The invention relates to a magnetic
solid-phase extraction method for
pyrethroid insecticides in
fruits and vegetables based on a Fe3O4-coated CS-coated AA material. The magnetic
solid-phase extraction method comprises the following steps: S1, synthesizing a Fe3O4-coated CS-coated AA magnetic adsorbent; s2, preparing a fruit and vegetable sample; s3, magnetic
solid phase extraction; s4, determining by using a
gas chromatography-
mass spectrometry method; fe3O4 nano magnetic particles are embedded in
chitosan gel, then
acrylic acid is grafted on
chitosan molecules for modification, the Fe3O4 CS AA magnetic adsorbent is prepared through
glutaraldehyde curing and crosslinking, and based on the fact that the
chitosan molecules contain a large number of-OH and-NH2 and-COOH active groups in
acrylic acid, the Fe3O4 CS AA magnetic adsorbent and
pyrethroid pesticide compounds form intermolecular
hydrogen-bond interaction, so that the magnetic adsorbent can be used for adsorbing the
pyrethroid pesticide compounds. Therefore, target component extraction is realized, and the method for determining
deltamethrin and
cyhalothrin pesticide residues in
fruits and vegetables by combining magnetic solid-phase extraction with
gas chromatography-
mass spectrometry is established.