-micron and 1.0-micron dual-band laser are guaranteed.
Owner:SOUTH CHINA UNIV OF TECH

Enhanced TFT alkali-free glass substrate and preparation process thereof

PendingCN121470777ANanowireAlkali free
The invention discloses an enhanced TFT alkali-free glass substrate and a preparation process thereof, and belongs to the technical field of glass. According to the invention, by optimizing the components of the glass matrix and the concentration gradient regulation strategy of the nanowires, the refractive index matching of the Ni-TiSMA nanowires and the glass matrix is realized, and the visible light transmittance of the substrate is kept to be 91% or above, so that the problems of light scattering and transmittance reduction caused by refractive index difference in the prior art are solved, and both the mechanical strength and the thermal stability are improved. Specifically, by accurately controlling the distribution gradient and surface modification of the nanowires in the glass substrate and the synergistic effect of the nanowires and the glass substrate, the applicability of the glass substrate in the high-end display field is improved, the strict requirements of a large-size, high-resolution and light and thin display technology for the performance of the substrate are met, and by means of an innovative preparation process, the glass substrate can be manufactured into a large-size, high-resolution and light-thin glass substrate. Precise control over gradient distribution of the nanowires is achieved, and a feasible scheme is provided for large-scale production of high-performance TFT alkali-free glass substrates.
Owner:SICHUAN SHUWANG CHENSHENG NEW MATERIALS CO LTD

Optical glass, preparation method thereof and light guide plate

The invention provides optical glass, a preparation method thereof and a light guide plate. The optical glass comprises a glass matrix, and the glass matrix comprises the following components in terms of 100% of the total mass of the glass matrix: 0.5%-8.0% of B; 0.5%-6% of Si; 30% to 55% of La; 0.5%-12% of Y; ti: 3.1% to 10.5%; 0.9% to 9.5% of Nb; 0%-4.5% of Zn; 0.9% to 8.4% of Zr; 18.7% to 31.5% of O; the refractive index of the optical glass is 2.00 to 2.03, and the abbe number of the optical glass is 27 to 33. The optical glass has the advantages of high refractive index, low density, appropriate relative grinding hardness and Knoop hardness, and high internal transmittance.
Owner:HUBEI NEW HUAGUANG NEW INFORMATION MATERIALS CO LTD

A substitution type nanocrystal reinforced anti-thermal quenching scintillation glass and a preparation method thereof

This invention discloses a substitutional nanocrystalline reinforced quench-resistant scintillation glass and its preparation method. This scintillation glass consists of a glass phase and (Sr) 1‑x‑2y‑2z M x Ln y Tb z Na y+z It is composed of AlF5 nanocrystalline phase; among which, (Sr 1‑x‑2y‑2z M x Ln y Tb z Na y+z The volume fraction of the AlF5 nanocrystalline phase is 15-35%, and the volume fraction of the glass phase is 65-85%. This invention uses perfluoride as the glass matrix and employs a two-step heat treatment process involving high-temperature melting and nucleation / crystallization to prepare a substitution-type nanocrystalline reinforced quenching-resistant scintillation glass. The prepared scintillation glass exhibits photoluminescence and radiative emission with quenching-resistant properties, high quantum efficiency and light yield, and stable imaging capability under high-temperature X-ray irradiation, making it suitable for the field of high-temperature scintillators.
Owner:ZHEJIANG UNIV

Dental block and method of manufacturing the same

Disclosed is a glass-ceramic block containing a crystal phase in a non-crystalline glass matrix, a main crystal phase of the crystal phase including lithium pyrosilicate, an additional crystal phase including eucryptite, a gradient of the main crystal phase size with respect to the depth, a functionally graded material in which the value of the gradient of the main crystal phase size changes without an interface, a dental block required for cutting processing, which can be effectively used to manufacture artificial tooth restorations similar in aesthetics to natural teeth, and which, due to the inclusion of the additional crystal phase such as eucryptite, can be easily manufactured into artificial tooth restorations by mechanical processing compared to a phase including only lithium pyrosilicate, thereby not only shortening the manufacturing time but also increasing the structural stability in terms of force dispersion through functional grading of mechanical properties.
Owner:HAAS CO LTD

Wideband high-transmittance perfluoride multiphase glass and preparation method thereof

The invention discloses novel wide-band high-transmittance perfluoride complex-phase glass and a preparation method thereof. The novel wide-band high-transmittance perfluoride complex-phase glass specifically comprises the following components: 30 to 40 mol percent of AlF3, 28 to 30 mol percent of ZnF2, 11 to 27 mol percent of BaF2 + SrF2, 0 to 7 mol percent of CaF2 + MgF2 and 10 to 15 mol percent of YF3. The innovation of the invention lies in that the trigonal system AlF3 rhombohedral crystal is directionally separated out through component regulation and control, the crystal with the same component as the network former of the glass matrix is separated out in the perfluoride glass system for the first time, scattering caused by the refractive index difference between the crystal and the glass matrix is weakened, and the high-transmittance spectral range of the material is widened; and meanwhile, high spectrum flatness is realized. The wide-band high-transmittance fluoride complex-phase glass can realize full-band transmittance from 0.23 [mu] m to 7.2 [mu] m, and the transmittance is greater than or equal to 60%, wherein the transmittance of 0.86 [mu] m to 6.3 [mu] m is greater than or equal to 80%. The material is obtained through one step of melting and quenching, the preparation process is economical, simple and safe, and follow-up heat treatment is not needed.
Owner:SHANGHAI INST OF OPTICS & FINE MECHANICS CHINESE ACAD OF SCI

Ge-As-Se-CsI glass ceramic as well as preparation method and application thereof

The invention provides a Ge-As-Se-CsI glass ceramic as well as a preparation method and application thereof, and the preparation method comprises the following steps: melting and quenching raw materials to obtain basic glass, then carrying out ultra-fast heating to a crystallization temperature, carrying out short-time heat preservation, then cooling to a relatively low temperature, and carrying out long-time heat preservation, so that CsI crystal grains are uniformly separated out in a matrix, and finally obtaining the Ge-As-Se-CsI glass ceramic. According to the glass ceramic, Ge-As-Se chalcogenide glass serves as a base body, CsI crystals are evenly dispersed in the glass base body, the molar composition of the Ge-As-Se-CsI glass ceramic is represented by the chemical formula of (1-x) Ge < 0.22 > As < 0.2 > Se < 0.58-x > CsI, and x ranges from 0.01 to 0.08. Compared with the prior art, the Ge-As-Se-CsI glass ceramic prepared by the preparation method disclosed by the invention has the advantages that CsI particles are fine and are uniformly distributed, the hardness of the Ge-As-Se-CsI glass ceramic can be greatly improved on the basis of ensuring that the Ge-As-Se-CsI glass ceramic has good infrared permeability, and the application scene of the chalcogenide glass ceramic is widened.
Owner:NINGBO SUNSHINE HEPU PHOTOELECTRIC TECH CO LTD

Process for preparing CsPbBr3 glass / PS light conversion diffusion plate at low temperature

The invention relates to a process for preparing a CsPbBr3 glass / PS light conversion diffusion plate at a low temperature. The process comprises the following steps: preparing green glass of which a glass matrix contains CsPbBr3; the green glass provided by the invention is a glass body which can excite green light and is not the green glass in common words; grinding the green glass into powder, and then uniformly mixing the powder with the PS master batch to obtain a mixed material; the invention relates to a preparation method of a CsPbBr3 glass / PS light conversion diffusion plate, which comprises the following steps: 1) preparing CsPbBr3 glass / PS light conversion diffusion plate, 2) carrying out a melting granulation process on a mixed material obtained in the step 2) by using a single screw extruder to prepare CsPbBr3 glass / PS master batch, and feeding the prepared CsPbBr3 glass / PS master batch into an injection molding machine to prepare the CsPbBr3 glass / PS light conversion diffusion plate. The luminous efficiency of the prepared CsPbBr3 glass / PS light conversion diffusion plate is greater than 50%, the NTSC standard color gamut is greater than 130%, and the stability test exceeds 1000 hours under the conditions of accelerated aging experiment (60 DEG C, 90% RH and 16.5 mW / cm < 2 >
Owner:南通创亿达新材料股份有限公司 +1