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34results about How to "Increase hydrophilic group" patented technology

Viscosity reduction high efficiency water-reducing polycarboxylate superplasticizer and preparation method thereof

The invention relates to a viscosity reduction high efficiency water-reducing polycarboxylate superplasticizer and a preparation method thereof. The superplasticizer is prepared by intermittent dropwise adding of macromonomers like TPEG monomer, unsaturated hydroxy acid monomer or its derivative, or unsaturated acid with a trans-structure for free radical polymerization reaction under the action of a reductant, an oxidant and a chain transfer agent. The anchoring group and side chain in the superplasticizer are molecular structures in block distribution, and can give full play to electrostaticrepulsion and steric-hinerance effect. In addition, the hydroxyl, carboxyl and other polar groups introduced by the unsaturated hydroxy acid monomer or its derivative monomer increase the proportionof hydrophilic groups and reduce the surface tension of the cement pore solution. In addition, in terms of the trans-structural body represented by fumaric acid and dihydroxyfumaric acid derivatives,because of the special structure, i.e. the stiffness of the monomer itself and the distribution of two carboxyl groups on the opposite side of the side chain, a stretching structure easily exhibits inspace to reduce the possibility of molecular chain entanglement and significantly increase the adsorption effect of the polycarboxylate superplasticizer on the cement surface, thereby enhancing the viscosity reduction effect of the polycarboxylate superplasticizer.
Owner:HUNAN UNIV

A kind of viscosity-reducing high-efficiency water-reducing polycarboxylate water-reducer and its preparation method

A viscosity-reducing high-efficiency water-reducing polycarboxylate water-reducer and its preparation method, the water-reducer is composed of macromonomers such as isopentenol polyoxyethylene ether monomers, unsaturated hydroxy acid monomers or derivatives thereof, Or the unsaturated acid with trans structure is prepared by free radical polymerization under the action of reducing agent, oxidizing agent and chain transfer agent by intermittent dropping. The anchor groups and side chains in the water reducer of the present invention are block-distributed molecular structures, which can give full play to the electrostatic repulsion and steric hindrance effects; in addition, the hydroxyl groups introduced by unsaturated hydroxyacid monomers or their derivative monomers Polar groups such as carboxyl and carboxyl groups increase the proportion of hydrophilic groups and reduce the surface tension of the cement pore solution; in addition, the trans structure represented by fumaric acid and dihydroxy fumaric acid derivatives, due to its special The structure, that is, the rigidity of the monomer itself and its two carboxyl groups are distributed on the opposite side of the side chain, which makes it easy to show a stretched structure in space, reduces the possibility of molecular chain entanglement, and significantly increases the polycarboxylate superplasticizer. Adsorption on the surface of cement, thereby improving the viscosity-reducing effect of polycarboxylate superplasticizer.
Owner:HUNAN UNIV

A method and device for improving the synthesizing of 3,4-methylenedioxy mandelic acid through emulsification

The invention provides a method and device for improving the synthesizing of 3,4-methylenedioxy mandelic acid through emulsification. Based on the principle that 3,4-methylenedioxy mandelic acid has both lipophilic and hydrophilic groups, the method takes a resultant as an emulsifying agent so as to make the separating of a product simpler and easier; a water reducing agent is added during reaction and can be directionally adsorbed on the surfaces of oil phase droplets, so that the surfaces of the oil phase droplets can carry charges, electrostatic repulsion can be generated, and therefore, the dispersing effect of the water reducing agent can be achieved, the oil phase can be dispersed, and flowability can be increased; through the lubricating function of the water reducing agent, friction can be reduced by increasing the hydrophilic groups to form solvated water films, so that a 1,3-benzodioxole phase during the viscous stage of the product can be more dispersed, the lubricating function can be achieved by forming a water film form, the mass and heat transfer process of a reaction system can be uniformed, and the purity and yield of the product can be enhanced; and an inert solvent is dropwise added during reaction, so that the conversion rate of the reaction can be enhanced on the basis of increasing the flowability of the product, and the viscous problems of the product canbe solved. Thus, the device is provided for the above technologies.
Owner:山东天大泰泽环保科技有限公司
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