211 results about "Pentachlorophenol" patented technology

The invention provides a mould-proof mothproof non-woven fabric, which comprises a top surface layer, a back surface layer, and a fiber cotton layer sandwiched between the top surface layer and the back surface layer, wherein the top surface layer and the back surface layer are made of non-woven fabric materials; the non-woven fabric is prepared by the following active ingredients in parts by weight through adopting a melt-blowing method: 100 parts of isotactic polypropylene, 2-3 parts of molybdenum disulfide, 1-2 parts of copper sulfate, 1-2 parts of jojoba oil, 1-2 parts of pentachlorophenol, 3-4 parts of zinc stearate, 1-2 parts of antioxidant 168, 12-15 parts of dioctyl terephthalate, 10-12 parts of rice hulls, 2-3 parts of bamboo charcoals, 2-3 parts of coptidis rhizome, 1-2 parts of cogongrass rhizome, 1-2 parts of rust-coloured crotalaria herb with root, and 4-5 parts of auxiliaries. The non-woven fabric has the mould-proof mothproof properties, as well as aromatic fragrance and health-care function, can adsorb harmful gas and peculiar smell, is heat-resistant, corrosion-resistant, non-toxic and odorless, large in tensile strength, good in binding power and free from dust and chips.

A post finishing process for superfine fiber artificial leather, i.e., chemically finishing and modifying fabric back material, is carried out by wet and dry finishing substrate, middle layer coating, and spraying a shining layer with appearance of natural leather for automobile seats, sofas and shoes. The artificial leather is like natural leather in elasticity, plumpness softness and appearance, neither Cr containing chemicals nor azo pigment nor pentachlorophenol nor free formaldehyde in production, i.e., an ecologic leather production.

The invention discloses a preparation method and application of sodium alginate microspheres. After reeds are washed, dried in air and crushed, reed powder is placed in a 600 DEG C muffle furnace (the environment is full of N2) to be subjected to pyrolysis for 2 h, after being cooled, the reed power is sieved through a 100-mesh sieve, and reed biochar is obtained after the reed powder is subjected to chlorohydric acid pickling. Meanwhile, sodium alginate is dissolved in deionized water to be prepared into a 4% sodium alginate solution. A 20g/L reed biochar aqueous solution and the sodium alginate solution are evenly mixed according to the volume ratio of 1:1, a mixed solution is dropped into a CaCl2 solution through a peristaltic pump, and reed biochar-sodium alginate microsphere adsorption materials are made. The sodium alginate microspheres are environment-friendly materials and low in cost, the preparation method is simple and easy to implement, specifications are uniform, the sodium alginate microspheres have a good adsorption effect on pentachlorophenol (PCP) and phenanthrene (Phe) and are easy to recycle and high in acid and alkali resistance. The preparation method can be used for waste water treatment and can also be used as growing carriers of microorganisms, algae and the like.

The invention relates to an earthworm strengthening repair method of soil polluted by phenanthrene, pyrene or pentachlorophenol, belonging to the treatment field of soil environment pollution and comprising the following steps: (A) measuring the content of the phenanthrene, pyrene or pentachlorophenol in soil at regular intervals; (B) adding earthworm or the earthworm and straw or the earthworm and a golden weeping willow. The earthworm is M.guillelmi geophagy earthworm, and is singly thrown mutually or thrown together with the golden weeping willow or thrown together with the straws. In the step B, 4-6 golden weeping willows are planted when the content of the phenanthrene, the pyrene and the pentachlorophenol is 5, 50 and 1mg/kg per square meter oil. The earthworm adopted by the invention can greatly improve the quality of cultivated soil and increase the agricultural reuse value of the soil while rapidly removing soil pollutants; the invention is harmonious with the natural ecologyprocess, and combines the earthworm repair with woody plants repair further so that organics are absorbed and utilized by the woody plant while the organics are metabolized.

The invention provides a visible light photocatalyst Bi12O17Cl2 and a preparation method of the photocatalyst. The preparation method comprises the following steps of: dissolving bismuth nitrate pentahydrate and potassium chloride in water to prepare a mixed solution, wherein the molar ratio of bismuth nitrate pentahydrate to potassium chloride is 1:1; and adjusting the pH value of the mixed solution to 12.5-13, then carrying out hydrothermal treatment at 160-180 DEG C on the solution to obtain a solid product, and washing and drying the solid product to obtain the Bi12O17Cl2 product, which is nano sheets with length of a few hundreds of nanometers and width of a few hundreds of nanometers. Under the irradiation of visible light, the photocatalyst can realize that more than 99.5% and approximate 100% of target pollutant pentachlorophenol is degraded within 45 minutes. The method is simple in synthetic route, easy in whole process control, easy in raw material obtaining, low in cost, and high in yield (up to 90%), and is suitable for industrial large-scale production.

The invention relates to a preparation method and an application of a polypyrrole-multiwalled carbon nanotube collaboratively-modified palladium-carried composite electrode and belongs to the technical field of electrochemical water treatment. The method comprises the following steps of: firstly ultrasonically dispersing carbon nanotubes after being pretreated into a volatile organic solvent to form carbon nanotube suspension liquid, soaking and lifting a Ti (titanium) net in the suspension liquid, and naturally drying the Ti net to ensure that the carbon nanotubes are dispersed on the surface of the Ti net; carrying out the electrochemical oxidization polymerization in a Py (polypyrrole) sulfuric acid solution to form polypyrrole, so as to obtain a polypyrrole-multiwalled nanotube modified membrane; finally electrically depositing Pd (palladium) in a PdCl2 solution to obtain the polypyrrole-multiwalled carbon nanotube-modified Pd-carried composite electrode. The electrode is used for electrically catalyzing and reducing chloride of chlorophenol in the water. Compared with a Pd/Ti electrode with no modified layer, the research shows that the electrode can rapidly and high-efficiently remove 2, 4-dichlorophen and pentachlorophenol and has universality. The prepared electrode is high in catalytic activity, good in stability, rapid and high-efficient for electrically catalyzing the chlorophenol in the water and promising in application prospect.

The invention provides an ecological environment-friendly treatment method of a dye or dye intermediate, which comprises the following steps: adding water and a neutralization agent into the dye or dye intermediate, and stirring the reaction system to react at 50-90 DEG C under atmospheric pressure or at 100-150 DEG C under 0.1-0.5 MPa for 3-5 hours; and after the reaction finishes, carrying out vacuum filtration, and washing with water to obtain the treated dye or intermediate, wherein the mole ratio of the dye or dye intermediate to the neutralization agent is 1:(0.2-6). After the dye or dye intermediate is subjected to ecological environment-friendly treatment, the contents of tetrachlorophenol (PCP), pentachlorophenol (TeCP) and chlorinated benzenes and toluenes are greatly lowered. In the fabric dyed by the dye or the dye synthesized by the dye intermediate, the contents of the PCP, TeCP and chlorinated benzenes and toluenes conform to limit requirements in Oeko-Tex Standard100.

The invention relates to a method for enhancement of ozone oxidation degradation of pentachlorophenol in a micro channel, and belongs to the water treatment technology field and the novel high-efficiency chemical equipment field. The method is mainly characterized in that an inlet is T-shaped or Y-shaped, an internal cross section of a main channel is rectangular in shape, and oxidative degradation of a POPs typical pollutant PCP is carried out by utilizing O3 in a square or circular micro channel reactor. When the initial concentration range of the substrate is 5-150 mg.L<-1>, under experimental conditions that the ranges of the superficial gas velocity, the superficial liquid velocity, the reaction temperature, the reaction pressure, and the ozone adding amount (according to the molar concentration ratio of ozone to the substrate) are respectively 0.10-12.00 m/s, 0.050-2.00 m/s, 0.1-1.0 MPa, 15-30 DEG C and 1.2-4.0, the reaction system enables the removal rate of the substrate PCP to reach as high as 90%-100%.

The invention provides an enzyme-linked immunosorbent assay kit suitable for pentachlorophenol residual analysis, which comprises elisa plate coated with pentachlorophenol antigen, concentrated cleaning liquid, pentachlorophenol standard, pentachlorophenol specific antibody, enzyme marker, coloration liquid and reaction stopping solution. The pentachlorophenol with the known concentration is detected and a standard curve is drawn, and then the concentration of the pentachlorophenol to be detected can be deduced. The invention has the advantages that the pentachlorophenol residual in the environment can be accurately and sensitively detected, the pretreatment process of the samples is simple and consumes less time, a great amount of the samples can be detected, and the detection cost of the samples is far lower than that of the detection method of the traditional instrument.

The invention discloses a disperse dye mixture. The disperse dye mixture comprises, by mass, 10-99% of one or more ingredients A which are compounds shown in the formula (I) and 1-90% of one or more ingredients B which are compounds shown in the formula (II). The disperse dye mixture is especially suitable for polyester fiber and ultrafine polyester fiber dyeing, has the characteristics of high dye uptake and good deep-dyeing property, does not contain pentachlorophenol and tetrachlorophenol and satisfies environmental protection requirements.

The invention discloses a catalytic material with a core-shell structure, gamma-Fe2O3-Fe3-xBixNbO7 (x is not less than 0.5 but not more than 1), SiO2-Fe3-xBixNbO7 (x is not less than 0.5 but not more than 1), MnO-Fe3-xBixNbO7 (x is not less than 0.5 but not more than 1); the particle size of gamma-Fe2O3, SiO2 and MnO is 0.06 to 2 microns, the particle size of core-coated Fe3-xBixNbO7 (x is not less than 0.5 but not more than 1) is 0.08 to 1.2 microns; the application of the catalytic material with the core-shell structure includes that: a reaction system consisting of a magnetic field device and photocatalytic material with a core-shell structure is used for degrading pentachlorophenol, Atrazine, diuron, crystal violet and other organic pollutants in water, and the magnetic-field intensity is chosen to be from 0.5 to 5T, and a xenom lamp or a high voltage mercury lamp is used as a light source; the volume percents of the three magnetic composite photocatalytic materials are all 1/3 of volume ratio so that the magnetic composite photocatalytic materials can be distributed in aqueous solution uniformly, and oxygenation and aeration are simultaneously adopted; the entire photoreaction is implemented under airtight and light-tight environment. Novel catalyst is loaded on a magnetic particle core through a multi-target magnetron sputtering deposition method, a pulse laser sputtering deposition method or a metal organic substance chemical vapor deposition method.

The invention discloses a specific detection method of pentachlorophenol. Pentachlorophenol is an electron-rich body, can be adsorbed to the surface of C<*+>, is oxidized into tetrachloroquinone by cavity h<+>, consumes C<*+> quantum dots, and causes weakening of a quantum dot electroluminescence signal, thus detection of pentachlorophenol is realized by detecting the change of the quantum dot electroluminescence signal. Compared with the traditional method, the method has higher sensitivity and specificity; by adopting the method, as low as 0.001nmol/L of pentachlorophenol can be detected; at the same time, the detection time is short, the sample treatment is simple, and the whole detection process does not exceed 30min; and the method is a new method for simply, conveniently, rapidly and specifically detecting pentachlorophenol.

A plant-microbe joint directional restoring penchlorol contaminated soil starts from selecting specific high degrading PCP degrading bacteria, then testing them and choosing optimum cultivating conditions. With soils of different degree of contamination, it can be used for potting plant suaeda glauce testing soil. Test the PCP left quantity in different growing stage of the suaeda glauce through sampling of the soil. It has the highest PCP degrading rate, with low density PCP (5mg/kg) reaching 94.73%. Combining of the specific PCP degrading bacteria and planting saeda glauce, restoring effect of soil is far bigger than implementing either one of them, reaching optimum PCP degrading result.

The invention discloses a multifunctional shoe polish for sneakers and a preparation method for the multifunctional shoe polish, which belong to the field of domestic chemistry engineering. The multifunctional shoe polish comprises, by weight, 20-30 parts of lithopone, 30-50 parts of microcrystalline wax, 20-40 parts of carnauba wax, 10-20 parts of montan wax, 5-10 parts of beeswax, 10-30 parts of silicon oil, 30-60 parts of glycerol, 5-8 parts of fatty alcohol-polyoxyethylene ether, 10-15 parts of turpentine, 2-5 parts of bactericide, 2-5 parts of sodium pentachlorophenol, 10-20 parts of stearic acid and 20-50 parts of deionized water. The preparation method for the multifunctional shoe polish includes steps of heating and smelting oil-phase materials in an oil-phase pot and uniformly mixing and emulsifying the melted oil-phase materials with water. The multifunctional shoe polish for sneakers and the preparation method for the multifunctional shoe polish have advantages of low cost of raw materials, high detergency, wide application of products and easiness in popularization.

The invention relates to a plant repair method of soil polluted by phenanthrene, pyrene or pentachlorophenol, belonging to the treatment field of soil environment pollution and comprising the following steps: (A) measuring the content of the phenanthrene, pyrene or pentachlorophenol in soil; and (B) implanting a golden weeping willow or planting deep-rootedness plant horse radish or implanting golden weeping willow and planting deep-rootedness plant horse radish at the same time. The willow in the step B is a golden weeping willow J1011(Salix*jiangsuensis CL.1011), and 4-6 golden weeping willows or deep-rootedness plant horse radishes are planted when the content of the phenanthrene, the pyrene and the pentachlorophenol 5, 50 or 1mg/kg per square meter of soil. The invention can stably remove organics in the soil well, conforms with the principle of taking actions that suit local circumstances and effectively applies natural force; the golden weeping willow and the deep-rootedness plant horse radish are used in combination, enabling pollutants to be concentrated intensively, therefore, the treatment effect is better than the sum of the effects of respective single treatment.

The present invention relates to a preparation method of a flower-like TiO2/graphene photocatalyst and application thereof. According to the photocatalyst disclosed by the present invention, titanium chloride (TiCl4) is taken as a titanium source, and a bromide N-butyl pyridine ionic liquid is taken as a shape control agent, so that the photocatalyst is prepared and formed through a hydrothermal microwave method; and the photocatalyst is specially applied to residual sodium pentachlorophenol in a vineyard, so that chemical toxic substances on grapes are reduced. In the preparation process, graphene oxide can be directly reduced into graphene by microwaves without the need of adding any other reducing agent, so that the purpose of green chemistry is achieved. The catalytic performance of the synthesized catalyst is greatly improved, the degradation of contaminants in industry is facilitated, and the synthesized catalyst has a good prospect in industrial applications.

A method for determination of the residual quantity of pentachlorophenol in eggs and egg products is characterized by comprising the steps: taking 1.0-5.0 g of a homogeneous sample in a 10 mL polypropylene centrifugal tube, adding 5-15 mL of an acetonitrile-water solution containing 5.0%-10.0% (V/V) of triethylamine, carrying out ultrasonic extraction and centrifugal separation, purifying the supernatant via a small mixed anion exchange column (6 mL), leaching with a methanol/water solution (50/50, V/V) containing 1.0%-5.0% (V/V) of formic acid, carrying out graded elution with a methanol solution containing 6.0%-15.0% (V/V) of formic acid, blowing the elution solution with nitrogen with the temperature of 40 DEG C to nearly dry, and redissolving with methanol for liquid chromatography tandem mass spectrometric determination. The method has the advantages of simple process, convenient and fast operation, good enrichment efficiency, high extraction recovery rate, low price, and good detection sensitivity and precision, is suitable for analysis of the residual quantity of pentachlorophenol in the eggs and the egg products, and has great significance on control of the residual quantity of pentachlorophenol in the eggs and the egg products and ensuring of food safety and human health.

Disclosed is a wood preservative composition comprising: an ester of boric acid; pentachlorophenol (PCP); and American Wood Preservative Association's (AWPA) P9 Type A solvent. The composition is useful for reducing insect and microbial decay in wood. Further disclosed are methods of making and using such compositions.

The invention relates to a flame-retardant type textile fabric. A used flame retardant coating layer is prepared from the following components: pentachlorophenol, ammonium polyphosphate, basalt fiber,nano carbon powder, polyvinylpyrrolidone, sodium polyacrylate, pozzolan and vinyl acetate. A preparation technique of a flame retardant for the textile fabric is simple, and the prepared product is relatively high in flame retarding performance.

Disclosed is a novel bacterial consortium comprise bacterial strains useful for effectively treating endocrine disrupters and a method for treating endocrine disrupters using the same. The invention provides a method for biologically restoring soils, wastes and water, etc. which are polluted with chlorinated compounds such as polychlorinated biphenyl (PCBs), dioxin, pentachlorophenol (PCP), perchloroethylene (PCE), trichloroethylene (TCE) and 1,1,1-trichloroethane (1,1,1-TCA), etc., polycyclic aromatic hydrocarbons (PAH) and petroleum-tar acids, and toluene which are all known as representative endocrine disrupters.

The invention relates to a method for purifying pentachlorophenol (PCP) in water through photocatalysis, which comprises the following processes of: mixing and stirring a bismuth silicate photocatalyst and pentachlorophenol sewage to be treated, performing ultrasonic dispersion, adsorbing and balancing, irradiating by using a xenon lamp and the like; and pentachlorophenol photocatalytic degradation reaction results prove that the pentachlorophenol in the water can be efficiently purified through the method. The invention can overcome the defects of high energy consumption, complex operation, violent reaction conditions, poor purification capacity and the like in the conventional purification method, provides a method having the advantages of short flow, simple equipment and good efficiency of purifying the pentachlorophenol, and has wide industrial application prospect.