Non-destructive detection method for pesticide residues in fruits and vegetables

A non-destructive testing and pesticide residue technology, applied in measuring devices, instruments, and material analysis through optical means, can solve problems such as inappropriate on-site detection of pesticide residues, difficult and complex detection methods, etc., and achieve information volume and complexity The effect of increasing, increasing the difficulty of distinguishing, and removing material interference

Inactive Publication Date: 2017-06-13
BEIJING TECHNOLOGY AND BUSINESS UNIVERSITY
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  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

This patented describes an improved technique called Surface Science Unmanned Spray Testing ("SSUM") for detecting pesticidial residences without damaging crops like peppers. Using this approach involves analyzing spectral patterns generated by sprayed droplets containing pestitives while measuring changes over time caused by these substances. These techniques allow accurate identification of pescence residents even if no known ones exist at all. Additionally, the proposed solution eliminates background noise sources and allows for quicker and nondispersible sampling compared to traditional approaches. Overall, this new technique offers faster and easier way to identify harmful organic compounds in food products.

Problems solved by technology

The technical problem addressed by this patents relates to improving upon currently available techniques such as surface enhancing raman scatter analysis that use laser excitation light sources, including expensive equipment and slow processing times. However, certain new tests require specific samples containing different substances, making it challenges even if they were developed beforehand. This makes it hard to identify all possible harmful ingredients within any given product during production. Therefore, the goal of this patented solution involves developing simpler and less invasively tested procedures while maintaining accuracy and reliability over previous approaches.

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  • Non-destructive detection method for pesticide residues in fruits and vegetables
  • Non-destructive detection method for pesticide residues in fruits and vegetables
  • Non-destructive detection method for pesticide residues in fruits and vegetables

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0049] Example 1: SERS non-destructive detection of pesticide residues on the surface of spinach

[0050] 1. Experimental materials

[0051] Deltamethrin pesticide: emulsifiable concentrate preparation, active ingredient content is 25g / L, purchased from Bayer Crop Science (China) Co., Ltd., Germany, production date 2016 / 3 / 2; surface enhancer: Easy Peak (Shufeng TM) scientific research type No. 2 silver sol, purchased from Shanghai Nateng Instrument Co., Ltd.; spinach: commercially available, with uniform leaf size and color.

[0052] 2. Sample Preparation

[0053] According to the provisions of the national standard GB 2763-2014 on the maximum residue limits of pesticide residues in food, the deltamethrin content in spinach should not exceed 0.5mg / kg, so the experimental implementation plan is as follows:

[0054] Prepare 15 standard solutions of deltamethrin with different concentrations, using deionized water as solvent, 25g / L deltamethrin EC as solute, and the mass fracti...

Embodiment 2

[0070] Example 2: Non-destructive testing of multiple pesticide residues on the surface of apples

[0071] 1. Experimental materials

[0072] Chlorpyrifos, malathion, and imidacloprid are three pesticide standard substances, the standard value of which is 1.0mg / ml, all purchased from the Institute of Standard Materials, China Institute of Metrology; surface enhancer: Easy Peak (Shufeng TM) scientific research type 2 Silver sol, purchased from Shanghai Nateng Instrument Co., Ltd.; Fuji apple: commercially available, uniform in shape, size and color.

[0073] 2. Sample Preparation

[0074] Three pesticide standard substances, chlorpyrifos, malathion and imidacloprid, were used as residues to prepare pesticide residue samples. Six commercially available Fuji apples with uniform shape and size were selected to add the three kinds of pesticide residue samples respectively. A sample of pesticide residues can be used to explore the influence of the background on the modeling later....

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Abstract

The invention discloses a non-destructive detection method for pesticide residues in fruits and vegetables. Based on an SERS (surface enhanced Raman spectroscopy) technology, various pretreatment methods are adopted and a qualitative model and a quantitative model are built, thus realizing quick and non-destructive detection for the content of the pesticide residues in the fruits and vegetables. The method comprises the following steps: building a differential spectrum data quantitative model for the residual content of deltamethrin on the surface of spinach, and building spectral data quantitative and qualitative model capable of simultaneously detecting three pesticides, namely chlorpyrifos, imidacloprid and malathion, in apples. By the adoption of the high-sensitivity SERS technology, any complicated pretreatment step of preparation of a sample and the like is not needed; due to direct detection of the pesticide residues in the fruits and vegetables or unit-area indirect detection, quick, non-destructive and pollution-free detection for the pesticide residues on the overall surfaces of the fruits and vegetables can be well realized; furthermore, the method is practical and relatively high in accuracy, and can be applied to non-destructive detection and on-site detection for the pesticide residues in other fruits and vegetables.

Description

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Claims

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Application Information

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Owner BEIJING TECHNOLOGY AND BUSINESS UNIVERSITY
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