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A reactive triazine halamine antibacterial precursor suitable for low-temperature and low-salt finishing, a method and a cotton fabric

This invention discloses a precursor of a monochlorotriazine halogen amine antibacterial agent for low-temperature, low-salt finishing, its preparation method, and a cotton fabric and finishing method thereof. The precursor incorporates a 5,5-dimethylhydantoin derivative group linked by a hydrophilic group of sodium p-benzenesulfonate and an ether bond, and is prepared by a temperature- and pH-controlled reaction of cyanuric chloride with sodium p-aminobenzenesulfonate and 3-(3-chloro-2-hydroxypropyl)-5,5-dimethylhydantoin. The cotton fabric finishing process involves precursor dissolution, neutral salt impregnation, low-temperature weak alkali grafting, and chlorination. The process includes impregnation at 25-40°C and alkali reaction at 15-35°C, with a neutral salt concentration of 20-60 g / L and an alkali concentration of 0.5-2 g / L. The precursor has excellent water solubility and fiber compatibility. The finishing process inhibits hydrolysis and reduces energy consumption. The treated cotton fabric has a kill rate of over 99.99% against Staphylococcus aureus and Escherichia coli within 1 minute. After 50 washes, the active chlorine recovery rate exceeds 80%. It has high strength retention, is energy-saving, environmentally friendly and easy to industrialize.
Owner:NANTONG UNIV