High-temperature dust-removing and coke-removing integrated purifying process of biomass crude gas

A technology for high-temperature dust removal and purification process, which is applied in gas dust removal, catalytic conversion of impurities, gas purification, etc., can solve problems such as environmental pollution, deactivation of nickel-based catalyst coke deposits, and large fluctuations in gas production, and achieves simple and convenient process flow. Flexible, broad market application prospects, and the effect of avoiding secondary pollution

Active Publication Date: 2014-03-05
GUANGZHOU INST OF ENERGY CONVERSION - CHINESE ACAD OF SCI
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Problems solved by technology

However, the common problem at present is that the gasification process will always produce a certain amount of tar and carry more fine ash particles, which will cause difficulty in gas purification, blockage and corrosion of pipelines, and will seriously affect the stable operation of related combustion equipment
The cyclone separation dust removal technology is the simplest, but it is difficult to achieve the ideal dust removal effect due to large fluctuations in gas production during the operation of the biomass gasifier
At present, the most common method is to use simple water washing to purify the gas. However, due to the existence of a large amount of tar in the biomass gas, the sewage discharged from washing contains more harmful substances such as phenols and benzene, which will bring more serious problems to the environment. pollution problem
Catalytic cracking or high-temperature thermal cracking technology is often used abroad to reduce the tar content in gas. Although catalytic cracking can remove more than 90% of tar, the tar in raw biomass gas is mainly composed of very complex condensed ring compounds. Catalytic cracking The process is easy to cause carbon deposition and deactivation of nickel-based catalysts, and the application of catalysts will greatly increase the production cost of biomass gas
Therefore, none of the above technical methods can completely remove the ash and tar in the biomass high-temperature gas, and it is easy to form secondary pollution due to tar and ash

Method used

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  • High-temperature dust-removing and coke-removing integrated purifying process of biomass crude gas
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  • High-temperature dust-removing and coke-removing integrated purifying process of biomass crude gas

Examples

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Embodiment 1

[0029] This embodiment is a 2.0MW circulating fluidized bed biomass gasification power station with wood chips as raw material, and adopts the high-temperature gas dedusting and decoking integrated purification process and device of the present invention, which can produce circulating fluidized bed biomass gasification Fly ash and tar are efficiently removed, and the purified clean biomass gas can be supplied to four 500KW gas-fired generator sets for power generation.

[0030] Example uses figure 2 The biomass high-temperature gas multi-stage purification device shown.

[0031] The high-temperature purification process of this set of gas is as follows: ① The high-temperature biomass gas with a temperature of about 750 °C passes through the outlet of the fluidized bed gasifier and is transported to the high-temperature gas heat exchanger, that is, the air preheater, where it exchanges heat with cold air in the high-temperature gas Fully heat exchange in the gasifier, so that...

Embodiment 2

[0033] This embodiment is a 2.0t / h mixed-suction fixed-bed biomass gasification heating system with wood chips as the raw material. By adopting the high-temperature gas integrated purification process and device of the present invention, the fly ash produced by fixed-bed biomass gasification can be processed. Efficiently removed, the purified high-temperature biomass gas (including gaseous tar) can be directly supplied to a 8.0t / h steam boiler for stable operation.

[0034] The structure of the gas purification system is the same as that of Example 1, and the specific process is as follows: ① Turn on the gas preheater and the electric heating and heat preservation system to raise the temperature of the high-temperature gas purifier and related pipelines to 350-450°C. ② The high temperature biomass gas at 450°C passes through the outlet of the fixed bed gasifier (the dust content of the crude gas is 2.5g / Nm 3 Therefore, the tar content is 0.5g / Nm 3 ), enter the high-temperatur...

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Abstract

The invention discloses a high-temperature dust-removing and coke-removing integrated purifying process of biomass crude gas and provides a new process for high-efficiency purification of biomass high-temperature gas at low cost. The process comprises a high-temperature gas heat exchanger (A), a high-temperature gas purifier (B), a Venturi pulse back-blowing system (C), a gas preheater (D) and an electric-heating insulation system (E), wherein the five sets of equipment operate cooperatively to form a set of complete high-temperature gas purifying integrated device; a filtering medium in the high-temperature gas purifier is a modified ceramic membrane dust-removing pipe. When filtering cakes on the outer surface of the modified dust-removing pipe are deposited to certain thickness, deposited ash can be back-blown into an ash discharging hopper box for collection by the Venturi pulse back-blowing system. The high-temperature dust-removing and coke-removing integrated purifying process disclosed by the invention has the advantages that high-efficiency separation and integrated treatment of ash and coke components in biomass gas are realized; the dust-removing temperature is low so as to be beneficial to reducing the manufacturing cost of the equipment and prolonging the service life; biomass ash side products with commercial value are produced while the high-efficiency purification of the biomass crude gas is realized; the process flow is simple and flexible, the operation is simple, the purification cost is low and the suitability for industrial production is achieved.

Description

technical field [0001] The invention belongs to the technical field of high-temperature gas purification, and in particular relates to an integrated purification process of high-temperature dedusting and decoking of raw biomass gas. technical background [0002] In recent years, with the rise of low-carbon economy, the substitution of fossil energy such as coal, natural gas and oil by biomass has become a research hotspot in the field of new energy, which has important strategic significance and has been given enough attention by countries all over the world. Among the many new technologies for biomass energy utilization, biomass gasification technology is one of the fastest-growing and relatively mature engineering technologies. Biomass gasification is one of the important ways to convert primary energy into clean secondary energy. Its products are mainly combustible gases, which can also be processed into high-quality gases such as syngas and hydrogen after advanced treatm...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C10K1/02C10K1/34
Inventor 郎林阴秀丽吴创之潘贤齐
Owner GUANGZHOU INST OF ENERGY CONVERSION - CHINESE ACAD OF SCI
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