This invention relates to preparation and use of nanocomposites comprised of an
elastomer matrix which contains a dispersion therein of at least partially exfoliated platelets of an intercalated, multilayered, water swellable clay (e.g.
montmorillonite clay). The exfoliated platelets are derived from such intercalated clay formed by an in situ cation exchange phenomenon between cationically exchangeable ions within the galleries between the
layers of the multilayered clay with a preformed latex of cationic (positively charged)
elastomer particles. Said positively charged latex
elastomer particles may be prepared by free radical
emulsion polymerization using: (A) a non-polymerizable cationic surfactant, and / or (B) a polymerizable cationic surfactant. Optionally, an additional cationic charge may be incorporated onto the cationic elastomer latex particles through the use and in the presence of: (C) a polymerizable
comonomer bearing a cationic charge, (D) a free radical generating
polymerization initiator bearing a cationic charge, and / or (E) a free radical
chain transfer agent bearing a cationic charge. Such free radical induced
emulsion polymerizations are exclusive of a
thermoplastic polymer latex and are exclusive of the presence of an anionic surfactant. Rubber composites can be prepared by blending such
nanocomposite with additional elastomer(s), additional reinforcing filler(s) and / or a
coupling agent. The invention further relates to the preparation of articles of manufacture, including tires, having at least one component comprised of said
nanocomposite or said rubber composite. Such a tire component may be selected from, for example, tire
tread and tire innerliner.