The invention discloses a reduction sulphur-fixing method and device for treating daub and iron-rich heavy
metal solid waste of a waste lead-acid storage battery. The method comprises the steps of: with iron-rich heavy
metal solid waste as a sulphur-fixing agent and smokeless conny as a
reducing agent, firstly, fully uniformly mixing raw materials such as daub of the waste lead-acid storage battery with the sulphur-fixing agent and a
solvent,
drying and pelleting, then continuously adding the mixture and the
reducing agent (fuel) into an
oxygen side-blowing bath
smelting furnace for reduction sulphur-fixing
smelting, further producing lead
bullion,
iron sulphur and sulphur-containing
slag in one step under the condition that no
sulfur dioxide is generated. According to the method, sulphur in the raw materials is fixed in the sulphur-containing
slag and
iron sulphur, so that low-concentration
sulfur dioxide
pollution is thoroughly eliminated, valuable elements such as iron, gold, silver,
tin,
antimony and
bismuth in the sulphur-fixing agent are recycled with high efficiency at low cost, and continuous cleaning
smelting of the daub of the waste lead-acid storage battery and continuous harmless treatment of the iron-rich heavy
metal solid waste are realized. The reduction sulphur-fixing method has the advantages of changing harmful substances into beneficial substances, recycling waste materials, and being simple in process,
environmentally friendly, and low in cost, and has important significance for continuous clean smelting of the daub of the waste lead-acid storage battery and the treatment and recycling of the heavy metal solid waste.