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172 results about "Cinnamyl alcohol" patented technology

Cinnamyl alcohol or styron is an organic compound that is found in esterified form in storax, Balsam of Peru, and cinnamon leaves. It forms a white crystalline solid when pure, or a yellow oil when even slightly impure. It can be produced by the hydrolysis of storax.

Nano-gold catalyst supported on combined metal oxide, preparation method and application thereof

The invention provides a nano-gold catalyst supported on combined metal oxide, a preparation method and an application thereof. The preparation method comprises the following steps: preparing layered double hydroxides (LDH) precursor crystal nucleus and dispersing the LDH precursor crystal nucleus into sucrose solution; then adding chloroauric acid solution in the obtained mixture so as to reduce Au3+ in HAuCl4 to Au single substances by using the reduction of glucose and fructose produced by sucrose hydrolysis; in the process of reduction, crystallizing the LDHs so as to obtain solid LDH supported on nano-gold; and carrying out high-temperature roasting on the solid LDH supported on the nano-gold so as to obtain the nano-gold catalyst supported on the combined metal oxide. The combined oxide of the catalyst is taken as a carrier on which the nanosize gold particles is supported, wherein the combined oxide refers to MgO or compound of ZnO and Al2O3, and the mole ratio of the MgO to the compound of ZnO and Al2O3 is 2-6:1; the gold capacity is 0.5 to 3 percent, the size of the gold particle is 8 to 15nm, and the gold particle is ellipsoidal or polyhedral. When the catalyst is used in the catalytic hydrogenation reaction of unsaturated aldehydes, the conversion rate of reactants reaches 60 to 97 percent, and the selectivity of cinnamyl alcohol is 40 to 75 percent.
Owner:BEIJING UNIV OF CHEM TECH

Hydrotalcite-loaded nanometer platinum catalyst as well as preparation method and application thereof

The invention provides hydrotalcite-loaded nanometer platinum catalyst as well as a preparation method and application thereof. The preparation method of the hydrotalcite-loaded nanometer platinum catalyst comprises the following steps of: preparing magnesium-aluminum hydrotalcite crystal nucleus by utilizing an all-return liquid mixing membrane reactor, dispersing the crystal nucleus in an aqueous solution; adding an chloroplatinic acid aqueous solution and tetradecyl trimethyl ammonium bromide (TTAB) as well as a proper proportion reducing agent of NaBH4; controlling the reducing velocity and the growth of Pt nanometer particles by utilizing the protecting and stabilizing effect of the TTAB to the Pt<4+> ion; and gradually crystallizing the hydrotalcite while reducing the Pt<4+> ion to obtain the hydrotalcite-loaded nanometer platinum catalyst. The catalyst is obtained by loading nanometer particles on a hydrotalcite carrier, wherein the chemical formula of the hydrotalcite is as follows: MgxAly(OH)16CO3 nH2O; the platinum nanometer particle dimension is 2 nm-8nm; the nanometer particles are polyhedral or ellipsoidal in appearance; the loading capacity of the platinum is 0.5%-3%; and the dispersion degree on the carrier is 20%-50%. The hydrotalcite-loaded nanometer platinum catalyst can be used for catalytic hydrogenation reaction of unsaturated aldehyde (cinnamyl aldehyde), wherein water is used as solvent, the conversation rate of the reactant cinnamyl aldehyde is 75%-95% and the selectivity of the product cinnamyl alcohol is 75%-95%.
Owner:BEIJING UNIV OF CHEM TECH

Composite metal oxide loaded Pt-based nano metal catalyst and preparation method therefor

A Pt-based nanometer metal catalyst supported by a composite metal oxide and a preparation method thereof belong to the technical field of catalyst preparation. Composite Metal Oxide Supported Pt-Based Nanometal Catalysts Composite Metal Oxide as CeO 2 -ZrO 2 、TiO 2 -ZrO 2 , ZrO 2 -TiO 2 One of them, the specific surface area of ​​the catalyst is 250-400m 2 / g, the average particle diameter of Pt particles is 2-5 nm, and the mass percentage of Pt is 1.0-5.5%. The metal salt solution, chloroplatinic acid solution and potassium borohydride solution are mixed in a colloid mill to nucleate at a high speed, and then use kinetics to control the hydrothermal reaction, and further realize the compounding of metal oxides and the reduction of precious metals, and finally obtain a compound Metal oxide-supported Pt-based nanometal catalysts. The method is applied to the reaction of preparing cinnamyl alcohol by selective hydrogenation of cinnamaldehyde, and the conversion rate of cinnamaldehyde and the selectivity to cinnamyl alcohol can reach 90-100% and 90-100% respectively. The metal nanoparticles of the catalyst have high dispersion degree, small size, strong interaction with carrier and simple preparation method.
Owner:BEIJING UNIV OF CHEM TECH

Osmanthus flower essence for water-based ink and preparing method of osmanthus flower essence

The invention relates to osmanthus flower essence for water-based ink. The osmanthus flower essence for the water-based ink consists of the following ingredients in percentage by weight: 1 to 30 percent of osmanthus flower essence, 5 to 55 percent of composite modified oligosaccharide and deionized water, wherein the osmanthus flower essence consists of beta-ionone, dihydro-beta-ionone, linalool, alpha-jasminolene, alpha-amyl cinnamic aldehyde, isoamyl salicylate, benzyl salicylate, benzyl benzoate, galaxolide, citronellol, geraniol, cinnamyl alcohol, cognac oil, tetradecyl aldehyde, para-mentha-8-thiolone with the mass percent concentration being 1 percent, terpilenol, methyl anthranilate, osmanthus flower extracts and ethyl alcohol. The invention also provides a preparing method of the osmanthus flower essence for the water-based ink. The composite modified oligosaccharide is used as a wall material; the osmanthus flower essence is coated to form nanocapsule slow-release essence, so that the fragrance retention and the water solubility of the essence are improved; the preparing method is applicable to the perfuming of the water-based ink. The osmanthus flower essence for the water-based ink has the advantages that the fragrance is exquisite; the natural feeling is high; the fragrance retention is durable.
Owner:SHANGHAI INST OF TECH

High-temperature-resistant bearing lubricant additive

The invention discloses a high-temperature-resistant bearing lubricant additive. The high-temperature-resistant bearing lubricant additive is prepared from, by weight, 6-12 parts of sodium dodecyl benzene sulfonate, 4-8 parts of fatty alcohol polyoxyethylene ether carboxylate, 5-9 parts of triphenyl phosphorothioate, 3-9 parts of zinc dialkyl dithiophosphate, 4-6 parts of para aminobenzoic acid, 6-9 parts of octyl phenol, 3-5 parts of calcium alkyl salicylate, 2-3 parts of a fluorinated surfactant, 2-5 parts of a fluorinated surfactant, 2-4 parts of cinnamyl alcohol, 5-12 parts of diisocyanate, 8-15 parts of dodecencylsuccinic acid, 3-6 parts of inositol hexaphosphoric acid, 4-8 parts of modified aluminium triphosphate, 4-8 parts of a viscosity index improver, 4-8 parts of an oxidation and corrosion inhibitor and 4-8 parts of an extreme pressure antiwear agent. Compared with the prior art, the lubricant additive has the advantages that the additive properties can be optimized through the compounding effect of multiple auxiliaries, the good lubricant property enhancing effect can be achieved through a little amount of the additive, the high temperature resistance, the viscosity property and the wear resistance of a lubricant can be promoted, and the quality of the lubricant is greatly promoted.
Owner:ANHUI QIANSHAN BEARING MFG

Preparation method of microwave radiation enhancement alkali-modified carbon-supported noble metal catalyst for production of cinnamyl alcohol by means of selective hydrogenation

The invention discloses a preparation method of a microwave radiation enhancement alkali-modified carbon-supported noble metal catalyst for production of cinnamyl alcohol by means of selective hydrogenation. The method comprises the steps of dispersing activated carbon powder into an alkaline solution at 50-100 DEG C, and carrying out modification treatment on activated carbon for 10-120 min undermicrowave irradiation to obtain modified activated carbon; then, using an impregnation method to prepare the platinum or palladium supported catalyst by taking the modified activated carbon as a carrier. The method adopts microwave radiation enhancement alkali modification, and has a remarkable pore-expanding effect on the activated carbon, thus greatly increasing the proportion of mesopores; furthermore, the types and number of oxygen-containing groups of the activated carbon are increased, and the content of impurities such as silicon and aluminum is greatly reduced. The catalyst prepared by the method is used for catalyzing a reaction for producing the cinnamyl alcohol by means of selective hydrogenation of cinnamyl aldehyde, and the yield of the cinnamyl alcohol is remarkably improved.
Owner:SHAANXI NORMAL UNIV +1
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